Patents Represented by Attorney Joseph G. Walsh
  • Patent number: 5493320
    Abstract: In a print head for ink jet printing a nozzle plate with a nozzle array is gold plated. The gold plated nozzle array is bonded to the polymer ink barrier layer on an electronic chip by a thin layer of tantalum, zirconium, titanium or silicon dioxide. The thin layer greatly increases the ability of the surface to bond chemically to the polymer.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: February 20, 1996
    Assignee: Lexmark International, Inc.
    Inventors: David L. Sandbach, Jr., Lawrence R. Steward, Charles S. Whitman, Gary R. Williams, John D. Zbrozek
  • Patent number: 5079086
    Abstract: The magnetic recording layer of a recording medium contains a film-forming resin, magnetic particles, poly(ethyleneimine), and an amionic surfactant.
    Type: Grant
    Filed: October 11, 1990
    Date of Patent: January 7, 1992
    Assignee: International Business Machines Corp.
    Inventors: John M. Burns, Walter Crooks, Wai C. Leung, Randall G. Simmons, Clinton D. Snyder
  • Patent number: 5077267
    Abstract: A process for forming a composite high temperature superconductor copper wire, said process comprising the steps of (1) directing a submicron sized powder of a superconducting ceramic material through a length of copper tubing to coat the interior surface of said tubing with a uniform compact film of said powder, and (2) sintering said powder while passing oxygen through said tube and while maintaining the outside of said tube in an inert atmosphere. In a preferred embodiment an aerosol process is used to generate the submicron sized powder of the superconductor.
    Type: Grant
    Filed: July 12, 1988
    Date of Patent: December 31, 1991
    Assignee: International Business Machines Corporation
    Inventors: Edward M. Engler, Toivo T. Kodas, Victor Y. Lee
  • Patent number: 5068054
    Abstract: Disclosed are compounds of the general formula:R--O--Ar--COS--Ph--COO--R'characterized by the presence of the thioester (--COS--) core and wherein R is an alkyl group with typically 8 to 16 carbon atoms, Ar is a substituted aromatic core group such as 1,4-benzene, 2,6-naphthalene, 4,4'-biphenyl, or 4,4'-diphenylethane, and R' is a chiral branched alkyl group such as the 1-substituted cases 1-methylpropyl through 1-methyloctyl or 2-substituted case such as 2-methylbutyl. These materials or their mixtures possess ferroelectric phases and as such are of interest for electro-optical applications. In certain cases specific materials are of particular interest due to the existence of stable ferroelectric phases near room temperature with large polarization density and fast electro-optic response.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: November 26, 1991
    Assignee: International Business Machines Corporation
    Inventors: Kathleen M. Betterton, William D. Hinsberg, Huu T. Nguyen, Wing T. Tang, Robert J. Twieg
  • Patent number: 5045608
    Abstract: Block copolymers of polyimide and poly (phenylquinoxaline) have been synthesized. They are useful, particularly as dielectric layers in thin film multilayer structures. The most preferred embodiments are formed from polyimides which are those from pyromellitic dianhydride and oxydianiline. The most preferred poly (phenylquinoxaline) is a monofunctional oligomer, which yields the best microstructure.
    Type: Grant
    Filed: September 27, 1989
    Date of Patent: September 3, 1991
    Assignee: IBM Corporation
    Inventors: James L. Hedrick, Jr., Donald C. Hofer, Jeffrey W. Labadie, Sally A. Swanson, Willi Volksen
  • Patent number: 5019481
    Abstract: An aqueous base developable negative resist composition comprising a phenolic resin, a radio-chemical acid generator and a small molecule which upon irradication and postbake reacts with the phenolic resin to decrease its rate of dissolution.
    Type: Grant
    Filed: September 25, 1989
    Date of Patent: May 28, 1991
    Assignee: International Business Machines Corporation
    Inventor: Hiroshi Ito
  • Patent number: 4999280
    Abstract: Photoresist images are made resistant to reactive ion etching by treating them with a poly(dimethylsilazane).
    Type: Grant
    Filed: March 17, 1989
    Date of Patent: March 12, 1991
    Assignee: International Business Machines Corporation
    Inventor: Hiroyuki Hiraoka
  • Patent number: 4988668
    Abstract: Stable, bulk electrical superconductors are prepared by heating mixed metal oxides in the presence of oxygen in a closed vessel in a preheated oven for 1-5 hours at 850.degree.-900.degree. C. The final oxides are in the molar ratio Ti.sub.0.6-1.1 Ca.sub.2-3 Ba.sub.0.75-1.25 Cu.sub.2-3 O.sub.(5+.delta.)-(9+.delta.), where .delta. is less than one.
    Type: Grant
    Filed: March 22, 1989
    Date of Patent: January 29, 1991
    Assignee: International Business Machines Corporation
    Inventors: Edward M. Engler, Victor Y. Lee, Adel I. Nazzal, Stuart S. P. Parkin
  • Patent number: 4981840
    Abstract: Substrates are coated with durable, adherent and continuous superconductive coatings by applying thereto a suspension of finely divided metal, finely divided ceramic superconducting above 77.degree. K., and fluorinated polymer in an organic solvent. The resulting coatings are adherent, durable and superconducting above 77.degree. K.
    Type: Grant
    Filed: July 28, 1989
    Date of Patent: January 1, 1991
    Assignee: International Business Machines Corporation
    Inventors: Charles A. Brown, Edward M. Engler, Victor Y. Lee
  • Patent number: 4980492
    Abstract: A triarylsulfonium salt is prepared in high yield and high purity by a two-step process involving a aryl Grignard reagent reacted with a diarylsulfoxide in a solvent which is a mixture of aliphatic and aromatic hydrocarbons, followed by a second step which is metathesis with ZMF.sub.6, where Z is a metal or metal-like anion, and M is antimony, arsenic or phosphorus, preferably employing an ammonium salt and carried out in a non-aqueous solvent.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: December 25, 1990
    Assignee: International Business Machines Corporation
    Inventors: John L. Dektar, Nigel P. Hacker
  • Patent number: 4970551
    Abstract: A cartridge for electrophotographic printing which contains a reciprocating photoconductor ribbon, a charging station, a developer station, a transfer station and a retractable cleaner blade. In operation, the photoconductor ribbon is directed past the charging station, through the developer station, and through the transfer station. The cleaner blade is moved into contact with the photoconductor ribbon.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: November 13, 1990
    Assignee: International Business Machines Corporation
    Inventor: Ronald C. Moore
  • Patent number: 4970098
    Abstract: A roll for hot fusing having a coating comprising a cross-linked elastomeric random copolymer of dimethylsiloxane and diphenylsiloxane and three additives, (1) from 40 to 55% by weight of small zinc oxide particles, (2) from 5 to 10% by weight of small graphite particles and (3) from 1 to 5% by weight of ceric dioxide particles.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: November 13, 1990
    Assignee: International Business Machines Corporation
    Inventors: Juan Ayala-Esquilin, William H. Dickstein, James L. Hedrick, Jr., John C. Scott, Arnold C. Yang
  • Patent number: 4954578
    Abstract: Thin films of polyimide having electrical insulation, low thermal expansion, high glass transition temperature, and good adhesion are made by dispersing fine domains of relatively flexible polyimide which is fluorinated in a matrix of relatively rigid polyimide.
    Type: Grant
    Filed: October 25, 1988
    Date of Patent: September 4, 1990
    Assignee: International Business Machines Corporation
    Inventors: Moonhor Ree, Sally A. Swanson, Willi Volksen, Do Y. Yoon
  • Patent number: 4948629
    Abstract: Diamond films are deposited at substrates below temperatures of 400.degree. C. by chemical vapor deposition using a high powered pulsed laser and a vapor which is an aliphatic carboxylic acid or an aromatic carboxylic anhydride.
    Type: Grant
    Filed: February 10, 1989
    Date of Patent: August 14, 1990
    Assignee: International Business Machines Corporation
    Inventors: Nigel P. Hacker, George W. Tyndall, III
  • Patent number: 4889784
    Abstract: An organic photoconductor comprising a charge generation layer and on top thereof a charge transport layer having a higher concentration of charge transport molecules nearer the charge generation layer than in the topmost portion.
    Type: Grant
    Filed: October 25, 1988
    Date of Patent: December 26, 1989
    Assignee: International Business Machines
    Inventors: Robert B. Champ, Meredith D. Shattuck, Donald A. Stremel
  • Patent number: 4880959
    Abstract: Thin-film electrical circuits are interconnected by a process comprising the steps of partially ablating the existing thin-film conductor at the connection point(s) by means of a pulsed laser and depositing a thin-film metal interconnection over the desired area, which includes the area(s) of the existing thin-film circuit that were exposed the pulsed laser.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: November 14, 1989
    Assignee: International Business Machines Corporation
    Inventors: Thomas H. Baum, Paul B. Comita, Robert L. Jackson
  • Patent number: 4875124
    Abstract: A thin film magnetic head is provided in which the electrical insulation surrounding the conductive coil comprises a photosensitive resin which has been crosslinked by a thermally activated crosslinking agent or promotor. The addition of the thermally activated crosslinking agent or promotor greatly reduces both the cure temperature and cure time and results in enhanced dimensional stability without any deleterious effects.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: October 17, 1989
    Assignee: International Business Machines Corporation
    Inventors: Heidi L. Dickstein, Hiroyuki Hiraoka, James H. Lee
  • Patent number: 4874682
    Abstract: Fatigue in organic photoconductors in which the charge transport layer is a source of acidic protons is reduced by including in the charge transport layer a small amount of a nonvolatile basic amine soluble in a common solvent with a charge transport material and the binder of the charge transport layer.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: October 17, 1989
    Assignee: International Business Machines Corporation
    Inventors: John Campbell Scott, Meredith D. Shattuck
  • Patent number: 4870052
    Abstract: Stable, bulk electrical superconductors are prepared by heating mixed metal oxides in the presence of oxygen in a closed vessel in a preheated oven for 1-5 hours at 850.degree.-900.degree. C. The final oxides are in the molar ratio Tol.sub.0.6-1.1 Ca.sub.2-3 Ba.sub.0.75-1.25 Cu.sub.2-3 O.sub.(5+.delta.)-(9+.delta.), where .delta. is less than one.
    Type: Grant
    Filed: March 8, 1988
    Date of Patent: September 26, 1989
    Assignee: International Business Machines Corporation
    Inventors: Edward M. Engler, Victor Y. Lee, Adel I. Nazzal, Stuart S. P. Parkin
  • Patent number: 4849501
    Abstract: A composition for the application of a planar polyimide coating having a glass transition temperature above 300.degree. C. comprises a solution in an anhydrous, aprotic solvent of an aromatic diamine and a dialkyldihydrogen pyromellitate which is more than 90% meta isomer.
    Type: Grant
    Filed: April 19, 1988
    Date of Patent: July 18, 1989
    Assignee: International Business Machines Corporation
    Inventors: Richard D. Diller, deceased, Anthony F. Arnold, Ying Ying Cheng, Patricia M. Cotts, Donald C. Hofer, Mahmoud Khojasteh, Elwood H. Macy, Prabodh R. Shah, Willi Volksen