Patents Represented by Attorney Hazel L. Deming
  • Patent number: 4115377
    Abstract: Mixed strontium-cadmium salts of the monoazo dyestuff ##STR1## having a gram atom ratio of strontium to cadmium from 1:1 to 5:1 are described. The mixed salts give red pigments which have excellent color and possess good lightfastness and heat stability.
    Type: Grant
    Filed: January 31, 1977
    Date of Patent: September 19, 1978
    Assignee: Hercules Incorporated
    Inventor: Richard Knight Putney
  • Patent number: 4113508
    Abstract: The production of iron blue pigment compositions by a flushing process has been found to be improved by carrying out the flushing step in the presence of an amine flushing agent and incorporating into the composition during or after flushing at least one surfactant of the polyoxyethylene type. The resulting iron blue compositions have improved consistency and dispersibility in printing inks, paints and the like.
    Type: Grant
    Filed: June 23, 1977
    Date of Patent: September 12, 1978
    Assignee: Hercules Incorporated
    Inventors: Johan Jozef Einerhand, Leonardus Johannes Hubertus Erkens, Rene Johannes Laenen, Joseph Wilhelmus Jacobus Hoofs
  • Patent number: 4098949
    Abstract: Metallizing compositions suitable for the production of fired on electrically conductive films which do not adversely affect the overall strength of heat resistant substrates are described. The compositions comprise, in specified proportions, at least one finely divided electrically conductive metal, certain alkali metal, crystallizable, high silica glass frits as binder, inert liquid vehicle and, if desired, inert filler and/or pigment. The compositions are particularly suited to glass substrates and provide therewith composite structures having greater strength than that of the glass substrate.
    Type: Grant
    Filed: December 13, 1976
    Date of Patent: July 4, 1978
    Assignee: Hercules Incorporated
    Inventor: Raymond Stanley Kosiorek
  • Patent number: 4079026
    Abstract: Printing inks and particularly fluorescent colored inks which provide outstanding color strength and dot resolution with planographic and letterpress printing processes are described. The inks comprise an intimate dispersion of colored resin particles in a vehicle containing specified amounts of certain alkyd resins, esters of modified rosin, carboxylated hydrocarbon resins and ink oil.
    Type: Grant
    Filed: June 20, 1977
    Date of Patent: March 14, 1978
    Assignee: Hercules Incorporated
    Inventor: John Gregory Mone
  • Patent number: 4077973
    Abstract: Metal phthalocyanines having a narrow particle size distribution are synthesized via the phthalodinitrile or phthalic anhydride-urea route using hexachlorobutadiene as the diluent. Higher yields and shorter reaction times are also realized by carrying out the syntheses in this manner.
    Type: Grant
    Filed: April 7, 1976
    Date of Patent: March 7, 1978
    Assignee: Hercules Incorporated
    Inventors: Gerardus Johannes Baptist Colbers, Johan Jozef Einerhand, Leonardus Johannes Hubertus Erkens, Hubertus Bartholomeus Nicola, Jacobus Michiel Hubertus Snijders
  • Patent number: 4056402
    Abstract: Dry, non-dusting pigment compositions which are water-dispersible and which develop good strength and color values upon stirring in water-borne industrial finish systems are described. The pigment compositions contain 55 to 80% pigment and, by weight of the pigment, from 15 to 45% of certain nonionic dispersing agents and from 10 to 67% of at least one water-soluble cellulose ether which is nonionic in nature and has a viscosity of less than 1000 cps. as measured on a 2% aqueous solution at 25.degree. C. The pigment compositions are preferably prepared by milling the pigment in water in the presence of the nonionic dispersing agent, mixing the milled pigment dispersion with the cellulose ether and then removing the water from the resulting mixture.
    Type: Grant
    Filed: August 24, 1976
    Date of Patent: November 1, 1977
    Assignee: Hercules Incorporated
    Inventor: John Guzi, Jr.
  • Patent number: 4054465
    Abstract: Lead chromate-containing pigments having improved dispersibility, heat stability and resistance to abrasion in thermoplastic systems are described. The improved pigments of this invention comprise silica coated lead chromate-containing pigment particles having absorbed on their coated surfaces from 1 to 15% based on the weight of the coated particles of certain liquid organopolysiloxanes. The pigments are produced by contacting silica-coated lead chromate-containing pigment particles with the desired amount of the liquid organopolysiloxane and recovering the resulting particles, both of the contacting and recovery steps being carried out under conditions which do not effect substantial polymerization or curing of the organopolysiloxane.
    Type: Grant
    Filed: September 29, 1976
    Date of Patent: October 18, 1977
    Assignee: Hercules Incorporated
    Inventor: Bernard George Ziobrowski
  • Patent number: 4046588
    Abstract: A process for the production of lead sulfochromate or lead chromate-sulfate-molybdate type pigments having a low content of acid soluble lead, good color and tinting properties and excellent resistance to industrial environments is described. The process comprises forming the desired lead chromate-containing precipitate in acidic aqueous medium containing chloride ions and a specified excess of lead ions in the absence of a pH buffering agent, coating the precipitate with a silicon and antimony compound, adjusting the pH of the medium to below 7 and recovering the coated precipitate as a pigment.
    Type: Grant
    Filed: August 24, 1976
    Date of Patent: September 6, 1977
    Assignee: Hercules Incorporated
    Inventors: Johan Jozef Einerhand, Gerardus Johannes Baptist Colbers, Wilhelmus Martha Andreas Huck, Herman Jozef Johannes Maria Geurts
  • Patent number: 4043824
    Abstract: Ceramic color compositions which are moisture or steam settable are described. The compositions are formulated from a dispersion of ceramic pigments or glass colors in certain moisture or steam set type vehicles and can be applied to green or bisque ceramic ware using standard decorating techniques and then set to a coating by exposure to moisture or steam. Over-glazing of the coating provides decoratively glazed ware of excellent quality and durability.
    Type: Grant
    Filed: August 4, 1975
    Date of Patent: August 23, 1977
    Assignee: Hercules Incorporated
    Inventor: Nelson William Wagar
  • Patent number: 4041194
    Abstract: Hot melt decorative coating compositions for glassware are described. The coating compositions contain 50 to 80% of non-vitrifiable filler which preferably contains at least one pigment intimately dispersed in 50 to 20% of water-insoluble vehicle having a melt softening point range from 45.degree. to 65.degree. C. The vehicle contains as essential ingredients from 5 to 75% of at least one normally solid C.sub.14.sub.-32 alcohol and 7 to 55% of certain polystyrenes and can also contain, if desired, up to 55% of paraffin wax, up to 40% of certain polyalkylene glycols, and up to 20% of specific lower alkyl acrylate polymers.
    Type: Grant
    Filed: September 29, 1975
    Date of Patent: August 9, 1977
    Assignee: Hercules Incorporated
    Inventor: Kennedy A. Jenkins
  • Patent number: 4038115
    Abstract: Mechanical properties of composite modified double-base propellant are improved by coating fillers for the propellant with a crosslinked, binder insoluble coating having reactive surface isocyanate groups. The reactive isocyanate groups become chemically bound to the nitrocellulose binder of the propellant during propellant cure. Failure of the propellant at the binder-filler interface under conditions of stress is substantially reduced.
    Type: Grant
    Filed: October 7, 1969
    Date of Patent: July 26, 1977
    Assignee: Hercules Incorporated
    Inventor: Henry C. Dehm
  • Patent number: 4029605
    Abstract: Metallizing compositions suitable for the production of fired on electrically conductive films which do not adversely affect the overall strength of heat resistant substrates are described. The compositions comprise, in specified proportions, at least one finely divided electrically conductive metal, certain alkali metal, crystallizable, high silica glass frits as binder, inert liquid vehicle and, if desired, inert filler and/or pigment. The compositions are particularly suited to glass substrates and provide therewith composite structures having greater strength than that of the glass substrate.
    Type: Grant
    Filed: December 8, 1975
    Date of Patent: June 14, 1977
    Assignee: Hercules Incorporated
    Inventor: Raymond Stanley Kosiorek
  • Patent number: 4009128
    Abstract: An improved process for the polymerization of epoxides with an organoaluminum catalyst is described. Improvements in conversion, yield and reaction rate are realized by contacting the epoxide at a temperature below 0.degree. C. with at least a catalytic amount of the organoaluminum compound in the presence of at least 0.1 mole, per mole of aluminum, of a perhalogenated aliphatic monoketone which is preferably hexafluoroacetone.
    Type: Grant
    Filed: January 14, 1975
    Date of Patent: February 22, 1977
    Assignee: Hercules Incorporated
    Inventor: Edwin J. Vandenberg
  • Patent number: 4002593
    Abstract: A process for producing essentially agglomerate free intimate dispersions of at least 10 weight % of pigment in condensation type polymers is described. The process is carried out by forming a liquid dispersion of pigment particles having a size less than 3 microns in certain hydrocarbon diluents, adding the liquid dispersion to a melt of the polymer, mixing the dispersion and polymer under molten conditions until the pigment transfers from the diluent phase to the polymer phase, removing the diluent phase and recovering the pigment-polymer phase.
    Type: Grant
    Filed: July 17, 1975
    Date of Patent: January 11, 1977
    Assignee: Hercules Incorporated
    Inventor: Marlene J. Jones
  • Patent number: 3991044
    Abstract: A process for improving the light-fastness of pigments of the Hansa Yellow and Diarylide Yellow class is described. Azo pigments prepared by coupling diazotized primary aromatic monoamines or tetrazotized primary aromatic diamines with acetoacetarylides in aqueous medium in the absence of surfactants are heated prior to or after separation from the aqueous medium at 120.degree. to about 250.degree. C. until the pigment is converted to crystalline particles having an average particle diameter at least twice that of the pigment which has not been heat treated.
    Type: Grant
    Filed: September 26, 1972
    Date of Patent: November 9, 1976
    Assignee: Hercules Incorporated
    Inventor: Joseph William Conley
  • Patent number: 3982975
    Abstract: The invention provides epoxy cured rubber based propellants containing one or more N,N'-dialkyl- and/or diarylphenylenediamines chemically locked in the polymeric network to impart improved resistance to oxidative hardening of the propellant surface and inner structure.
    Type: Grant
    Filed: June 4, 1968
    Date of Patent: September 28, 1976
    Assignee: Hercules Incorporated
    Inventors: Donald E. Elrick, Harry Gilbert
  • Patent number: 3948698
    Abstract: Solid propellant compositions wherein the polymeric binder is an all-epoxide cured carboxy-terminated rubber are described. A typical composition contains oxidizer, fuel and a binder formed by curing a carboxy-terminated polybutadiene with a specified mixture of a diepoxide and triepoxide using chromium 2-ethylhexanoate as catalyst.
    Type: Grant
    Filed: September 6, 1967
    Date of Patent: April 6, 1976
    Assignee: Hercules Incorporated
    Inventors: Donald E. Elrick, Harry Gilbert
  • Patent number: 3936315
    Abstract: A salt grinding process is described for converting crude phthalocyanines into pigments having improved strength, cleanliness and transparency. The process is carried out by grinding an anhydrous charge of dry phthalocyanine crude, salt grinding aid, organic liquid conditioning agent and a specified amount of an alkali metal hydroxide under conditions of shear and then recovering the pigment from the charge. The process is particularly useful for crudes of unsubstituted or halogen substituted copper phthalocyanines.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: February 3, 1976
    Assignee: Hercules Incorporated
    Inventors: Richard Milledge Ferrill, Jr., Louis John Gagliano