Abstract: A method for the removal of metal from a hydrocarbon solution containing metal alkaryl sulfonate. Briefly, the method comprises contacting the hydrocarbon solution containing metal alkaryl sulfonate with an aqueous ammonia or an aqueous ammonium salt solution and recovering a hydrocarbon having a reduced metal concentration.
Abstract: A method of removing metal alkaryl sulfonate from a hydrocarbon solution is disclosed. Briefly, the method comprises contacting the hydrocarbon solution containing metal alkaryl sulfonate with basic anion-exchange resin and recovering a hydrocarbon having a reduced concentration of metal alkaryl sulfonate.
Type:
Grant
Filed:
February 1, 1982
Date of Patent:
September 6, 1983
Assignee:
UOP Inc.
Inventors:
Lee Hilfman, Thomas P. Malloy, Russell W. Johnson
Abstract: A process for liquefying a calcium-containing coal which comprises contacting calcium-containing coal with an aqueous sulfur oxide solution. The resulting admixture is contacted with hydrogen sulfide to produce water soluble thiosulfate. After the treated coal is separated from the resulting aqueous phase, the coal is charged to a coal liquefaction zone.
Abstract: An improved process for the treatment and liquefaction of calcium-containing subbituminous coal and coals of lower rank to form water soluble compounds of calcium, thereby suppressing the formation of scale, made up largely of calcium carbonate which normally forms within the coal liquefaction zone, e.g. on reactor surfaces, lines, auxiliary equipment and the like. An oxide of sulfur is contacted with a coal feed sufficient to impregnate the pores of the coal. The impregnated coal is then contacted with hydrogen sulfide to produce water soluble thiosulfate. After the treated coal is liquefied in a coal liquefaction zone, the effluent is water washed to remove the water soluble thiosulfate.
Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a catalyst composite comprising from about 5 weight percent to about 95 weight percent of a silica polymorph consisting of crystalline silica, said silica polymorph after calcination in air at 600.degree. C. for one hour, having a mean refractive index of 1.39.+-.0.01 and a specific gravity at 25.degree. C. of 1.70.+-.0.05 g/cc and at least 5 weight percent to about 95 weight percent Ziegler alumina.
Abstract: A catalytic slurry process for effecting the conversion of a hydrocarbonaceous black oil charge stock is disclosed and which process possesses improved efficiency by the addition of antifoamant.
Abstract: A process for liquefying coal which comprises contacting coal and solvent in the presence of a residual oil containing asphaltenes and at least one finely divided, unsupported metal sulfide and recovering valuable liquid hydrocarbon products from the resulting liquid coal extract.
Abstract: A method for the removal of carbon or carbon compounds from a waste stream generated in an unsupported slurry catalyst process utilized for the hydroconversion of heavy hydrocarbonaceous black oil which stream comprises vanadium sulfide, nickel sulfide and carbon or carbon compounds is disclosed. The carbon or carbon compound is removed by contacting the waste stream with sulfur dioxide at oxidizing conditions to yield a solid residue which contains metal sulfides.
Abstract: A process for the conversion of an asphaltene-containing, hydrocarbonaceous black oil in a catalytic slurry reaction zone wherein an admixture of converted hydrocarbonaceous oil and deasphalter solvent is recycled to the reaction zone.
Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a catalyst composite comprising a silica polymorph consisting of crystalline silica, said silica polymorph after calcination in air at 600.degree. C. for one hour, having a mean refractive index of 1.39.+-.0.01 and a specific gravity at 25.degree. C. of 1.70.+-.0.05 g/cc and a refractory inorganic oxide.
Abstract: A solid carbonaceous material, such as coal, is converted to liquid products and the asphaltene content of a heavy hydrocarbonaceous liquid is reduced in the process wherein the solid is solvent extracted by the heavy hydrocarbonaceous liquid and a hydrocarbonaceous recycle stream with a finely divided, unsupported metal catalyst and the resultant mixture of liquids is recovered as the product.
Abstract: Isomerizable hydrocarbons are isomerized using a catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, of a tin component, and of a halogen component and from about 1 to about 100 weight percent of a Friedel-Crafts metal halide calculated on a Friedel-Crafts metal halide-free basis.
Abstract: Isomerizable hydrocarbons are isomerized using a catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, of a tin component, and of a halogen component.
Abstract: Isomerizable hydrocarbons are isomerized using a catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, of a tin component, and of a halogen component.
Abstract: A process for liquefying coal by subjecting bituminous coal particles to electromagnetic wave energy and having wavelengths of from about 0.001 to about 100 A and recovering valuable liquid hydrocarbon products from the resulting liquid coal extract.
Type:
Grant
Filed:
October 8, 1980
Date of Patent:
April 27, 1982
Assignee:
UOP Inc.
Inventors:
John F. Flagg, Russell W. Johnson, John G. Gatsis
Abstract: A process for the conversion of aromatic hydrocarbons, e.g., reacting an alkylating agent, preferably an olefin, with an aromatic hydrocarbon. The process uses a novel catalyst prepared by subjecting alumina to an anhydrous tetravalent titanium fluoride complex of an organic compound selected from the group of organic compounds containing at least one methoxy group per molecule or organic compounds having at least one electron donor atom and double bond per molecule, and heat treating the resulting impregnated alumina in an inert atmosphere.
Abstract: A process for deashing primary coal liquids with a selective multi-solvent extraction wherein the coal liquids and a primary solvent are contacted initially at a temperature greater than the temperature at which the deashing extraction occurs.
Abstract: A process for the conversion of aromatic hydrocarbons, e.g., reacting an alkylating agent, preferably an olefin, with an aromatic hydrocarbon. The process uses a novel catalyst prepared by subjecting alumina to an anhydrous tetravalent titanium fluoride complex of an organic compound selected from the group of organic compounds containing at least one methoxy group per molecule of organic compounds having at least one electron donor atom and double bond per molecule, and heat treating the resulting impregnated alumina in an inert atmosphere.
Abstract: Hydrocarbons are converted with a catalyst comprising an alumina-zeolite support, a Group VIII metallic component and a Group VI-B metallic component. Key features of the process are the commingling of alumina and zeolite before the rare earth exchange of the faujasite and the extremely low sodium concentration of the finished catalyst.
Abstract: A novel method of preparing an unsupported molybdenum sulfide catalyst utilized in the processing of hydrocarbon feedstocks containing asphaltenes and organometallic compounds.