Patents Represented by Attorney, Agent or Law Firm Gregory F. Wirzbicki
  • Patent number: 6117333
    Abstract: A process is disclosed which involves removing hydrocarbons, arsenic and mercury from wastewater produced in oil and gas fields. An oxidant, ferric ions, and flocculent are sequentially added to the wastewater to form a removable sludge containing the arsenic, hydrocarbon, and mercury contaminants. The Oxidation-Reduction Potential of the wastewater is controlled by oxidant addition to allow the required arsenic oxidation to occur while maintaining the mercury in elemental form. The process requires relatively short residence times between chemical additions and provides for large wastewater throughputs. The cleaned wastewater is suitable for discharge to the environment.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: September 12, 2000
    Assignee: Union Oil Company of California
    Inventors: Theodore C. Frankiewicz, John Gerlach
  • Patent number: 6112524
    Abstract: Boron, silicon and/or arsenic in geothermal steam is removed by contacting the steam with an alcohol containing at least four carbon atoms or polyols having at least two carbon atoms.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: September 5, 2000
    Assignee: Union Oil Company of California
    Inventor: Darrell L. Gallup
  • Patent number: 6110874
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: August 29, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 6107255
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: August 22, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 6099645
    Abstract: An apparatus for holding a plurality of semiconductor wafers during heat treatment of the wafers in a furnace, which apparatus comprises a plurality of support members or rails extending essentially vertically between a top and bottom plate. At least two of the support members are located toward the front of the carrier where the wafers are inserted, and at least one support member is located toward the back of the carrier. A first plurality of slats is attached to one of the front support members and to a back support member such that the space between the top surface of one slat and the bottom surface of the next higher adjacent slat forms a slot for receiving a portion of a semiconductor wafer. A second plurality of slats is attached to another front support member and to a back support member to form corresponding slots on another side of the carrier for receiving another portion of a semiconductor wafer.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: August 8, 2000
    Assignee: Union Oil Company of California
    Inventors: Micheal E. Easley, Ronald E. Plummer
  • Patent number: 6095245
    Abstract: A repositionable apparatus for perforating and gravel packing an underground well uses gravity or other means to reposition the apparatus instead of a conventional wireline or work string attached to a rig. Perforating and packing can be accomplished without a rig after the apparatus is initially placed and set in the well. One embodiment of the inventive apparatus uses a perforating gun assembly, a connected ported sub above the gun assembly, a translating annulus packer above the ported sub, a circumferential screen located above the packer, blank pipe connected above the screen, an openable port above the blank tubular pipe, and a second translating annulus packer attached to the blank tubular.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: August 1, 2000
    Assignee: Union Oil Company of California
    Inventor: Matthew J. Mount
  • Patent number: 6083625
    Abstract: A graphite furnace element, such as a heat shield or heating element, comprises a plurality of bent, rigid, solid and arcuate-shaped graphite sheets that have been joined together, usually by screws or bolts. The bent graphite sheets typically have a wall thickness between 0.05 and 0.5 inch.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: July 4, 2000
    Assignee: Union Oil Company of California
    Inventors: Larry D. Fiel, Jamie Lorzadeh
  • Patent number: 6034037
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: March 7, 2000
    Assignee: Union Oil Company of California,
    Inventor: Donald C. Van Slyke
  • Patent number: 6030521
    Abstract: By controlling one or more properties of a gasoline fuel suitable for combustion in automobiles, the emissions of NOx, CO and/or hydrocarbons can be reduced. The preferred fuel for reducing all three such emissions has a Reid Vapor Pressure no greater than 7.5 psi (0.51 atm), essentially zero olefins, and a 50% D-86 Distillation Point greater than about 180.degree. F. (82.degree. C.) but less than 205.degree. F. (96.1.degree. C.
    Type: Grant
    Filed: November 13, 1998
    Date of Patent: February 29, 2000
    Assignee: Union Oil Company of California
    Inventors: Peter J. Jessup, Michael C. Croudace
  • Patent number: 6019903
    Abstract: A corrosive acid sulfate geothermal brine is mixed with a near neutral, bicarbonate geothermal brine containing above about 300 ppm silica to produce a relatively benign mixed brine of pH from about 4.5 to about 6.5 having reduced corrosivity as compared to the acid sulfate brine and a reduced tendency as compared to the near neutral, bicarbonate brine for depositing silica in equipment during brine processing.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: February 1, 2000
    Assignee: Union Oil Company of California
    Inventor: Darrell L. Gallup
  • Patent number: 6017854
    Abstract: Simplified drilling fluids (and other well bore fluids) contain a non-aqueous-base fluid and a viscosifying/fluid loss agent that meets certain performance criteria.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: January 25, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5965031
    Abstract: Sulfurous acid and/or sulfurous acid precursors, such as sulfur dioxide, are introduced into a hydrogen sulfide-containing geothermal brine or fluid prior to extracting energy from the resulting mixture by, e.g., passing the mixture through a flash vessel or a heat exchanger. The introduction of the sulfurous acid or its precursors into the geothermal brine or fluid inhibits scale formation and/or removes previously formed scale during processing of the brine or fluid.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: October 12, 1999
    Assignee: Union Oil Company of California
    Inventors: Kevin R. Kitz, Darrell L. Gallup
  • Patent number: 5963030
    Abstract: An openable ring assembly is externally centered around and moved parallel to the centerline of a stationary pipe. As a low-frequency EM source signal is applied to the ring assembly, the time and/or frequency shifts of a detected EM signal from the source signal can be correlated to pipe wall thickness without removal of external pipe insulation and metal cladding, if present. The ring assembly may be opened or expandably segmented to allow pipe thickness detection around obstructions or larger diameter pipe. Centering is preferably accomplished by using rollers circumferentially attached to the ring assembly.
    Type: Grant
    Filed: March 30, 1998
    Date of Patent: October 5, 1999
    Assignee: Union Oil Company of California
    Inventor: Mitchel A. Stark
  • Patent number: 5958845
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: September 28, 1999
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5957203
    Abstract: Cationic polymer-containing gels are stable at elevated temperatures in soft and hard waters.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: September 28, 1999
    Assignee: Union Oil Company of California
    Inventors: Richard D. Hutchins, Hoai T. Dovan, Burton B. Sandiford
  • Patent number: 5912080
    Abstract: A sheet of high strength graphite material is bent into an arcuate shape, and the bent sheet is retained in that shape for use in a high temperature furnace. The bent sheet is rigid and can replace prior art machined blocks of lower strength graphite in a furnace. The bent sheet can also be further machined and/or further deformed into other shapes.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: June 15, 1999
    Assignee: Union Oil Company of California, dba Unocal
    Inventors: Larry D. Fiel, Jamie Lorzadeh
  • Patent number: 5879433
    Abstract: One or more contaminants selected from the group consisting of acidic gases, inert particulates, and mixtures thereof are removed from steam by contacting the contaminated steam with a nonaqueous sorbent such as crystalline molecular sieves, silica gels, soda ash, carbonaceous adsorbents, and amine liquid ion exchange resins.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: March 9, 1999
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, Thomas S. Powell
  • Patent number: 5858245
    Abstract: A method for controlling fouling of a production or reinjection well, a flashing vessel or a heat-exchange surface exposed to a high-enthalpy geothermal brine that forms metal/silicon-containing scale comprises the addition of a metal complexing agent to the brine to form a fluid mixture containing a soluble metal/silicon component complex that inhibits the amount of scale formation when the temperature of the fluid mixture is reduced. The addition of a preferred metal complexing agent such as forms of EDTA, citric acid or acetic acid maintains dissolved aluminum species in the brine and inhibits the formation of aluminum silicate precipitate.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: January 12, 1999
    Assignee: Union Oil Company of California
    Inventor: Darrell L. Gallup
  • Patent number: 5837126
    Abstract: By controlling one or more properties of a gasoline fuel suitable for combustion in automobiles, the emissions of NOx, CO and/or hydrocarbons can be reduced. The preferred fuel for reducing all three such emissions has a Reid Vapor Pressure no greater than 7.5 psi (0.51 atm), essentially zero olefins, and a 50% D-86 Distillation Point greater than about 180.degree. F. (82.degree. C.) but less than 205.degree. F. (96.1.degree. C.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: November 17, 1998
    Assignee: Union Oil Company of California
    Inventors: Peter J. Jessup, Michael C. Croudace
  • Patent number: 5814120
    Abstract: A repositionable hot-glass contact pad composed at least in part of a relatively high-strength nonmetallic material having one or more repositionable support projections and a glass-contact surface. The high strength nonmetallic material and use of multiple support projections allow reliable attachment of the pad to a metal support structure in a plurality of positions to handle a variety of hot-glass article shapes and sizes with minimal checking or other damage.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: September 29, 1998
    Assignee: Union Oil Company of California
    Inventors: Patrick H. Lloyd, Kyle D. Nelson