Patents Represented by Attorney, Agent or Law Firm Henry E. Naylor
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Patent number: 6114265Abstract: Disclosed is a process for controlling combustion in a fluid catalytic cracking regenerator. More specifically, afterburning which occurs during the combustion process is controlled by adjusting oxygen concentration in at least one of two combustion streams which is injected into a fluid catalytic cracking regenerator. Preferably, the combustion streams used in the invention are asymmetrically injected into a dense phase catalyst bed within the regenerator.Type: GrantFiled: March 15, 1994Date of Patent: September 5, 2000Assignee: Exxon Research and Engineering CompanyInventors: Todd R. Steffens, Paul K. Ladwig
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Patent number: 6106697Abstract: C.sub.2 to C.sub.4 olefins are selectively produced from a gas oil or resid in a two stage process. The gas oil or resid is reacted in a first stage comprised of a fluid catalytic cracking unit wherein it is converted in the presence of conventional large pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage comprised of a process unit containing a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia.Type: GrantFiled: May 5, 1998Date of Patent: August 22, 2000Assignee: Exxon Research and Engineering CompanyInventors: George A. Swan, Michael W. Bedell, Paul K. Ladwig, John E. Asplin, Gordon F. Stuntz, William A. Wachter, Brian Erik Henry
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Patent number: 6103106Abstract: A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.Type: GrantFiled: June 7, 1999Date of Patent: August 15, 2000Assignee: Exxon Research and Engineering CompanyInventors: Gary B. McVicker, James J. Schorfheide, William C. Baird Jr., Michele S. Touvelle, Michel Daage, Darryl P. Klein, Edward S. Ellis, David E.W. Vaughan, Jingguang Chen, Sylvain S. Hantzer
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Patent number: 6103104Abstract: A process for hydroprocessing middle distillate petroleum streams in two temperature stages. The feedstream is hydroprocessed in two or more first temperature stages operated at a temperature from about 360.degree. C. to about 450.degree. C. The reaction product of the first temperature stage(s) is quenched to a temperature from about 260.degree. C. to about 350, stripped of H.sub.2 S, NH.sub.3 and other dissolved gases, then sent to the second temperature stage which is operated at said quenched temperature range. The product from the second temperature stage is also stripped of dissolved gases. Color bodies produced in the higher temperature first stage are hydrogenated in the last stage.Type: GrantFiled: May 7, 1998Date of Patent: August 15, 2000Assignee: Exxon Research and Engineering CompanyInventor: Ramesh Gupta
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Patent number: 6093435Abstract: A process for removing fat substitutes from food products containing same, particularly fried food products, such as potato chips. The method involves treating a fat substitute-containing food product with an effective solvent at effective temperatures and pressures, then separating the fat substitute-laden solvent from the food product now having reduced fat substitute content.Type: GrantFiled: November 3, 1995Date of Patent: July 25, 2000Assignee: University Research & MarketingInventors: Henry L. Franke, Henry E. Naylor, Neelam Misal
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Patent number: 6093867Abstract: A process for selectively producing C.sub.3 olefins from a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500.degree. to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.Type: GrantFiled: May 5, 1998Date of Patent: July 25, 2000Assignee: Exxon Research and Engineering CompanyInventors: Paul K. Ladwig, John Ernest Asplin, Gordon F. Stuntz, Tan-Jen Chen
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Patent number: 6087544Abstract: A process for producing distillate fuels, such as diesel fuels and jet fuels having both high lubricity and low sulfur levels. Such fuels are produced by fractionating a distillate feedstream into a light fraction which is relatively low in lubricity and which contains from about 50 to 100 wppm of sulfur and a heavy fraction having a relatively high lubricity. The first fraction is hydrotreated to remove substantially all of the sulfur and is then blended with the second fraction to produce a distillate fuel product having relatively low sulfur levels and a relatively high lubricity.Type: GrantFiled: May 7, 1998Date of Patent: July 11, 2000Assignee: Exxon Research and Engineering Co.Inventors: Robert J. Wittenbrink, Darryl P. Klein, Michele S. Touvelle, Michel Daage, Paul J. Berlowitz
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Patent number: 6069287Abstract: A process for selectively producing C.sub.2 -C.sub.4 olefins from a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500 to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia.Type: GrantFiled: May 5, 1998Date of Patent: May 30, 2000Assignee: Exxon Research and Engineering Co.Inventors: Paul K. Ladwig, John Ernest Asplin, Gordon F. Stuntz, William A. Wachter, Brian Erik Henry
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Patent number: 6054113Abstract: A method for preparing novel zeolitic catalyst compositions having a high Si/Al ratio and a crystallinity of at least about 70%. The method involves cation exchanging an as synthesized faujasite material having an Si/Al greater than about 4 with a component selected from the group consisting of ammonium ions and mineral acids, then steam calcining said cation exchanged faujasite in a single steam calcination step at a temperature from about 900.degree. F. to about 1 500.degree. F.Type: GrantFiled: March 17, 1998Date of Patent: April 25, 2000Assignee: Exxon Research and Engineering Co.Inventors: David E. W. Vaughan, Karl G. Strohmaier, Gary B. McVicker, Owen C. Feeley
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Patent number: 6054041Abstract: A hydroprocessing process includes two cocurrent flow liquid reaction stages and one vapor stage, in which feed components are catalytically hydroprocessed by reacting with hydrogen. The liquid stages both produce a liquid and a hydrogen-rich vapor effluent, with most of the hydroprocessing accomplished in the first stage. The first stage vapor is also hydroprocessed. The hydroprocessed vapor and second stage vapor are cooled to condense and recover additional product liquid and produce an uncondensed hydrogen-rich vapor. After cleanup to remove contaminants, the hydrogen-rich vapor is recycled back into the first stage as treat gas. Fresh hydrogen is introduced into the second stage. This is useful for hydrotreating heteroatom-containing hydrocarbons.Type: GrantFiled: May 6, 1998Date of Patent: April 25, 2000Assignee: Exxon Research and Engineering Co.Inventors: Edward S. Ellis, William Ernest Lewis, David C. Dankworth, Ramesh Gupta
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Patent number: 6036844Abstract: A three stage hydroprocessing process includes two liquid and one vapor reaction stages, with a hydrogen containing vapor effluent produced in both liquid stages. The second liquid stage vapor effluent comprises part of the first liquid stage feed and the first liquid stage vapor effluent is the feed for the vapor stage. At least a portion of the hydrogen for the first liquid stage and vapor stage reactions is respectively provided by the hydrogen in the second and first liquid stage vapor effluents.Type: GrantFiled: May 6, 1998Date of Patent: March 14, 2000Assignee: Exxon Research and Engineering Co.Inventors: Ramesh Gupta, Henry Jung, Edward S. Ellis, Gerald E. Markley
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Patent number: 6013598Abstract: The present invention relates to catalysts for hydrodesulfurizing naphtha streams. The catalysts are comprised of a suitable support material, and about 1 to about 10 wt. % MoO.sub.3, about 0.1 to about 5 wt. % CoO supported on a suitable support material. They are also characterized as having an average medium pore diameter from about 60 .ANG. to 200 .ANG., a Co/Mo atomic ratio of about 0.1 to about 1.0, a MoO.sub.3 surface concentration of about 0.5.times.10.sup.-4 to about 3.0.times.10.sup.-4 g MoO.sub.3 /m.sup.2, and an average particle size of less than about 2.0 mm in diameter.Type: GrantFiled: December 12, 1997Date of Patent: January 11, 2000Assignee: Exxon Research and Engineering Co.Inventors: Mark P. Lapinski, Kenneth L. Riley, Clyde L. Aldridge, Michele S. Touvelle
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Patent number: 6007787Abstract: A reaction vessel for processing liquid petroleum or chemical streams wherein the stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one interaction zone. The reaction vessel contains vapor, and optionally liquid, passageways to bypass one or more packed beds, preferably catalyst beds. This permits more stable and efficient vessel operation.Type: GrantFiled: August 23, 1996Date of Patent: December 28, 1999Assignee: Exxon Research and Engineering Co.Inventors: Ramesh Gupta, David C. Dankworth, Dennis D. Fleming, Edward S. Ellis, James J. Schorfheide
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Patent number: 5998676Abstract: A process for the conversion of a picrate salt, preferably ammonium pricrate, to picric acid by acidifying the picrate salt in a two phase liquid system. One phase is an aqueous phase which contains an acid which is effective for acidifying ammonium picrate to picric acid and the other phase is an organic solvent phase in which the picric acid is soluble.Type: GrantFiled: September 9, 1998Date of Patent: December 7, 1999Assignee: Gradient TechnologyInventors: Kym B. Arcuri, Dwayne A. Goetsch
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Staged upflow hydroprocessing with noncatalytic impurity removal from the first stage vapor effluent
Patent number: 5989411Abstract: A hydroprocessing process for removing impurities from a feed comprising a hydrocarbonaceous liquid comprises at least two cocurrent, upflow hydroprocessing reaction stages and a non-catalytic, vapor-liquid contacting stage. The reaction and contacting stages may all be in the same reactor vessel. The feed and a hydrogen treat gas are passed up into a catalyst bed which comprises the first reaction stage, which produces a partially hydroprocessed liquid and vapor effluent. This first stage vapor is passed up into the contacting stage in which it contacts a hydrocarbonaceous liquid which reduces the vapor impurity content. The impurity-enriched contacting liquid passes down and mixes with the first stage liquid effluent. The combined effluents and hydrogen are passed up into the second reaction stage to form a processed product liquid and hydrogen-containing vapor effluent.Type: GrantFiled: October 23, 1998Date of Patent: November 23, 1999Assignee: Exxon Research and Engineering CompanyInventor: Ramesh Gupta -
Patent number: 5990354Abstract: Ammonium picrate, Explosive "D", is converted to picric acid, which is then converted to triaminophenol by the conversion of the aromatic nitro groups to amino groups. The triaminophenols are then converted to triaminobenzenes by the removal of the hydroxyl groups and the triaminobenzenes are converted to m-phenylenediamine, aniline, and primary aliphatic amines by the removal of amino groups.Type: GrantFiled: November 17, 1998Date of Patent: November 23, 1999Assignee: Gradient TechnologyInventors: Duane A. Goetsch, Kym B. Arcuri
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Patent number: 5985131Abstract: A process for upgrading a liquid petroleum or chemical stream wherein said stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one reaction zone. The reaction vessel used in the practice of the present invention contains vapor and optionally liquid passageway means to bypass one or more catalyst beds. This permits more stable and efficient reaction vessel operation.Type: GrantFiled: August 23, 1996Date of Patent: November 16, 1999Assignee: Exxon Research and Engineering CompanyInventors: Ramesh Gupta, David C. Dankworth, Dennis D. Fleming, Edward S. Ellis, James J. Schorfheide
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Patent number: 5985136Abstract: A process for hydrodesulfurizing naphtha feedstreams wherein the reactor inlet temperature is below the dew point of the feedstock at the reactor inlet so that the naphtha will completely vaporize within the catalyst bed. It is preferred to use a catalyst comprised of about 1 to about 10 wt. % MoO.sub.3, about 0.1 to about 5 wt. % CoO supported on a suitable support material. They are also characterized as having an average medium pore diameter from about 60 .ANG. to 200 .ANG.. a Co/Mo atomic ratio of about 0.1 to about 1.0, a MoO.sub.3 surface concentration of about 0.5.times.10.sup.-4 to about 3.0.times.10.sup.-4 g MoO.sub.3 /m.sup.2, and an average particle size of less than about 2.0 mm in diameter.Type: GrantFiled: June 18, 1998Date of Patent: November 16, 1999Assignee: Exxon Research and Engineering Co.Inventors: Garland B. Brignac, Jeffrey L. Kaufman, John C. Coker
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Patent number: 5985135Abstract: A hydroprocessing process for removing impurities from a feed comprising a hydrocarbonaceous liquid comprises at least one cocurrent, upflow hydroprocessing reaction stage, a vapor-liquid contacting stage and a downflow hydroprocessing reaction stage. The feed and hydrogen react in the upflow stage to produce a partially hydroprocessed liquid and vapor effluent. The vapor contacts a hydrocarbonaceous liquid in the contacting stage, which transfers impurities from the vapor into the liquid. The impurity-enriched contacting liquid mixes with the upflow stage liquid effluent and the combined liquid effluents react with hydrogen in the downflow reaction stage, to form a hydroprocessed product liquid and vapor effluent. Additional product liquid is recovered by cooling and condensing either or both the contacting and downflow stage vapor effluents.Type: GrantFiled: October 23, 1998Date of Patent: November 16, 1999Assignee: Exxon Research and Engineering Co.Inventor: Ramesh Gupta
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Patent number: 5968346Abstract: A hydroprocessing process includes two hydroprocessing reaction stages, both of which produce a liquid and a vapor effluent, and a liquid-vapor contacting stage. The first stage vapor effluent contains impurities, such as heteroatom compounds, which are removed from the vapor by contact with processed liquid effluent derived from one or both reaction stages and, optionally, also liquid recovered from processed vapor. The first and contact stage liquid effluents are passed into the second stage to finish the hydoprocessing. The contact and second stage vapor effluents are cooled to recover additional hydroprocessed product liquid.Type: GrantFiled: September 16, 1998Date of Patent: October 19, 1999Assignee: Exxon Research and Engineering Co.Inventors: Henry Jung, Ramesh Gupta, Edward S. Ellis, William E. Lewis