Patents Represented by Attorney, Agent or Law Firm J. Jeffrey Hawley
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Patent number: 7858160Abstract: The present invention relates to an inkjet recording element having very good dye keeping properties in time. Said inkjet recording element comprises a support and at least one ink-receiving layer, said ink-receiving layer comprising at least one hydrosoluble binder and at least one aluminosilicate polymer obtainable by a preparation method consisting in treating an aluminum halide with a mixture of at least one silicon alkoxide only having hydrolyzable substituents and at least one silicon alkoxide having a non-hydrolyzable substituent, with an aqueous alkali in the presence of silanol groups, the aluminum concentration being maintained less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the hybrid aluminosilicate polymer. The ink-receiving layer also comprises inorganic particles.Type: GrantFiled: July 2, 2004Date of Patent: December 28, 2010Assignee: Eastman Kodak CompanyInventors: Gérard A. Friour, Olivier J. Poncelet
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Patent number: 7632555Abstract: The present invention relates to a recording element intended for forming images by inkjet printing having very good colorfastness over time and a good ink drying time. Said recording element comprises a support and at least one ink-receiving layer, said ink-receiving layer comprising at least one hydrosoluble binder and at least one aluminosilicate polymer capable of being obtained according to a preparation method consisting in treating an aluminum halide with an alkyl orthosilicate only having hydrolyzable functions with an aqueous alkali in the presence of silanol groups, the aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.Type: GrantFiled: December 3, 2004Date of Patent: December 15, 2009Assignee: Eastman Kodak CompanyInventors: Stephanie V. Desrousseaux, Olivier J. Poncelet
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Patent number: 7560092Abstract: The present invention relates to a method for preparing an aluminosilicate polymer and the polymer resulting from this method. Said method consists in treating an aluminum halide with an alkyl orthosilicate only having hydrolyzable functions with an aqueous alkali, in the presence of silanol groups, aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then in stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the aluminosilicate polymer.Type: GrantFiled: July 14, 2003Date of Patent: July 14, 2009Assignee: Eastman Kodak CompanyInventors: Olivier J. Poncelet, Stephanie V. Desrousseaux
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Patent number: 7507392Abstract: The present invention relates to a method for preparing a hybrid aluminosilicate polymer and the polymer resulting from this method. Said method consists in treating an aluminum halide with a mixture of at least one silicon alkoxide only having hydrolyzable substituents and at least one silicon alkoxide having a non-hydrolyzable substituent, with an aqueous alkali, in the presence of silanol groups, aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then in stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the hybrid aluminosilicate polymer.Type: GrantFiled: July 14, 2003Date of Patent: March 24, 2009Assignee: Eastman Kodak CompanyInventors: Olivier J. Poncelet, Stephanie V. Desrousseaux
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Patent number: 7384139Abstract: The present invention relates to ink for inkjet printing providing a printed image having improved stability, demonstrated by improved color fastness in time. Said ink includes at least particles of synthetic, substantially amorphous aluminosilicate polymer, the synthetic amorphous aluminosilicate polymer having an average diameter of 1 to 10 nm, wherein the aluminosilicate polymer exhibits an X-ray diffraction pattern that has weak peaks at about 2.2 and 3.3 ?.Type: GrantFiled: January 12, 2005Date of Patent: June 10, 2008Assignee: Eastman Kodak CompanyInventors: Gerard Amede Friour, Olivier Jean Poncelet
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Patent number: 6919171Abstract: The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.Type: GrantFiled: December 23, 2003Date of Patent: July 19, 2005Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Peter J. Ghyzel, John W. Boettcher, James L. Wakley, David A. Dickinson, Joe E. Maskasky, Roger L. Klaus, Victor P. Scaccia, Thomas Blanton
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Patent number: 6790585Abstract: The present invention relates to a method for developing an exposed high contrast photographic silver halide material, said photographic material comprising a support bearing at least one silver halide emulsion layer, containing at least one hydrazide nucleating agent. According to the invention, the nucleating agent has the formula (I) and the photographic material is developed in a hydroquinone-free developer, comprising a main developing agent of the ascorbic acid or ascorbic acid salt type, and as auxiliary developing agent a mixture of 3-pyrazolidones of which at least one has the formula (II): wherein at least one of the radicals R3 to R9 contains a solubilizing group. This combination enables photographic materials with ultrahigh contrast to be obtained.Type: GrantFiled: June 19, 2003Date of Patent: September 14, 2004Assignee: Eastman Kodak CompanyInventors: Jacques Roussilhe, Siu C. Tsoi, John D. Goddard, Llewellyn J. Leyshon
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Patent number: 6723397Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer, and b) a fusible, porous ink-transporting layer of fusible, polymeric particles and a film-forming, hydrophobic binder.Type: GrantFiled: September 18, 2001Date of Patent: April 20, 2004Assignee: Eastman Kodak CompanyInventor: Allan Wexler
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Patent number: 6692906Abstract: The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.Type: GrantFiled: July 22, 2002Date of Patent: February 17, 2004Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Peter J. Ghyzel, John W. Boettcher, James L. Wakley, David A. Dickinson, Joe E. Maskasky, Roger L. Klaus, Victor P. Scaccia, Thomas Blanton
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Patent number: 6685836Abstract: The invention relates to a method for separating a mixture of aluminosilicates, wherein said method consists in carrying out an ultrafiltration of a solution of colloidal aluminosilicate particles so as to obtain a permeate and a retentate, and an imogolite like fibrous aluminosilicate polymer of high purity with an Al:Si molar ratio between 1.8 and 2.5 is obtained in the retentate, and allophanes like spherical aluminosilicate particles are obtained in the permeate.Type: GrantFiled: November 27, 2001Date of Patent: February 3, 2004Assignee: Eastman Kodak CompanyInventor: Olivier J. Poncelet
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Patent number: 6680066Abstract: The present invention relates to a composite material with an improved structure in which is dispersed an active organic compound, and a method for treating effluents, in particular a method for treating photographic effluents. The composite material takes the form of a structured gel comprising an aluminosilicate polymer matrix in the form of fibers in which at least two distinct fibers are interconnected by at least two covalent bonds to form an irreversible chemical gel and, dispersed in the matrix, an active organic compound. The choice of the degree of cross-linking of the matrix makes it possible to control the diffusion of a hydrophilic active organic compound. The invention further concerns a method for preparing such a composite material.Type: GrantFiled: February 5, 2002Date of Patent: January 20, 2004Assignee: Eastman Kodak CompanyInventors: Olivier J. Poncelet, Danielle M. Wettling
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Patent number: 6652761Abstract: The invention relates to a method of recycling wash-water resulting from the treatment of a film provided with a carbon particles based backing layer, and especially from a washing treatment to remove the said carbon particles based backing layer. The method comprises the step of passing the wash-water through an microfiltration unit equipped with a microfiltration membrane made from a polytetrafluorethylene-based membrane. The method enables the regeneration of the wash-water and its recycling with a high efficiency and considerable lowering of the water consumption used in this step of the processing.Type: GrantFiled: January 18, 2002Date of Patent: November 25, 2003Assignee: Eastman Kodak CompanyInventor: Didier J. Martin
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Patent number: 6638708Abstract: The present disclosure relates to dispersions of silver (carboxylate-n-alkyl thiolate). The carboxylates are typically silver salts of long chain fatty acids and the n-alkyl thiolate is preferably 1-dodecanethiol. These silver (carboxylate-n-alkyl thiolate) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.Type: GrantFiled: July 22, 2002Date of Patent: October 28, 2003Assignee: Eastman Kodak CompanyInventors: Peter J. Ghyzel, Mark Lelental, David A. Dickinson, Alan R. Pitt, Trevor J. Wear
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Patent number: 6620397Abstract: The present invention relates to a material and a method for treating of photographic effluents in order to eliminate microorganisms and pollutant by-products so as to control bacterial growth and thereby obtain effluents that comply with regulatory requirements. The method for preparing an oxidizing material according to the invention comprises the dispersion in colloidal form of a metal or metal compound in an aqueous solution of an inorganic aluminosilicate polymer, said aluminosilicate being able to form an inorganic gel, and said metal or metal compound being able to cause the oxidation of oxidizable products and (or) micro-organisms to be eliminated, followed by the addition of a base to cause said aluminosilicate to gel. The metal is preferably silver in a powder form that is able to form a colloid when it is dispersed. The oxidizing material of the invention is efficient especially for the treatment of photographic baths, in particular wash baths placed after the fixing step.Type: GrantFiled: May 31, 2002Date of Patent: September 16, 2003Assignee: Eastman Kodak CompanyInventors: Danielle M. Wettling, Olivier J. Poncelet
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Patent number: 6582881Abstract: An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer, a light reflecting layer is disclosed. The recording layer comprises (i) a metallized azo ether dye having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus wherein the phenyl nucleus has an ether substituent ortho to the azo group and said phenyl nucleus is free of strong electron withdrawing groups and (ii) a cyanine dye. The recording layer also has, when unrecorded a refractive index, at a selected wavelength from 400 to 660 nm, comprising a real part (n) greater than 1.8 and an imaginary part (k) less than 0.2.Type: GrantFiled: February 20, 1998Date of Patent: June 24, 2003Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Ann L. Carroll-Lee, Csaba A. Kovacs
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Patent number: 6447981Abstract: Metallized azo thioether dyes having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus are disclosed. The phenyl nucleus has an thioether substituent ortho to the azo group but does not have electron withdrawing substituents on the phenyl nucleus. The dyes are useful in optical recording elements.Type: GrantFiled: May 26, 1998Date of Patent: September 10, 2002Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Csaba A. Kovacs
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Patent number: 6391537Abstract: There is disclosed a nanoparticulate dispersion of a silver carboxylate particles having on the surface of the particles a surface modifier which is a nonionic oligomeric surfactant based on vinyl polymer with an amido function. In particular, the surface modifier is acrylamide, methacrylamide or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate.Type: GrantFiled: January 18, 2001Date of Patent: May 21, 2002Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Alan R. Pitt, David A. Dickinson, James L. Wakley, Peter J. Ghyzel
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Patent number: 6387611Abstract: There is disclosed an oxidation-reduction imaging forming composition comprising an aqueous based dispersion of (i) nanoparticulate silver carboxylate particles having on the surface of the particles a surface modifier which is a phosphoric acid ester and (ii) an organic reducing agent. In particular, the surface modifiers can be mixtures of mono- and di-esters of orthophosphoric acid and hydroxyl-terminated, oxyethylated long-chain alcohols or oxyethylated alkyl phenols or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate.Type: GrantFiled: January 18, 2001Date of Patent: May 14, 2002Assignee: Eastman Kodak CompanyInventors: Mark Lelental, David A. Dickinson, James L. Wakley, Michael W. Orem, Peter J. Ghyzel
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Patent number: 6365336Abstract: There is disclosed an aqueous photothermographic composition comprising a) a photosensitive silver halide emulsion precipitated in a water dispersible cationic starch peptizing agent and b) an oxidation-reduction imaging forming composition comprising (I) a colloidal dispersion of silver compound particles and (ii) an organic reducing agent. The use of a starch peptizing agent reduces the fog in an element using the composition upon thermal processing.Type: GrantFiled: October 31, 2000Date of Patent: April 2, 2002Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, David A. Dickinson, Mark Lelental
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Patent number: 6361922Abstract: The present invention discloses optical recording elements having optical recording layers containing tetra dyes. The dyes have metallized azo dianionic dye with cationic dye counterions. The recording layer has a thickness from 225 to 300 nm.Type: GrantFiled: October 16, 1996Date of Patent: March 26, 2002Assignee: Eastman Kodak CompanyInventors: Derek David Chapman, James C. Fleming, Ramanuj Goswami, Csaba Andras Kovacs