Abstract: An amine functional copolymer of vinyl alcohol is provided by copolymerizing a vinylester with a morpholinoalkylvinylether or a morpholinoalkylallylether and then hydrolyzing the ester groups in the copolymer to hydroxy groups. The preferred copolymer is formed from vinyl acetate and morpholinoethylvinylether and 1 to 30 mol percent of the polymerized ethylene linkages in the polymer backbone contain pendant morpholinoethylether groups.

Abstract: A process for combusting low B.T.U. high moisture content fuels by enriching the normal process air used in the combustion process.

Abstract: Artificial aging of metal alloys in the process of precipitation hardening is performed in the elevated temperature vapor of a perfluorochemical to reduce temperature fluctuations, preserve alloy integrity and avoid environmentally detrimental process conditions and by-products.

Abstract: The present invention is a cryogenic process to produce medium to high pressure gaseous nitrogen without the use of a nitrogen product compressor. The process is an improvement to a conventional nitrogen generator with waste expander. The present invention reboils crude liquid oxygen from the main distillation column in two stages at different pressures and uses a small number of trays above one of the reboilers. The use of the trays above one of the reboilers allows collection of a pressurized stream with a composition similar to air. This pressurized stream is recycled to an intermediate stage of the main air compressor.

Abstract: An improved highly erosive and abrasive wear resistant multi-layered coating system on a substrate which provides protection against impact of large particles is disclosed comprising a plurality of composite layers. In each of the composite layers, the first layer closest to the substrate comprises tungsten of sufficient thickness to confer substantial erosion and abrasion wear resistance characteristics to the coating system and a second layer deposited on the first layer comprises a mixture of tungsten and tungsten carbide and the tungsten carbide comprises W.sub.2 C, W.sub.3 C, or a mixture of both. Because the resulting coating system has enhanced high cycle fatigue strength over the substrate, the coating system is especially useful on such structures as turbine blades and similar articles of manufacture where such high stress cycles occur during normal operation. Also dislcosed is the method for preparing such improved composite coating systems.

Abstract: An improved adsorbent for gas separation comprising a lithium exchanged chabazite having a Si/Al ratio between 2.1 and 2.8 wherein at least 65% of the exchangeable ion capacity is in the lithium form.

Abstract: A novel composition of the formula: ##STR1## wherein the carbon rings are fully fluorinated.

Abstract: The present invention is an energy efficient process for the recovery and purification of C.sub.3.sup.+ hydrocarbons from a high pressure natural gas or refinery/petrochemical feed gas containing C.sub.3.sup.+ hydrocarbons and light gases. In the process, the high pressure feed gas is initially cooled by heat exchange with a multi-component refrigerant fluid circulating in a closed-loop cycle thereby condensing a large portion of the C.sub.3.sup.+ hydrocarbons. The non-condensed, remaining gas is work expanded to an intermediate pressure thus providing refrigeration for condensing the remaining C.sub.3.sup.+ hydrocarbons. The condensed C.sub.3.sup.+ hydrocarbon liquid streams are combined and are further purified by distillation in an integrated distillation column. Optically, refrigeration for refluxing the integrated distillation column can be provided by the mixed refrigerant cycle.

Abstract: A vinyl acetate-ethylene copolymer emulsion which is about 65-70% solids and has a viscosity of less than about 3,500 is disclosed. The emulsion is prepared by copolymerization of vinyl acetate and ethylene monomers in the presence of a stabilizing system consisting essentially of 2-4 wt %, based on vinyl acetate monomer, of a polyvinyl alcohol having a 100-600 degree of polymerization and 2-4wt %, based on vinyl acetate monomer, of a surfactant. Such emulsions demonstrate an improved speed of set as an adhesive.

Abstract: Aqueous, clay-based drilling mud compositions are improved with respect to waterloss control by the addition of a hydrolyzed copolymer of acrylamide and an N-vinylamide. The copolymer, which is effective over a broad range of molecular weights, contains at least 5 mol percent of the N-vinylamide monomer moiety of which at least 5 mol percent is hydrolyzed to vinylamine units. Well drilling is improved by circulating through the bore hole a drilling mud containing this waterloss control additive.

Abstract: A method and apparatus are described for reforming hydrocarbons, particularly natural gas, to form hydrogen wherein the reformation is performed in a reactor in which the heat of reformed products are utilized to reform the hydrocarbons in a catalytic tube reformer. The reformer can be used in conjunction with a traditional steam reformer to produce hydrogen with less energy consumption, lower steam production and less capital cost.

Abstract: This invention relates to a process for producing ethylene diamine in high selectivity and high conversion by reacting monoethanolamine with ammonia in the presence of a catalyst. The catalyst which permits the production of ethylenediamine in high selectivity and high conversion is a hydrogen mordenite catalyst that has been treated in such a manner as to raise the silicon to aluminum ratio of the mordenite, such treatment, then being referred to as partial dealumination.

Abstract: This invention relates to the catalytic preparation of C.sub.2 to C.sub.4 alkyl amines by the reaction of a C.sub.2-4 alkanol with ammonia in the presence of hydrogen, the reaction being carried out utilizing a crystalline alumino-silicate catalyst system where the ions in the crystalline alumino-silicate catalyst system are predominately cobalt or nickel.

Abstract: A freezer (1) which comprises a drum (2) is characterized in that a cylinder (12) is disposed in said drum (2), and a fan (14) is provided for circulating cryogen through the space (20) between the outer surface of the cylinder (12) and the inner surface of the drum (2). The outer surface of the drum (2) is provided with a plurality of grooves (4) of parabolic cross-section. In use, droplets (23) of liquid egg are dropped on to the grooves (4) where they freeze individually. The frozen particles fall away from the drum as they approach the lowermost point of travel of the drum (2) and form an attractive granular product.

Abstract: A gas regulator includes a housing having a high pressure chamber with an inlet passage thereto, a low pressure chamber with an outlet passage therefrom, and an orifice extending between the high pressure chamber and the low pressure chamber. The low pressure chamber is open at one end and an enclosed bonnet is mounted on the housing across the open end of the low pressure chamber. A movable pressure sensing/control element is mounted across the open end of the low pressure chamber and separates the low pressure chamber from the bonnet. The bonnet is filled with a gas under pressure which applies a force onto one side of the pressure sensing/control element. A valve plug is in the high pressure chamber and is connected to the pressure sensing/control element so as to be movable toward and away from the orifice to open and close the regulator. A spring is connected to the pressure sensing/control element so as to apply a force thereto opposite to the force applied by the gas in the bonnet.

Abstract: An adsorptive separation process is set forth for recovery of two gas products in high recovery and high purity using adsorption, depressurization low pressure purge, evacuation and repressurization. Depressurization and purge effluents are recycled to feed and optionally pressure equalizations are performed after the adsorption and after the evacuation as well as a pressure equalization using the low pressure effluent.

Abstract: A high acceleration high performance solid rocket motor grain such as for a ballistic defense missile or rocket assisted projectile comprises a propellant material which includes a highly plasticized binder so that the grain has a solids ratio equal to at least about 95 percent. In order that the grain with such a solids ratio may have adequate strength and withstand high acceleration forces, a reticulated structure is embedded therein. A method of constructing a rocket motor having such a grain is also disclosed.

Abstract: An improved pressure swing adsorption process is disclosed for the recovery of high-purity primary and secondary components from a multicomponent gas mixture. The process utilizes a first group of absorbent beds selective for the secondary component and a second group of adsorbent beds selective for retention of tertiary impurities in the mixture. The gas mixture is passed through a first and second bed in series, very high purity primary component product is discharged from the second bed, and high purity secondary component product is recovered by desorption from the first bed. A low-pressure purge of the first bed with high-purity secondary component product is utilized to minimize compression power and improve purity of the secondary product component. Several novel pressure equalization steps improve primary product recovery and reduce power consumption. Further increased product recovery is realized by recycling depressurization and purge streams from the first bed.

Abstract: This invention relates to an improvement in a fixed bed process for producing tert-butyl-derivatives of aromatic amines, e.g., para-phenylenediamine and toluenediamine by the reaction of isobutylene with the corresponding aromatic diamine in the presence of a highly acidic crystalline alumino-silicate catalyst. The improvement for regenerating the catalyst during operation constitutes adding sufficient water to the catalyst to provide sufficient saturation of the catalyst during the reaction and generally retard the reaction and then substantially decreasing the quantity of added water or reducing the amount of water added.

Abstract: An improved pressure swing adsorption process is disclosed for the recovery of two individual components from a multicomponent gas mixture. The process utilizes a first group of adsorbent beds selective for the secondary component product and a second group of beds selective for tertiary impurities in the mixture. The gas mixture is passed through the first and second beds in series and high purity primary component product is discharged from the second beds. The secondary component product is recovered by desorption from the first beds. Product recovery is improved by recycling depressurization gas from the first beds and by several novel pressure equalization steps. The process can be used to recover high-purity hydrogen and carbon dioxide from a gas mixture containing these components along with minor amounts of methane, carbon monoxide, and nitrogen.