Abstract: An aqueous emulsion concentrate comprising:A) a water-insoluble oil component;B) at least one hydrophilic nonionic emulsifier;C) at least one lipophilic co-emulsifier; andD) from about 50 to about 70% by weight of water, based on the weight of the concentrate;wherein components A), B) and C) are present in a ratio by weight of A:B:C of 1:(0.31-1.5):(0.31-1.5); and wherein the emulsion concentrate is flowable and pumpable at 20.degree. C.

Abstract: A composition that is useful in the preparation of radiation curable coatings is provided. The composition comprises the reaction product of an epoxy component comprised of a diepoxide and an acid component comprised of an ethylenically unsaturated carboxylic acid or reactive derivative thereof, reacted in the presence of a polyamide based on a polymerized fatty acid. The polyamide preferably has a number average molecular weight of less than about 10,000 g/mole. Also provided is a polymerizable composition comprised of the reaction product and a reactive diluent. A method of coating a substrate is also provided which comprises applying to a substrate a composition comprised of the reaction product and exposing said composition to radiation to cure said composition.

Abstract: Starting from a mixture containing tocopherol, fats and/or fat derivatives, more particularly fatty acids, and optionally sterol and/or sterol derivatives, the free fatty acids present in the mixture are esterified with an alcohol and fatty glycerides are transesterified with an alcohol in the presence of a zinc oxide and/or zinc hydroxide catalyst. After the esterifications, the excess lower alcohol is distilled off from the reaction mixture. The transesterification catalyst and the glycerol present, if any, are removed and the fatty acid alkyl ester is distilled off from the mixture. Distillation of fatty acid alkyl esters can be accomplished with a packed column in sequence with a wiped film evaporator. The simultaneous recovery of tocopherol and sterol is possible. Tocopherols and sterols can be separated by the crystallization of sterols from a blend of organic solvents.

Abstract: The subject matter comprises shaped mixtures of valuable materials for the stimulation and cultivation of plant growth, said materials containing plant nutrients and/or plant-protective agents in admixture with a thermoplastic binder. According to the invention the mixtures of valuable materials, which mixtures have in particular been shaped as fertilizer rods, are characterized in that they contain, as the binder, a starch that has been thermomechanically digested at elevated pressures and temperatures.The invention further relates to the process for producing these multi-component mixtures and to the use of thermomechanically digested starch, optionally in admixture with inferior amounts of further biologically compatible binder components, as a biologically degradable binder for mixtures of valuable materials of the type described.

Abstract: Provided are polymers produced by the process of polymerizing monomers comprised of:(i) an aromatic monomer having the formula CH.sub.2 .dbd.C(R.sup.1)(R.sup.2) wherein R.sup.1 is an aromatic group having from 6 to 10 carbon atoms, and R.sup.2 is hydrogen or methyl,(ii) a long-chain aliphatic monomer having the formula CH.sub.2 .dbd.C(C(O)OR.sup.3)(R.sup.4) wherein R.sup.3 is a fatty alkyl group having from 12 to 22 carbon atoms and R.sup.4 is hydrogen or methyl,(iii) a hardening monomer having the formula CH.sub.2 .dbd.C(C(O)OR.sup.5)(R.sup.6) wherein R.sup.5 is a hardening alkyl group having from 1 to 4 carbon atoms and R.sup.6 is hydrogen or methyl, and(iv) a plasticizing monomer having the formula CH.sub.2 .dbd.C(C(O)OR.sup.7)(R.sup.8) wherein R.sup.7 is a plasticizing alkyl group (preferably having from 3 to 10 carbon atoms) and R.sup.

Abstract: Antimicrobial mixtures containing specific antimicrobial diols, e.g. 1,2-dodecanediol, and specific aromatic alcohols, e.g. phenylethyl alcohol or hydrocinnamic alcohol, are provided. Such mixtures with a weight ratio of diol to aromatic alcohol of 9:1 to 1:9 have been found to exhibit a synergistic effect, i.e. a high antimicrobial activity which cannot be explained by an additive effect of the very low-activity components. Such mixtures are useful in the disinfection of hard surfaces, in the production of disinfectant cleaning preparations and in the preservation of water-based preparations of microbially degradable substances.

Abstract: The invention relates to a process for the production of plastics containing amide groups with elimination of CO.sub.2 by reaction of polyfunctional isocyanates, carboxylic acids and, optionally, alcohols in the presence of tertiary amines, more particularly heteroaromatic amines. The heteroaromatic amines preferably contain another heteroatom and/or substituents having +I and/or +M effects. The reaction preferably starts at room temperature. Fine-cell foams having an acid value of less than 40 and a density of at most 150 g/l can be produced in short reaction times at room temperature without any need for additional blowing agents.

Abstract: Described are moisture-curing sealing and/or adhesive compositions based on alkoxysilane-terminated polyurethanes and containing diurethanes as plasticizers. The diurethanes are prepared either from diol mixtures and mono-functional isocyanates, reacting with substantially all the free hydroxyl groups, or from diisocyanates and mono-functional alcohols, reacting with substantially all the free isocyanate groups. Also described is a method of preparing the moisture-curing sealing and/or adhesive compositions and their use as joint sealants.

Abstract: A flexible packaging printing ink is formulated from a resin binder (e.g. an alcohol soluble polyamide or a water-dispersible polyacrylate), pigment, solvent (e.g. a lower alkanol or water), and an alkyl polyglycoside surfactant. Related methods, compositions and articles are also provided. A method of preparing a polyamide resin by condensing a dibasic acid mixture with a diamine mixture and melt blending the resin with an alkyl polyglycoside is also provided. These polymers are particularly useful as the binder for a flexible packaging laminating ink composition.

Abstract: Compositions and methods relating to cementitious compositions are provided. The use of a blend of a rosin and a tannin to entrain air into cementitious compositions is provided. A blend of a rosin and a tannin in a weight ratio of about 1:1.22 to about 1:1.86 are added to a wet cementitious composition at levels of less than 1% by weight based on the weight of the cement and air is mixed into the cement. The resulting cement will contain, e.g. 5% to 10% by volume air which improves the resistance of the set cement to freeze damage. Also provided is a method of entraining air into a cementitious composition which employs such a blend.

Abstract: Described are materials based on a starch which has been thermomechanically digested at elevated temperatures and pressures and upon the addition of water and/or lower molecular weight plasticizers and which contains oxidatively cross-linkable alkyd resins having been incorporated in an intimate admixture. Preferably, these alkyd resins have been at least predominantly composed of key substances based on re-growable raw materials.The starch blends thus modified are suitable for the manufacture of shaped articles which in the presence of air will be reactively cured and thereupon are imparted with an increased strength, and especially an increased resistance to water.

Abstract: Chocolate-flavored morsels essentially free of fat and a method for their preparation are provided. The morsels are manufactured by first preparing a mixture comprised of a major amount by weight of an aqueous syrup comprised of a crystallizable saccharide, said aqueous syrup being supersaturated with respect to said crystallizable saccharide, a minor amount by weight of defatted cocoa powder, a minor amount by weight of said crystallizable saccharide in crystalline form, and a minor amount by weight of an instant starch having a cold-water solubility of greater than 50 weight percent (and preferably a fat content of less than 0.25 weight percent), the amount of water in said aqueous syrup being insufficient to dissolve a major portion of said minor amount of instant starch.

Abstract: A method and apparatus for separation of an extract component from a raffinate component in a simulated moving bed chromatographic separation train system. The system includes a plurality of beds, packed with a sorbent material, connected to form a closed recycle loop. Inlets to the train are provided for a feed stream and a desorbent stream along with outlets for removal of a raffinate stream and an extract stream. Increased product throughput and yield are obtained by intermittantly introducing and withdrawing the various streams to the train while continuously recycling a portion of the fluid in the system.

Abstract: A method of preparing a bulking agent useful in the replacement of carbohydrates and/or fats is provided. The bulking agent is comprised of a randomly-bonded polysacchardie prepared from a granular reducing saccharide and a granular edible polyol by means of an apparatus having a vented chamber with means for conveying the ingredients longitudinally through said chamber with lateral mixing of said ingredients and minimal longitudinal mixing of said ingredients.

Abstract: A method for producing anhydrous crystalline fructose by crystallizing from solution is provided. A highly supersaturated aqueous solution of fructose is added to a heel of crystalline fructose and dry seed. The temperature of the solution is then lowered to crystallize fructose from the solution to form a massecuite. The massecuite is divided into a product portion and a heel portion, the product portion being treated to isolated crystalline fructose which is then classified into product cuts on the basis of particle size of the fructose crystals, each product cut having a substantially typical particle size distribution.

Abstract: Methods of preparing and using sweetener syrups comprised of crystalline saccharides are provided. A crystalline saccharide composition comprised of crystalline fructose is dissolved in a potable liquid to form a concentrated syrup. Anhydrous crystalline fructose and/or crystalline fructose dihydrate are used to prepare the syrups. At least about 42% by weight of the crystalline saccharide composition is fructose, the remainder preferably being crystalline dextrose. The use of crystalline saccharides yield color stable syrups especially useful in clear and/or colorless beverages.

Abstract: A cold-water-swellable granular starch which affords aqueous solutions or dispersions having high-viscosity and/or excellent clarity is provided. In one embodiment, the granular starch is made cold-water swellable by contact with aqueous alcohol, then derivatized with an .alpha.-halocarboxylic acid, and then isolated under condition which inhibit esterification of the granular starch, e.g. high pH, to afford a starch that has excellent paste clarity. In other embodiments, the cold-water-swellable granular starch is crosslinked to afford a starch that has very high paste viscosity.

Abstract: A method of manufacturing gel pieces is provided. The gel pieces are prepared from a cooked mixture comprising a thin-boiling starch as a gelling agent and a sweetener system comprising a high fructose corn syrup and a crystalline sweetener comprised of fructose. The cooked mixture is deposited in a plurality of molds and allowed to set to yield gel pieces which can then be packaged in bulk. The use of high fructose corn syrup and a crystalline fructose sweetener yields gel pieces which have excellent resistance to adhesion to hard surface molds and/or one another when packaged in bulk even over a long period of time at elevated storage temperatures.

Abstract: A method of purifying hydrolysed protein compositions by contact with crystalline zeolite agglomerates is provided. A reduction in the concentration of chlorohydrins, measured as 1,3-dichloropropen-2-ol, in hydrolysed protein compositions can be obtained by contacting the hydrolysed protein composition with a crystallin zeolite agglomerate, e.g., as pellets, beads or granules of crystalline zeolite. The method allows removal of chlorohydrins without affecting the organoleptic qualities of the hydrolysed protein.

Abstract: Radiation-curable compositions containing monoalkyl or mono-aralkyl ether di-acrylates or di-methacrylates of particular ethoxylated and/or propoxylated polyols of formulae I and II have been developed. These polyol derivatives substituted with hydrophobic ether functionalities constitute UV-curable diluents that can be isolated in excellent yields with minimal losses during the manufacturing process.