Abstract: Olefin/maleic acid copolymer is refined to pharmaceutical quality by use of dichloroethane to remove contaminants, as by precipitating from solution with dichloroethane.

Abstract: Dehydrohalogenation-rearrangement-hydrogenation of 1,1-bis(4-hydroxyaryl)-2-haloethanes in an aliphatic carboxylic acid solvent containing a carboxylic acid salt in the presence of gaseous hydrogen and a hydrogenation catalyst is effected in one step to yield 1,2-bis(4-hydroxyaryl)ethanes. The process is particularly directed to the production of 1,2-bis(4-hydroxyphenyl)ethane from 1,1-bis(4-hydroxyphenyl)-2-chloroethane.

Abstract: The reaction of carbon monoxide and water to produce hydrogen and carbon dioxide is catalyzed by a rhodium or iridium component with an iodide promoter.

Abstract: An improved alkylation catalyst is provided exemplified by a type X or Y zeolite with cesium, rubidium or potassium cations, and with a boron or phosphorous component added. The catalyst is useful in producing styrene from toluene and methanol.

Abstract: This invention relates to an electrolytic flow-cell apparatus and a process for effecting sequential electrochemical reactions of redoxidative compounds at a porous working electrode. The porous working electrode has a first face and a second and opposite face, at which faces the sequential reactions are effected.

Abstract: Organic electrophiles are added to carbon acids via catalysis by electrogenerated bases to yield carbon acid-organic electrophile addition products.

Abstract: Electrolysis of a substantially anhydrous electrolysis medium comprising a primary alcohol having at least one beta-hydrogen atom and anhydrous hydrogen halide selected from the group consisting of hydrogen chloride and hydrogen bromide yields acetals of 2-haloaldehydes corresponding to the primary alcohol.

Abstract: The level of blood cholesterol in a living animal body in which a state of hypercholesterolemia exists is lowered by orally administering to said animal body a pharmaceutically effective amount of a polymer, which is (1) polymerized unsaturated carboxylic acid or anhydride, or (2) a copolymer of (a) an unsaturated monomer having, for Example, 2 to 30 carbon atoms and, (b) an unsaturated carboxylic acid, anhydride or derivative thereof as exemplified by octadecene-l/maleic anhydride copolymer. Polymers having lipophilic properties are a preferred class. A typical dosage is an amount which represents in the range of from about 0.01 to about 5.0% of the diet.

Abstract: The level of blood cholesterol in a living animal body in which a state of hypercholesterolemia exists is lowered by orally administering to said animal body a pharmaceutically effective amount of a polymer, which is (1) polymerized unsaturated carboxylic acid or anhydride, or (2) a copolymer of (a) an unsaturated monomer having, for example, 2 to 30 carbon atoms and, (b) an unsaturated carboxylic acid, anhydride or derivative thereof as exemplified by octadecene-1/maleic anhydride copolymer. Polymers having lipophilic properties are a preferred class. A typical dosage is an amount which represents in the range of from about 0.01 to about 5.0% of the diet.

Abstract: An improved alkylation catalyst is provided exemplified by a type X or Y zeolite with cesium, rubidium or potassium cations, and with a boron or phosphorous component added. The catalyst is useful in producing styrene from toluene and methanol.

Abstract: Electrolytic oxidation of cresol salts substituted with non-interfering, blocking substituents at least at the 2,4,6-positions relative to the phenolic oxyanion where at least one of the substituents is the cresolic methyl leads to methyl-methyl coupled dehydrodimeric cresols.

Abstract: Electrolytic reductive coupling of hydroxybenzaldehydes in an aqueous alkaline electrolysis medium in an undivided electrolytic cell yields 1,2-bis(hydroxyphenyl)ethane-1,2-diols.

Abstract: Hydrogenolysis of hydrobenzoins [1,2-bis(aryl)ethane-1,2-diols] in the presence of a catalyst comprising cobalt carbonyl yields 1,2-bis(aryl)ethanes. The process is particularly directed to the production of 1,2-bis(4-hydroxyphenyl)ethane from 4,4-dihydroxyhydrobenzoin [1,2-bis(4-hydroxyphenyl)ethane-1,2-diol].

Abstract: The invention concerns dehydrogenation of carboxylic acids, lactones, esters, nitriles, the carbon skeleton of the feed material being characterized as containing mono-unsaturation or alternatively functional groups such as hydroxyl which convert under process conditions to unsaturation, the dehydrogenation reaction being conducted in the presence of a contact catalyst comprising a carbonaceous layer effective for the dehydrogenation of mono-unsaturated reactants to di-unsaturated products. Another aspect of the invention involves production of the mono-unsaturated reactants. In particular, the invention provides a route to sorbic acid, for example by dehydrogenation of hexenoic acids or esters thereof.

Abstract: Electrolytic dehydrodimeric coupling of malonate esters at elevated temperatures yields ethane-1,1,2,2-tetracarboxylate esters. Similar intramolecular coupling of bismalonate esters yields related cyclic tetracarboxylate esters in which the ethane-1,1,2,2-ethanetetracarboxylate moiety is incorporated into a ring.

Abstract: Tertiary phosphonomethylamines are oxidized with oxygen, preferably in contact with activated carbon, to cause cleavage of a phosphonomethyl group and selective production of a secondary amine.

Abstract: Electrolytic carboxylation of carbon acids via electrogenerated bases leads to carboxylated carbon acids.

Abstract: This invention relates to an electrolytic flow-cell apparatus and a process for effecting sequential electrochemical reactions of redoxidative compounds at a porous working electrode. The porous working electrode has a first face and a second and opposite face, at which faces the sequential reactions are effected.

Abstract: The present invention relates to a process for the preparation of saturated hydrocarbons from alcohols, ketones, aldehydes, esters or ethers by hydrogenolysis in the presence of catalyst systems containing an iridium or rhodium component and a halogen component. The process is specifically directed to the production of methane from methanol, toluene from benzaldehyde, ethyl benzene from methyl benzyl alcohol or acetophenone, bis(p-hydroxyphenyl) ethane from anisoin.

Abstract: The level of blood cholesterol in a living animal body in which a state of hypercholesterolemia exists is lowered by orally administering to said animal body a pharmaceutically effective amount of a polymer, which is (1) polymerized unsaturated carboxylic acid or anhydride, or (2) a copolymer of (a) an unsaturated monomer having, for Example, 2 to 30 carbon atoms and, (b) an unsaturated carboxylic acid, anhydride or derivative thereof as exemplified by octadecene-1/maleic anhydride copolymer. Polymers having lipophilic properties are a preferred class. A typical dosage is an amount which represents in the range of from about 0.01 to about 5.0% of the diet.