Abstract: A method of breaking a water-in-oil emulsion in a hydrocarbon liquid comprising adding to the hydrocarbon a sufficient amount of a quaternary alkyl amine ethoxylate.
Abstract: A method for controlling the deposition of scale imparting species on the structural surfaces of steam generating systems comprising the use of a water soluble polymer having the structure ##STR1## wherein R.sub.1 is H or lower (C.sub.1 -C.sub.4) alkyl, R.sub.2 is (CH.sub.2 --CH.sub.2 --O).sub.n, ##STR2## or a mixture of both, and n is an integer of from about 1 to about 40, R.sub.3 is H, lower (C.sub.1 -C.sub.4) alkyl or an acetate. This polymer may also be used in concert with topping agents such as phosphoric acids, phosphonic acids, amines, metal chelating agents and oxygen scavengers.
Type:
Grant
Filed:
February 7, 1992
Date of Patent:
September 7, 1993
Assignee:
Betz Laboratories, Inc.
Inventors:
Fu Chen, Keith A. Bair, Scott M. Boyette
Abstract: A method for detecting the presence of sugars in the water of a steam generating system by using an indicator composition comprised of potassium permanganate and an acetate in an aqueous solution. After a period of time, depending upon the temperature of the sample tested, the color of the sample is observed to determine if sugars are present in the water.
Abstract: A method for treating the microbial slime that is generated in industrial water systems by adding to the water a combination of enzymes specific to the numerous saccharide units that make up the exopolysaccharide layer. These enzymes comprise galactosidase, galacturonidase, rhamnosidase xylosidase, fucosidase, arabinosidase and .alpha.-glucosidase.
Abstract: A composition and method of use thereof for the treatment of wastewater comprising a block copolymer having the formula: ##STR1## wherein E is a polymeric segment obtained from the polymerization of hydrophobic monomers, x when present is a nonionic monomer, y is a cationic monomer, R.sub.1 and R.sub.2 are the same or different and are H or a lower alkyl group from C.sub.1 to C.sub.3 and F is a salt of an ammonium cation.
Type:
Grant
Filed:
September 3, 1992
Date of Patent:
August 10, 1993
Assignee:
Betz Laboratories, Inc.
Inventors:
Wen P. Liao, Fu Chen, Stephen R. Vasconcellos
Abstract: A composition to control foam in aqueous systems such as those found in papermaking operations comprising a polybutene and at least one surfactant having a melting or pour point below 20.degree. C. The surfactants include polyethylene glycol esters, sorbitan ester, polyoxyalkylene ester, oleic diethanolamide and block copolymers of ethylene oxide and propylene oxide. Due to their low melting point, these surfactants may be blended with the polybutene at room temperature resulting in a foam control composition that is translucent, resistant to deposition and highly effective.
Type:
Grant
Filed:
February 6, 1991
Date of Patent:
July 20, 1993
Assignee:
Betz PaperChem, Inc.
Inventors:
Duy T. Nguyen, Mitzi K. Fader, William A. Hendriks
Abstract: A method for inhibiting fouling during the elevated temperature processing of hydrocarbon comprising adding to the hydrocarbon a composition comprising a catechol having the structure: ##STR1## wherein R is H or C.sub.1 -C.sub.10 alkyl and, an organic acid.
Abstract: A water soluble graft copolymer useful for dewatering wastewater having the structure: ##STR1## wherein E is the repeat unit obtained after polymerization of an .alpha.,.beta. ethylenically unsaturated compound the molar percentage of a:b is from about 95:5 to 5:95 with the proviso that the sum of a and b equals 100%; G comprises the structure: ##STR2## wherein d is a cationic monomer, R.sub.1, R.sub.2 and R.sub.3 are the same or different and are hydrogen or a lower alkyl group having C.sub.1 to C.sub.3, F is the salt of an ammonium cation and the molar percentage of c:d is from 95:5 to 5:95 with the proviso that the sum of c and d equals 100%.
Abstract: A process for adding an amine having a pKa of between 5 and 8 to a petroleum refinery distillation unit for the purpose of neutralizing acidic species contained in the hydrocarbon feedstock. The use of these amines raises the dew point pH sufficiently to prevent corrosion of the metallic surfaces of the overhead equipment while reducing the potential for the precipitation of amine salts.
Abstract: A composition and method of use thereof for the treatment of wastewater comprising a block copolymer having the formula: ##STR1## wherein E is a polymeric segment obtained from the polymerization of hydrophobic monomers, x when present is a nonionic monomer, y is a cationic monomer, R.sub.1 and R.sub.2 are the same or different and are H or a lower alkyl group from C.sub.1 to C.sub.3 and F is a salt of an ammonium cation.
Type:
Grant
Filed:
February 26, 1991
Date of Patent:
January 26, 1993
Assignee:
Betz Laboratories, Inc.
Inventors:
Wen P. Liao, Fu Chen, Stephen R. Vasconcellos
Abstract: A method for controlling the deposition of scale imparting species on the structural surfaces of steam generating systems comprising the use of a water soluble polymer having the structure ##STR1## wherein E is the repeat unit remaining after polymerization of an alpha, beta ethylenically unsaturated compound.This polymer may also be used in concert with topping agents such as phosphoric acids, phosphonic acids, polyvalent metal salts, metal chelating agents and oxygen scavengers.
Type:
Grant
Filed:
January 28, 1992
Date of Patent:
January 19, 1993
Assignee:
Betz Laboratories, Inc.
Inventors:
Fu Chen, Scott M. Boyette, Keith A. Bair
Abstract: A water soluble terpolymer useful in controlling deposition of scale in aqueous systems comprised of monomeric repeat units (g), (h) and (i) wherein repeat unit (g) comprises the structure ##STR1## wherein E is the repeat unit obtained after polymerization of an .alpha.,.beta. ethylenically unsaturated compound, wherein repeat unit (h) comprises the structure ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and denote H, methyl or ethyl and M is a water soluble cation or H, and wherein repeat unit (i) comprises the structure ##STR3## wherein R.sub.3 is a lower alkyl (C.sub.1 -C.sub.3), R.sub.4 is a hydroxy substituted alkyl or alkylene group having from 1 to about 6 carbon atoms or a non-substituted alkyl or alkylene group having from 1 to about 6 carbon atoms, X is an anionic radical, Z is H, hydrogen atoms or a water soluble cation or cations which together counterbalance the valance of X and a is 0 or 1.
Abstract: A method inhibiting the deposition of silica and silicate compounds on the metallic surfaces of cooling water equipment comprising adding to the water a composition consisting of hydroxyphosphonoacetic acid and a polymer having the formula: ##STR1## wherein M is a water soluble cation. This composition may further comprise a molybdate compound.
Abstract: A process for the detackification and coagulation of oversprayed water-borne and mixed water-borne and oil based paint particles in the water collection system of a paint spray booth comprising adding a unitary blend of an inorganic anion and a cationic polymer selected from the group consisting of polydiallyl dimethyl ammonium chloride, a condensation product of dimethylamine plus epichlorohydrin and a condensation product of dimethylamine plus ethylene diamine plus epichlorohydrin.
Abstract: In a paint spray booth wherein water is used to collect oversprayed paint, a process for detackifying and coagulating the oversprayed paint by the addition of specific amounts of specific anions and cationic polymers blended prior to addition to the water system.
Abstract: In a papermaking operation which utilizes secondary fiber furnish containing hot melt or pressure sensitive adhesive contaminants, a method of inhibiting stickies comprising adding to the pulp slurry at least one surfactant selected from the group consisting of fatty alkanolamides and ethoxylated compounds in addition to a hydrocarbon solvent.
Abstract: A water soluble terpolymer useful in controlling deposition of scale in aqueous systems comprised of monomeric repeat units (g), (h) and (i) wherein repeat unit (g) comprises the structure ##STR1## wherein E is the repeat unit obtained after polymerization of an .alpha.,.beta. ethylenically unsaturated compound, wherein repeat unit (h) comprises the structure ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and denote H, methyl or ethyl and M is a water soluble cation or H, andwherein repeat unit (i) comprises the structure ##STR3## wherein R.sub.3 is H or a lower alkyl (C.sub.1 -C.sub.3), R.sub.4 is a hydroxy substituted alkyl or alkylene group having from 1 to about 6 carbon atoms or a non-substituted alkyl or alkylene group having from 1 to about 6 carbon atoms, X is an anionic radical, Z is H, hydrogen atoms or a water soluble cation or cations which together counterbalance the valance of X and a is 0 or 1.
Abstract: A method for inhibiting the corrosion of copper or copper-bearing metals in contact with an aggressive aqueous environment by combining a copper corrosion inhibitor with a chelant. Azoles are employed as the corrosion inhibitor. Characteristic chelants include ethylenediamine tetracetic acid nitrilotriacetic acid, citric acid, tartaric acid and dialkyldithiocarbamates.
Abstract: This invention relates to processes and compositions for stabilizing distillate fuel oil which comprises adding to the distillate fuel oil an effective stabilizing amount of a mixture of (a) a phosphite compound having the formula ##STR1## wherein R, R' and R" are the same or different and are alkyl, aryl, alkaryl or aralkyl groups, and (b) an effective carboxylic acid having from 2 to about 20 carbon atoms, wherein the weight ratio of (a):(b) is from about 1:5 to aboug 1000:1.
Abstract: A composition and method for improving the removal of corrosive contaminants from crude oil within the desalter in a petroleum refinery. An amine is added to the wash water or to the crude oil prior to processing in the desalter. The amine maximizes the yield of wash water removed from the desalter and substantially improves the removal of acid generating corrosive elements.The addition of the amine upstream of the desalter results in the removal of a significant amount of corrosive chlorides from the crude oil before it is passed through the fractionating unit and other refinery operations. Furthermore, the avoidance of adding metals and the assistance in removing other metals from the crude system aids in the reduction or elimination of downstream fouling and petroleum catalyst poisoning.