Abstract: Disclosed is a two-step process for the generation of diisopropyl ether from a crude by-product acetone stream which comprises:a) Hydrogenating said crude acetone over a bulk-metal, nickel-rich catalyst to give an isopropanol-rich effluent;b) Dehydrating said isopropanol-rich intermediate in the presence of a strong acid zeolite catalyst from the group consisting of .beta.-zeolite, optionally modified with one or more metals from Group IB, VB, VIB, VIIB and VIII of the Periodic Table, and a dealuminized Y-zeolite, wherein the dehydration temperature is from about 80.degree. C. to 200.degree. C.

Abstract: A method for determining the widths of fractures in reservoir earthen cores utilizes a series of CT X-ray scans which are translated into an estimated porosity image. A region of interest within the image is selected and a frequency histogram of the porosity distribution is created. The contribution of the fracture widths to the pore volume is determined from the histogram.

Abstract: A method has been discovered for recovering polyoxyalkylene glycols from wastewater. A skimming surface is heated to a temperature above the cloud point. The heated surface is contacted with the wastewater, causing the polymer to deposit. Deposited polymer skimmed from the surface is recovered. Heating, or other processing of the bulk wastewater is avoided.

Abstract: A method for fluid control or plugging of a well by injecting a mixture of an acid polymerizable resin, a polar organic diluent, and an acid catalyst, and later injecting an acidic fluid to quick-set a portion of the resin and hold it in place while the pre-mixed catalyst sets the resin. In an alternate sand consolidation embodiment, a fluid slug is injected between the resin and acidic fluid injections to create permeability in the resin saturated area of the formation prior to final set of the resin.

Abstract: An artificial intelligence system is used with a conglomeration of fluorescence data to provide a method of improving recognition of an unknown from its spectral pattern. Customized neural network systems allow the ultimate organization and resourceful use of assumption-free variables already existing in a total scanning fluorescence database for a much more comprehensive, discrete and accurate differentiation and matching of spectra than is possible with human memory. The invention provides increased speed of fingerprinting analysis, accuracy and reliability together with a decreased learning curve and heightened objectivity for the analysis.

Abstract: Apparatus and method for concurrently determining steam flow rate and quality, through a conduit which comprises an orifice plate positioned in series with a critical flow venturi in said conduit. Pressure sensing means in the conduit senses pressures therein for application in a formula to provide the desired steam values and provide a method for determining both the quality and the mass flow rate of steam flow passing through the conduit. The measurements are of particular value in the instance of steam flow where a minimal decrease in steam pressure across the measuring instrument is a relevant factor.

Abstract: The apparatus and method proves to be the use of the pipeline carrying a petroleum fluid. A through-put pipe having a meter to be proved, and the bypass pipe are connected with valves to the pipe line so that petroleum fluid may be caused to fall either through the through put pipe or the bypass pipe. A prover is spatially arranged with a bypass pipe and measures a fluid flow in the bypass pipe. At least one sensor arranged with a through-put pipe senses a physical characteristic of the petroleum stream flowing the through-put pipe. A computer which includes memories having stored the meter's manufacturers' performance data, is at work for determining the type of curve generated by the stored performance data, a circuit for fitting data generated by the prover to the determined type of curve.

Abstract: A wear resistant vent orifice is formed by a ring plate member, having erosion protective material at least on the inner annulus thereof, defining the vent orifice between the inner annulus of the ring plate and a tube member passing therethrough.

Abstract: The present invention concerns a new optical photometry system for on-line analysis of industrial fluid streams. The invention is a general purpose optical photometer, capable of absorption, fluorescence and reflectance measurements at single wavelengths in the ultraviolet, visible and near infrared spectral ranges. Light signals generated by the light source are carried between a central photometric console and remote analysis sites by fiber optic cables. The return light signals are compared with a standard to make the desired analysis.

Abstract: Railroad wheel flange lubricating is carried out with a lubricating composition which is particularly useful in a locomotive-mounted applicator. The water base lubricant comprises a compatible blend of two polyoxyalkylene glycols, one a synthetic lubricant and the other a synthetic thickener. The lubricating composition is persistent and environmentally innocuous.

Abstract: Unequal phase splitting at branch T pipe junctions, wherein the branch line is of substantially lesser diameter than the main line, is substantially eliminated by structure (either a weir or sump) in the main line which collects at least a portion of the liquid phase and a bypass line which connects the weir or sump to the branch line downstream of a constriction creating a reduced pressure section in the branch pipe.

Abstract: A multi-phase fluid flow meter based on passive and non-intrusive acoustics is described for use in field applications on pipes. The present design uses the pipe's characteristic acoustic frequency and its amplitude variation in conjunction with a differential pressure measurement to obtain the total mass flow rates and mass flow rates of each phase. In addition to the mass flow rates the void/liquid fraction, fluid velocities and densities become viable estimates. Instrument construction is simple and very robust, allowing for use in extreme environments. This includes down hole as well as surface measurements.

Abstract: A low-cost low-pressure drop critical flow venturi is formed from a single rigid member with mirror image inlet and diffuser sections. The mirror imaging allows the member to be mounted in a flow stream, without regard to the direction of flow, and to still be operative.

Abstract: A method of recovering hydrocarbons from an underground reservoir with a cyclic injection/production process, wherein after one or more injection and production cycles, a second recovery fluid is injected into the formation comprising a cosolvent, a solute, preferably polydimethylsiloxane, and the primary recovery fluid such as carbon dioxide, said second fluid composition designed for solute to drop out of solution in the formation during the later soaking and production phases.

Abstract: Dialkyl ethers having 5 to 7 carbon atoms; e.g. MTBE, and alcohols having 1 to 4 carbon atoms are extracted from wastewater with contaminant-free gasoline. Wastewater saturated with contaminants is reduced to 200 ppm contaminants in the absence of stripping. An octane enhanced gasoline is recovered. Additional ether may be added to the recovered gasoline to increase octane. The method is particularly effective in wastewater/gasoline system containing emulsifiers such as surfactants, gasoline detergents and colloidal particles.

Abstract: Tertiary butyl alcohol (TBA) is prepared by non-catalytically reacting isobutane with oxygen to provide a reaction product comprising isobutane, peroxides including tertiary butyl hydroperoxide and impurities, charging the de-isobutanized reaction product and a soluble hydroperoxide decomposition catalyst to a first hydroperoxide decomposition reactor fitted with a fractionating column to provide a liquid reaction product comprising TBA, catalyst, hydroperoxides, and contaminants, and a vaporized decomposition product, cooling said vaporized reaction product to provide a condensate, and recovering a portion as a TBA reaction product, charging the liquid reaction product to a second hydroperoxide decomposition reactor to substantially completely decompose the peroxides therein and to form a second hydroperoxide decomposition product, which is charged to a second distillation column and separated therein into a third lighter overhead fraction comprising TBA, and a third heavier liquid fraction comprising normal

Abstract: A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of pentagonally cross-sectioned alumina having palladium deposited thereon and is brought into contact with the catalyst in liquid phase with agitation under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.

Abstract: A method for preparing tertiary butyl alcohol wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium and gold supported on alumina, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.

Abstract: A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of titania or zirconia and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.

Abstract: The means and method of the present invention includes a source of microwave energy and associated elements which provide microwave energy to a petroleum stream. Other circuitry include elements which receive microwave energy from the petroleum stream. Electronic apparatus provides at least one outputs utilizing the provided microwave energy, the received microwave energy and known values for 100 percent oil, 100 percent gas and 100 percent water, corresponding to a ratio of gas to liquid. From the readings of attenuation and phase shift, an estimate of the proportions in the mix is extracted by interpolation.