Abstract: A waterbased coating composition containing about 10-30% by weight of film forming binder dispersed in an aqueous carrier; wherein the binder contains abouta. 60-90% by weight, based on the weight of the binder, of a methylol (meth)acrylamide acrylic polymer of polymerized monomers of alkyl methacrylate, alkyl acrylate or mixtures thereof, 1-10% by weight, based on the weight of the acrylic polymer, of methylol methacrylamide, methylol acrylamide or mixtures thereof, 0.5-10% by weight, based on the weight of the acrylic polymer, of an ethylenically unsaturated carboxylic acid, 0.5-10% by weight, based on the weight of the acrylic polymer, of an ethylenically unsaturated hydroxyl containing monomer and the acrylic polymer has a glass transition temperature of -40 to +40C and a weight average molecular weight of 500,000 to 3,000,000; and the carboxyl groups of the carboxylic acid are reacted with ammonia to provide a pH to the composition of about 7.0-10.0;b.

Abstract: A process for making a rigid composite structure with a thermoplastic polymer surface by:a. thermoforming a thermoplastic polymeric sheet into a three dimensional structure; the sheet has primary glass transition temperature that is at least 10.degree. C. greater than the molding temperature of step c. below;b. placing the thermoformed structure and a charge of sheet molding compound (SMC) in a mold andc. heating the charge and thermoformed structure under pressure in the mold to cure the SMC and to adhere the SMC to the thermoformed structure, where the molding temperature is at least 10.degree. C. below the primary glass transition temperature of the thermoplastic polymeric sheet;the resulting composite structure which can be finished with a paint or a layer of clear coat and color coat also is part of the invention.

Abstract: A process for forming a composite that is useful as an exterior vehicle part in which a layer of a coating composition is applied to a flexible smooth glossy polymeric carrier sheet and dried and laminated under heat and pressure to a flexible polymeric substrate to form a laminate, the carrier sheet is removed and the laminate is thermoformed into a three dimensional structure and a rigid thermoformable plastic is adhered to the thermoformed laminate to form the composite; the coating compsition used in the process that forms the exterior finish on the composite has a film forming binder which is in an organic liquid carrier is of a polyesterurethane and a multifunctional crosslinking agent of an epoxy compound or an organic polyisocyanate; whereinthe polyesterurethane is formed by reacting a hydroxy functional polyester with a hydroxy containing carboxylic acid and an organic polyisocyanate.

Abstract: An improved process for applying a two component polyurethane coating composition to a substrate; a stream of a polyol having reactive hydroxyl groups is mixed with a stream of an organic polyisocyanate crosslinking agent to form a blend that is applied to the substrate; the improvement used in this process is as follows:adding to the stream of polyol a monohydric primary or secondary alcohol in a ratio of about 0.5-2.0 equivalents of alcohol hydroxyl to polyol hydroxyl before mixing with the stream of organic polyisocyanate and before application to the substrate to prevent or substantially reduce the formation of gel particles;wherein the monohydric primary or secondary alcohol has a 90% evaporation rate at 25.degree. C. of less than 10,000 seconds as determined by ASTM D3539 using an Automatic Shell Thin Film Evaporator.

Abstract: Disclosed herein are cathodic electrodepositable coating baths containing lead cyanamide as a supplementary catalyst. It has been found that using lead cyanamide in conjunction with a primary metal catalyst (e.g. dibutyltin oxide) results in an electrocoat system with superior underbake cure without sacrificing chipping characteristics during overbake cure.

Abstract: A coating composition which cures at ambient temperatures and contains 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder contains about:A. an acrylic polymer A of polymerized monomers of methyl methacrylate and monomers of styrene, alkyl methacrylate and/or alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the polymer backbone aminoester groups, hydroxy aminoester groups or hydroxyamine groups,B. an acrylic crosslinking polymer B of polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent of glycidyl methacrylate or acrylate and the remainder of the monomers are alkyl methacrylate an acrylate each having 1-12 carbon atoms in the alkyl group and optionally contains at least 3% by weight, based on the weight of the crosslinking polymer, of an alkyl methacrylate or acrylate having a pendent group of the formula ##STR1## C.

Abstract: A coating composition which cures at ambient temperatures and contains 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder contains about:A. 60-80% by weight, based on the weight of the binder, of an acrylic polymer A of polymerized monomers of methyl methacrylate and monomers of styrene, alkylmethacrylate and/or alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the polymer backbone aminoester groups, hydroxy aminoester groups or hydroxyamine groups,B.

Abstract: Preparation of a semi-crystalline catalyst for curing coating compositions wherein an isocyanate-sulfonate or -phosphonate is made by a Michael addition followed by chain extension with an isocyanate.

Abstract: A device for measuring the thickness of a wet or dry paint film applied on a substrate without contacting the film is disclosed. The device uses an optical sensor positioned centrally and coaxially with an inductive eddy-current proximity sensor. The optical sensor measures the distance between the device and the upper surface of the paint film at specular reflection angle. The proximity sensor measures the distance between the device and the upper surface of the substrate. The two distances measured, when compared, produce the film thickness value. The device is capable of accurately measuring thickness of various paint films, such as flat, glossy and metal-flake containing paint films.

Abstract: A process for making a rigid composite structure with a thermoplastic polymer surface by:a. thermoforming a thermoplastic polymeric sheet into a three dimensional structure; the sheet has a primary glass transition temperature that is at least 10.degree. C. greater than the molding temperature of step c. below;b. placing the thermoformed structure and a charge of sheet molding compound (SMC) in a mold andc. heating the charge and thermoformed structure under pressure in the mold to cure the SMC and to adhere the SMC to the thermoformed structure, where the molding temperature is at least 10.degree. C. below the primary glass transition temperature of the thermoplastic polymeric sheet;the resulting composite structure which can be finished with a paint or a layer of clear coat and color coat also is part of the invention.

Abstract: A waterbased coating composition containing about 10-30% by weight of film forming binder dispersed in an aqueous carrier; wherein the binder contains abouta. 60-90% by weight, based on the weight of the binder, of a methylol (meth)acrylamide acrylic polymer of polymerized monomers of alkyl methacrylate, alkyl acrylate or mixtures thereof, 1-10% by weight, based on the weight of the acrylic polymer, of methylol methacrylamide, methylol acrylamide or mixtures thereof, 0.5-10% by weight, based on the weight of the acrylic polymer, of an ethylenically unsaturated carboxylic acid, 0.5-10% by weight, based on the weight of the acrylic polymer, of an ethylenically unsaturated hydroxyl containing monomer and the acrylic polymer has a glass transition temperature of -40.degree. to +40.degree. C. and a weight average molecular weight of 500,000 to 3,000,000; and the carboxyl groups of the carboxylic acid are reacted with ammonia to provide a pH to the composition of about 7.0-10.0;b.

Abstract: An automotive and refinish coating containing a curing catalyst which minimizes yellowing of a finish after exposure to weathering wherein the composition has a binder of an acrylic polymer of polymerized monomers of alkyl methacrylate, alkyl acrylate or mixtures thereof and the polymer has pendent aminoester or hydroxy aminoester groups and a glycidyl acrylic crosslinking polymer of polymerized monomers of glycidyl methacrylate or glycidyl acrylate and an alkyl methacrylate or acrylate or mixtures thereof; wherein the catalyst isthe alkyl ester of para hydroxy benzoic acid having 1-4 carbon atoms in the alkyl group.

Abstract: A process for forming a composite useful as an exterior vehicle part that has the following layered components:a. a layer of a glossy clear acrylic thermoplastic finish bonded firmly tob. a layer of an acrylic thermoplastic pigment containing paint firmly bonded toc. a flexible thermoformable polymeric material that is bonded tod. a thick rigid synthetic resinous substrate;The resulting composite and thermoformable laminate that can be made into the above composite having the layers a.-c. of the above structure also are part of this invention.

Abstract: A portable colorimeter for characterizing the optical properties of a colored surface and in particular a colored surface containing metallic or pearlescent particles, which employs three multiangular spectrophotometric measurements to derive color constants for the surface. The colorimeter is a compact integrated unit housing irradiation, detection, control, analysis and display means and employs three illumination angles, preferably -30.degree., 0.degree., and 65.degree., and one detection angle, preferably 45.degree., all measured from the sample normal. The method includes determining the tristimulus values of the color of the sample surface from low resolution spectral reflectance data preferably using twelve detector elements.

Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.

Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.