Patents Represented by Attorney K. K. Brandes
  • Patent number: 5269990
    Abstract: Shaped zirconia particles are prepared by mixing zirconia powder with an aqueous colloidal zirconia solution or an aqueous acid solution so as to obtain a shapable mixture containing about 4-40 weight-% water, shaping this mixture, and heating the shaped particles at a temperature in excess of about 90.degree. C.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: December 14, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Gyanesh P. Khare, Hobert L. Williams
  • Patent number: 5254790
    Abstract: An integrated process for converting C.sub.4 /C.sub.5 hydrocarbons contained in a gasoline feedstock to more valuable motor fuel components includes various distillation steps, a hydroisomerization step, an etherification step (for producing t-amyl methyl ether), and an alkylation step. In a preferred embodiment, this process additionally includes a dehydrogenation step and a step of using formed debydrogenated hydrocarbons in the etherification step.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: October 19, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Gregory D. Thomas, Vernon A. Cawi
  • Patent number: 5254791
    Abstract: C.sub.5 -C.sub.10 cycloalkanes (preferably methylcyclopentane) are isomerized in the presence of a catalyst comprising aluminum chloride and at least one of the following materials: boron phosphate on silica, boron phosphate on activated carbon, boron sulfate on silica.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: October 19, 1993
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Lyle R. Kallenbach, Marvin M. Johnson
  • Patent number: 5254794
    Abstract: Isomerization catalyst compositions are prepared by heating aluminum chloride, at least one of several metal salts (preferably CuSO.sub.4), at least one of several inorganic support materials (alumina, silica, aluminum phosphate and combinations thereof) and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at a temperature of about 40.degree.-90.degree. C. The dried catalyst compositions are used for the isomerization of C.sub.5 -C.sub.10 cycloalkanes and/or C.sub.4 -C.sub.10 alkanes.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: October 19, 1993
    Assignee: Phillips Petroleum Company
    Inventor: An-hsiang Wu
  • Patent number: 5254793
    Abstract: A composition of matter, which is an effective alkylation catalyst composition, is prepared by a method comprising heating, at a temperature of about 40.degree.-90.degree. C., (a) aluminum chloride, (b) boron phosphate, (c) alumina and/or silica, and (d) at least one chlorinated hydrocarbon (preferably CCl.sub.4), and subsequently separating the formed solid from the chlorinated hydrocarbon. The thus-prepared catalyst composition is employed in the alkylation of C.sub.2 -C.sub.7 alkane(s) with C.sub.2 -C.sub.7 alkene(s).
    Type: Grant
    Filed: January 25, 1993
    Date of Patent: October 19, 1993
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Marvin M. Johnson
  • Patent number: 5245121
    Abstract: A waste material which contains chromium and/or lead impurities is treated by mixing the waste material with diatomaceous earth and/or sodium borate and then heating the mixture in a free oxygen containing gas at about 500.degree.-1500.degree. C., preferably in the presence of steam.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: September 14, 1993
    Assignee: Phillips Petroleum Company
    Inventors: James W. Gall, Ollie G. Buck, Dennis R. Kidd
  • Patent number: 5244641
    Abstract: Hydrogen sulfide is removed from a gas by contacting it with an absorbent composition consisting essentially of a mixed oxide of iron, zinc and nickel and an inorganic binder.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: September 14, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Gyanesh P. Khare
  • Patent number: 5245103
    Abstract: In one embodiment, C.sub.4 -C.sub.10 alkanes and/or C.sub.5 -C.sub.10 cycloalkanes are isomerized in the presence of a catalyst which has been prepared by heating AlCl.sub.3, at least one aluminum sulfate-containing support material and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at about 40.degree.-90.degree. C., followed by separating the formed solid from the chlorinated hydrocarbon.In another embodiment, C.sub.5 -C.sub.10 cycloalkane(s) are isomerized in the presence of a catalyst which has been prepared by heating AlCl.sub.3, at least one sulfur-containing acid (H.sub.2 SO.sub.4 and/or ClSO.sub.3 H and/or FSO.sub.3 H and/or CF.sub.3 SO.sub.3 H) and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at about 40.degree.-90.degree. C., followed by separating the formed solid from the chlorinated hydrocarbon.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: September 14, 1993
    Assignee: Phillips Petroleum Company
    Inventor: An-hsiang Wu
  • Patent number: 5238896
    Abstract: A composition is prepared by mixing at least one aluminum halide (preferably AlCl.sub.3), at least one copper(II) salt (preferably CuCl.sub.2), calcium aluminate and at least one alcohol (preferably ethanol), shaping the mixture, and drying the shaped particles. The thus-obtained catalyst composition can be employed as a catalyst in the isomerization of alkanes and/or cycloalkanes.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: August 24, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Gyanesh P. Khare
  • Patent number: 5233119
    Abstract: A composition of matter comprises trifluoromethane on a solid support material which contains boron phosphate and/or boron sulfate. Preferred support materials are boron phosphate, boron phosphate-coated silica and boron sulfate-coated silica. The above composition is used as a catalyst for alkylating at least one C.sub.2 -C.sub.7 alkane (preferably isobutane or an isopentane) with at least one C.sub.2 -C.sub.7 alkene (preferably butene-2).
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: August 3, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Lyle R. Kallenbach, Roy F. Wright, David C. Miller
  • Patent number: 5220091
    Abstract: A process for dehydrogenating C.sub.2 -C.sub.8 alkanes in the presence of steam and a catalyst composition containing zinc aluminate, a tin oxide and platinum, wherein the zinc aluminate support material has been prepared by calcining zinc oxide and a hydrated alumina (so as to alleviate coking during the dehydrogenation process).
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: June 15, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Francis M. Brinkmeyer, Kelly B. Savage, Gyanesh P. Khare, Donald H. Kubicek
  • Patent number: 5208405
    Abstract: A process for selectively hydrogenating C.sub.4 -C.sub.10 diolefins to the corresponding monoolefins is carried out with a catalyst comprising (a) nickel metal and/or compound(s), (b) silver metal and/or compound(s), and (c) a solid inorganic support material (preferably alumina).
    Type: Grant
    Filed: March 3, 1992
    Date of Patent: May 4, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Tin-Tack P. Cheung, Marvin M. Johnson
  • Patent number: 5202519
    Abstract: A catalyst composition is prepared by mixing at least an aluminum halide (preferably AlCl.sub.3), at least one copper(II) salt (preferably CuCl.sub.2), calcium aluminate and at least one alcohol (preferably ethanol), shaping the mixture, and drying the shaped particles. The thus-obtained catalyst composition is employed in the isomerization of alkanes and/or cycloalkanes.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: April 13, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Gyanesh P. Khare
  • Patent number: 5202521
    Abstract: A selective absorption process for separating C.sub.2 -C.sub.4 alkenes (in particular ethylene) from C.sub.1 -C.sub.5 alkanes with a liquid extractant comprising dissolved copper(I) compound(s), in particular dissolved Cu(I) hydrocarbonsulfonate(s), is carried out in a one-column operation, wherein an overhead product is withdrawn which contains alkene(s) at a lower concentration than the feed, a side product is withdrawn which contains alkene(s) at a higher concentration than the feed, and a bottoms stream is withdrawn which contains primarily the liquid extractant.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: April 13, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Ronald E. Brown, Robert L. Hair
  • Patent number: 5192724
    Abstract: A spent metal contaminated zeolite-containing catalytic cracking catalyst composition is reactivated by a process which comprises contacting with (a) dissolved lactic acid and either (b1) at least one dissolved calcium compound or, alternatively, (b2) at least one dissolved tin compound and at least one dissolved phosphorus compound.
    Type: Grant
    Filed: March 17, 1992
    Date of Patent: March 9, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Chia-Min Fu, Michael K. Maholland
  • Patent number: 5191151
    Abstract: A process for separating C.sub.2 -C.sub.4 alkenes from C.sub.1 -C.sub.6 alkanes comprises the presence of water vapor in the alkene/alkane feed and the use of an Ag.sup.+ -exchanged sulfonated copolymer of tetrafluoroethylene and perfluorovinyl ether having been prepared by one of several specific ion-exchange methods.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: March 2, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Odd I. Eriksen, Elin Aksnes, Ivar M. Dahl, Fu-Ming Lee
  • Patent number: 5188995
    Abstract: A spent metal-contaminated zeolite-containing catalytic cracking catalyst is reactivated by a process which comprises contacting the spent catalyst with at least one dissolved carboxylic acid and at least one antimony compound.
    Type: Grant
    Filed: March 24, 1992
    Date of Patent: February 23, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Michael K. Maholland, Chia-Min Fu, Richard E. Lowery
  • Patent number: 5180848
    Abstract: P,P-dihydrocarbylphosphinoacetic acids are prepared by reacting a 2-methyl-4,4-dialkyl-2-oxazoline (preferably 2,4,4-trimethyl-2-oxazoline) with a basic alkali metal compound (preferably potassium hydride), followed by coupling with at least one halodihydrocarbylphosphine (preferably chlorodiphenylphosphine or chlorodiethylphosphine or chlorodi(t-butyl)phosphine or chlorodicyclohexylphosphine), and subsequent hydrolysis under acidic conditions.
    Type: Grant
    Filed: November 7, 1991
    Date of Patent: January 19, 1993
    Assignee: Phillips Petroleum Company
    Inventor: An-hsiang Wu
  • Patent number: 5180485
    Abstract: Indole impurities are removed from hydrocarbon-containing fluids by means of a magnesia-containing sorbent material.
    Type: Grant
    Filed: September 10, 1991
    Date of Patent: January 19, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Filippo Pennella, Fan-Nan Lin, Marvin M. Johnson
  • Patent number: 5179063
    Abstract: A composition (being effective for removing chloride ions from liquids) comprises at least one hydrotalcite and 3-6 weight percent of at least one sodium polyphosphate. Preferably, this composition is prepared by a process comprising the step of calcining a mixture of at least one hydrotalcite and 3-6 weight percent of at least one sodium polyphosphate for about 10-20 hours at a temperature of about 370.degree.-480.degree. C.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: January 12, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Jesse R. Harris, Gary A. Delzer, Randall A. Porter