Patents Represented by Attorney Gwenetta Douglas Hill
  • Patent number: 4302200
    Abstract: A process for the extraction of an anthocyanin-type color from a natural product which comprises bringing the natural product containing said color into contact with a sulfite ion-containing aqueous solution at a temperature of 85.degree. C. or higher for 30 minutes or less, at which time the sulfite ion content of said aqueous solution firstly contacting the natural product is adjusted to at least 10,000 ppm in terms of SO.sub.2.
    Type: Grant
    Filed: June 3, 1980
    Date of Patent: November 24, 1981
  • Patent number: 4257808
    Abstract: A ferritic cryogenic steel which has a relatively low (about 4-6%) manganese content and which has been made suitable for use at cryogenic temperatures by a thermal cycling treatment followed by a final tempering. The steel includes 4-6% manganese, 0.02-0.06% carbon, 0.1-0.4% molybdenum and 0-3% nickel.
    Type: Grant
    Filed: August 13, 1979
    Date of Patent: March 24, 1981
  • Patent number: 4174263
    Abstract: Bitumen is separated from tar sands by contacting the tar sands with a small amount of liquid, heating the liquid treated tar sands to expand the liquid as a vapor thereby reducing the density of the bitumen and separating the bitumen from the remainder of the tar sands on the basis of density.
    Type: Grant
    Filed: June 28, 1978
    Date of Patent: November 13, 1979
  • Patent number: 4165300
    Abstract: Maleic anhydride and acrylic acid are produced by the oxidation of 1,3-butadiene, n-butylenes, crotonaldehyde and furan with molecular oxygen in the vapor phase in the presence of a catalytic oxide of antimony, molybdenum, vanadium and lithium, cerium, or mixture thereof, wherein the element selected from the group consisting of calcium, iron, tungsten, magnesium, aluminum and nickel is optionally added as a reducing agent. The oxidation of 1,3-butadiene in the presence of a catalyst wherein tungsten metal is used as a reducing agent gives especially desirable high yields to maleic anhydride.
    Type: Grant
    Filed: March 21, 1977
    Date of Patent: August 21, 1979
  • Patent number: 4155920
    Abstract: Maleic anhydride is produced by the oxidation of 1,3-butadiene, n-butylenes, crotonaldehyde and furan with molecular oxygen in the vapor phase in the presence of catalytic oxides of antimony, molybdenum, at least one element selected from the group consisting of niobium, zirconium, titanium and tantalum and optionally a reducing agent capable of reducing at least part of the molybdenum in the catalyst to a valence state below +6 selected from the group consisting of hydrazine hydrate, molybdenum, tungsten, magnesium, aluminum, and nickel. This catalyst may optionally contain one or more elements selected from the group consisting of Li, Ag, Ce, Cd, Co, As, Si, Zn, Ge, Bi, Ru, Pt, U, Al and Ni. Especially desirable yields of maleic anhydride are obtained from 1,3-butadiene in the presence of a catalyst wherein molybdenum metal is used as a reducing agent.
    Type: Grant
    Filed: April 4, 1977
    Date of Patent: May 22, 1979
  • Patent number: 4146733
    Abstract: Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, arsenic, at least one element selected from the group consisting of Ag, Rh, Ru, and Au, oxygen, and optionally, at least one of Cd, Pt, Tl, Pd, Al, Ge, Cu, Ni, alkaline earth metal, NH.sub.4 and Cl.
    Type: Grant
    Filed: March 14, 1977
    Date of Patent: March 27, 1979
  • Patent number: 4139719
    Abstract: Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, arsenic, at least one element selected from the group consisting of U, Ti, Nb, Re, Pb, Zn, and Ga, oxygen, and optionally, at least one of Cu, a rare earth element, Ag, Ta, In, Th, Cd, Tl, alkaline earth metal, NH.sub.4, Cl, Ni, Al and Ge.
    Type: Grant
    Filed: January 31, 1977
    Date of Patent: February 13, 1979
  • Patent number: 4136110
    Abstract: Methacrylic acid or acrylic acid is produced by the oxidation of methacrolein or acrolein respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum and phosphorus, promoted with chromium or at least one element selected from the group consisting of thallium, rubidium, cesium, potassium, titanium, and arsenic, or a mixture thereof, wherein at least part of the molybdenum employed in the preparation of the catalyst is supplied in the form of molybdenum trioxide. The oxidation of methacrolein in the presence of a catalyst wherein all the molybdenum employed in the preparation of the catalyst has been supplied by molybdenum trioxide gives especially desirable high yields and selectivities to methacrylic acid.
    Type: Grant
    Filed: January 31, 1977
    Date of Patent: January 23, 1979
  • Patent number: 4120876
    Abstract: Maleic anhydride is produced by the oxidation of n-butane, n-butenes, 1,3-butadiene or mixture thereof with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, arsenic, oxygen, and at least one element selected from the group consisting of Sn, rare earth metal, Zr, Rh, Mn, Re, Ru, Cu, Pb, Zn, Ti and Cr, Nb, Al, Ga, and alkaline earth metal.
    Type: Grant
    Filed: October 19, 1976
    Date of Patent: October 17, 1978
  • Patent number: 4113768
    Abstract: Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, bismuth, copper, oxygen, optionally a halogen selected from the group consisting of chlorine, bromine or iodine, and optionally, at least one element selected from the group consisting of Fe, Cr, Ni, Mn, Sb, Te, Rh, and Pd.
    Type: Grant
    Filed: December 6, 1976
    Date of Patent: September 12, 1978
  • Patent number: 4110369
    Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.
    Type: Grant
    Filed: October 19, 1976
    Date of Patent: August 29, 1978
  • Patent number: 4097501
    Abstract: Very desirable temperature control and selectivity are obtained in the oxidation of benzene to maleic anhydride using an oxidation catalyst of an essentially inert support of at least 20 microns containing on its outer surface a coating of a catalytically active oxide material or a catalytically active oxide material and an oxide support.
    Type: Grant
    Filed: May 19, 1976
    Date of Patent: June 27, 1978
  • Patent number: 4093635
    Abstract: Maleic anhydride is produced by the oxidation of n-butane, n-butenes, 1,3-butadiene with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, bismuth, copper, oxygen, and a halogen selected from the group consisting of chlorine, bromine or iodine.
    Type: Grant
    Filed: October 19, 1976
    Date of Patent: June 6, 1978
  • Patent number: 4089870
    Abstract: Maleic anhydride is produced by the oxidation of n-butane, n-butenes, 1,3-butadiene or mixture thereof with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, rubidium, oxygen, and at least one element selected from the group consisting of Sn, rare earth element, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co and Cu.
    Type: Grant
    Filed: October 21, 1976
    Date of Patent: May 16, 1978
  • Patent number: 4087446
    Abstract: Maleic anhydride is produced by the oxidation of n-butane, n-butenes, 1,3-butadiene or mixture thereof with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, oxygen, and at least one element selected from the group consisting of As, Rb, Pd, Cd, Cs, Tl and In.
    Type: Grant
    Filed: October 21, 1976
    Date of Patent: May 2, 1978
  • Patent number: 4085121
    Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.
    Type: Grant
    Filed: April 4, 1977
    Date of Patent: April 18, 1978
  • Patent number: 4083805
    Abstract: Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, bismuth, copper, oxygen, a halogen selected from the group consisting of chlorine, bromine or iodine, and optionally, at least one element selected from the group consisting of Fe, Cr, Ni, Mn, Sb, Te, Rh, and Pd.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: April 11, 1978
  • Patent number: 4076731
    Abstract: Phthalic anhydride is prepared by the oxidation of ortho-xylene with molecular oxygen at a temperature of about 200.degree. to about 600.degree. C. in the presence of an oxidation catalyst that comprises an essentially inert support having a strongly-adhering coat of a catalytic composition containing an oxide of vanadium wherein the concentration of vanadium is less than 10%.
    Type: Grant
    Filed: November 12, 1976
    Date of Patent: February 28, 1978
  • Patent number: 4075124
    Abstract: Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, arsenic, at least one element selected from the group consisting of Ag, Rh, Ru, and Au, oxygen, and optionally, at least one of Cd, Pt, Tl, Pd, Al, Ge, Cu, Ni, alkaline earth metal, NH.sub.4 and Cl.
    Type: Grant
    Filed: October 19, 1976
    Date of Patent: February 21, 1978
  • Patent number: 4075231
    Abstract: Phthalic anhydride is prepared by the oxidation of ortho-xylene with molecular oxygen at a temperature of about 200.degree. to about 600.degree. C. in the presence of an oxidation catalyst that comprises an essentially inert support having a strongly-adhering coat of a catalytic composition containing an oxide of vanadium wherein the concentration of vanadium is less than 10%.
    Type: Grant
    Filed: November 12, 1976
    Date of Patent: February 21, 1978