Patents Represented by Law Firm Keil, Thompson & Shurtleff
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Patent number: 4154755Abstract: N',N'-disubstituted N-(2-cyanophenyl)-formamidines are manufactured by reacting isatoic anhydrides with ammonia and then with a mixture of acid halides and formamides.The N-(2-cyanophenyl)-formamidines which may be manufactured by the process of the invention are valuable starting materials for the manufacture of dyes, crop protection agents and drugs.Type: GrantFiled: May 13, 1977Date of Patent: May 15, 1979Assignee: BASF AktiengesellschaftInventors: Dieter Schneider, Horst Scheuermann
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Patent number: 4139641Abstract: Agents for preserving and ensiling animal feedstuffs and which contain one or several furan or thiophene derivatives, and the use thereof. These furan or thiophene derivatives have the general formula ##STR1## WHERE X denotes oxygen or sulfur, R denotes the radicals --CHO, --CN or --COOR.sup.3, or the vinylogous radicals --CH.dbd.CH--CHO, --CH.dbd.CH--C.tbd.N or --CH.dbd.CH--COOR.sup.3, R.sup.3 denoting hydrogen, a cation equivalent or alkyl of from 1 to 4 carbon atoms, and n denotes one of the integers 0, 1, 2 and 3.Type: GrantFiled: September 19, 1977Date of Patent: February 13, 1979Assignee: BASF AktiengesellschaftInventors: Bernd Zeeh, Johann Jung, Eberhard Ammermann
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Patent number: 4138591Abstract: Alkylphenols are manufactured by reacting phenols with olefins, stripping the reaction mixture by means of an inert gas, cooling the phenol-containing gas mixture and removing the unconverted phenol. The products are starting materials for the manufacture of dyes, pesticides, pharmaceuticals, emsulfiers, dispersing agents, stabilizers, antioxidants, plasticizers, corrosion inhibitors, disinfectants, seed dressings, stabilizers against ageing, crop protection agents and scents.Type: GrantFiled: October 19, 1977Date of Patent: February 6, 1979Assignee: BASF AktiengesellschaftInventors: Karl G. Baur, Hans Hellbach, Rolf Platz, Kurt Taglieber
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Patent number: 4138560Abstract: Melamine synthesis waste gases are first treated for the removal of melamine by condensation. The waste gases are then treated with urea-containing melts which are cooled indirectly. At least parts of said indirect cooling takes place together with the treatment of the reaction waste gases with the urea-containing melts in a single zone.Type: GrantFiled: December 27, 1977Date of Patent: February 6, 1979Assignee: BASF AktiengesellschaftInventors: Engelbert Hillenbrand, Hermann D. Fromm, Alfred Widmann
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Patent number: 4137261Abstract: N-Vinyl-N-alkyl-carbamic acid chlorides are manufactured by reacting crude Schiff bases, which have advantageously been manufactured in the presence of pentane, with phosgene and tertiary amines, treating the reaction mixture with water and then isolating the end product, after having separated off the aqueous phase containing the amine salt. The products are starting materials for the manufacture of surface-coating intermediates, plastics, paints and crop protection agents.Type: GrantFiled: December 27, 1976Date of Patent: January 30, 1979Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Koenig, Christian Reitel, Dietrich Mangold
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Patent number: 4137213Abstract: Pigment formulations and their use.The formulations contain pigments, organic solvents and from 10 to 80% by weight of a wetting agent consisting of a non-ionic organic compound which has a viscosity of from 500 to 10,000 mPa.s and has been produced by reacting an alkylated amide/formaldehyde reaction product and an epoxy resin, which may or may not be modified, in a weight ratio of from 9:1 to 1:9. They are used as additives in surface-coating binders, especially in cationic electrocoating finishes.Type: GrantFiled: January 31, 1977Date of Patent: January 30, 1979Assignee: BASF AktiengesellschaftInventors: Fritz E. Kempter, Erich Gulbins, Armin Haag, Ruprecht Kroker
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Patent number: 4137212Abstract: A flameproofed nylon molding composition which can be processed by thermoplastic methods and which contains, as the flameproofing agent, from 5 to 30% by weight of brominated styrene oligomers and a synergistic metal oxide. The compositions may be used for the manufacture of injection moldings for the electrical industry.Type: GrantFiled: November 30, 1977Date of Patent: January 30, 1979Assignee: BASF AktiengesellschaftInventors: Rainer Theysohn, Klaus Penzien, Wolfgang Seydl, Rolf Wurmb, Horst Reimann, Claus Cordes, Hans-Josef Sterzel
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Patent number: 4135909Abstract: New and valuable salts of phosphonic acids whose cationic components are ammonium radicals, agents for influencing the growth of plants with these salts, and a process for their manufacture.Type: GrantFiled: December 29, 1976Date of Patent: January 23, 1979Assignee: BASF AktiengesellschaftInventors: Johann Jung, Karl Kiehs, Bernd Zeeh, Hans Theobald
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Patent number: 4136100Abstract: Dyes of the formula ##STR1## where Y is alkyl of 3 to 18 carbon atoms or phenyl which is unsubstituted or substituted by chlorine, bromine, alkoxy of 1 to 4 carbon atoms, alkoxycarbonyl (where alkoxy is of 1 to 4 carbon atoms), phenoxy, benzoylamino, trifluoromethyl or alkylcarbonyl (where alkyl is of 1 to 6 carbon atoms), X is hydrogen or ##STR2## where R is alkyl of 1 to 17 carbon atoms, phenylamino, phenyl, alkoxycarbonyl-alkyl (where alkoxy is of 1 to 8 carbon atoms and alkyl of 2 to 4 carbon atoms), alkoxy of 1 to 10 carbon atoms or alkoxyalkyl of a total of 3 to 12 carbon atoms, A is chlorine, bromine, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms, B is hydrogen or nitro and n is 0, 1, 2 or 3. On cellulose and cellulose-containing textiles, the dyes, used in the presence of swelling agents, give bluish violet to greenish blue dyeings having very good fastness properties.Type: GrantFiled: September 19, 1977Date of Patent: January 23, 1979Assignee: BASF AktiengesellschaftInventor: Gerhard Epple
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Patent number: 4135992Abstract: An aqueous cyanide-free alkaline zinc bath for electroplating metallic surfaces with mirror-bright zinc coatings, which bath contains zinc ions, alkali metal hydroxides and, as the brightener, a polyalkylenepolyamine which is at least partially alkylated, with alkyl of 1 to 3 carbon atoms, at the basic nitrogens.Type: GrantFiled: November 16, 1977Date of Patent: January 23, 1979Assignee: BASF AktiengesellschaftInventors: Rolf Fikentscher, Klaus Glaser, Guenther Gotsmann, Werner Streit
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Patent number: 4136124Abstract: Dialkyl-ketals are manufactured by reacting ketones with alkanols in the presence of an acid condensing agent and of an at least equivalent amount, based on the ketone, of anhydrous calcium sulfate.Type: GrantFiled: August 1, 1977Date of Patent: January 23, 1979Assignee: BASF AktiengesellschaftInventors: Helmut Zinke-Allmang, Walter Scheidmeir
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Patent number: 4135043Abstract: Polymers in powder form are manufactured by polymerizing water-soluble ethylenically unsaturated monomers, which form hydrophilic polymers, in a powder bed of polymers of water-soluble ethylenically unsaturated compounds in the presence of polymerization initiators and water as an auxiliary liquid, the water being entirely or partially removed from the polymerization zone by evaporation during the polymerization.Type: GrantFiled: August 1, 1977Date of Patent: January 16, 1979Assignee: BASF AktiengesellschaftInventors: Bernd Kast, Joachim Stedefeder, Axel Sanner, Hans-Uwe Schenck, Richard Thoma, Hermann Fischer
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Patent number: 4134813Abstract: A photopolymerizable composition which contains one or more olefinically unsaturated compounds and from 0.2 to 20% by weight (based on the unsaturated compound(s)) of a photoinitiator, with or without conventional additives, the photoinitiator being a mixture of one or more aromatic carbonyl compounds of the general formula (A) ##STR1## where Ar is an ortho-arylene radical which may or may not be substituted by one or more radicals R.sup.1 to R.sup.4, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each is H, alkyl or 1 to 5 carbon atoms, phenyl, halogen, alkoxy of 1 to 5 carbon atoms, alkaryl of 7 to 11 carbon atoms, aralkyl of 7 to 11 carbon atoms or --CO.sub.2 R.sup.9, where R.sup.9 is alkyl of 1 to 5 carbon atoms, and n is 0 or 1, and an amine, with or without an aromatic carbonyl compound which differs from (A).This photopolymerizable composition is particularly suitable for the manufacture of photopolymer printing plates and UV-curing printing inks.Type: GrantFiled: December 8, 1977Date of Patent: January 16, 1979Assignee: BASF AktiengesellschaftInventors: Werner Kuesters, Rolf Osterloh, Manfred Jacobi
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Patent number: 4134932Abstract: Surface-coating binders for cathodic electrocoating which comprise a protonized heat-curable reaction product (A), substantially free from epoxide groups, of(a) one or more Mannich bases, prepared from(a.sub.1) one or more polyhydric condensed phenols which may or may not contain ether groups.(a.sub.2) one or more secondary amines which contain one or more hydroxyalkyl groups, with or without one or more secondary amines which do not contain such groups, and(a.sub.3) formaldehyde or a formaldehyde donor, with(b) one or more epoxy resins,Which binder also contains from 1 to 40% by weight, based on the total of (A) + (B), of a water-insoluble non-ionic resin (B), free from epoxide groups and containing urethane groups, which resin has been obtained by reacting a partially blocked diisocyanate or higher polyisocyanate with a reaction product of a polyepoxide and one or more low molecular weight compounds containing SH and/or OH groups.Type: GrantFiled: March 9, 1978Date of Patent: January 16, 1979Assignee: BASF AktiengesellschaftInventors: Fritz E. Kempter, Heinrich Hartmann, Erich Gulbins
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Patent number: 4134889Abstract: Manufacture of glycinonitriles by reacting amines with carbonyl compounds and hydrogen cyanide under specific reaction conditions in respect of the temperature, reaction time and hydrogen cyanide concentration.The glycinonitriles obtainable by the process of the invention are antioxidants and valuable starting materials for the manufacture of dyes, fungicides, bactericides, textile auxiliaries and inhibitors for use in antifreezes.Type: GrantFiled: May 2, 1977Date of Patent: January 16, 1979Assignee: BASF AktiengesellschaftInventors: Harry Distler, Erwin Hartert, Helmut Schlecht
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Patent number: 4134915Abstract: Formamide is manufactured continuously from methyl formate and gaseous ammonia. The reaction is carried out in a reactor at from 30 to 90.degree. C, from 5 to 20% by volume of the reactor output is drawn off continuously and fed to the formamide working-up stage, and the remainder of the reactor output is cooled, in an external circuit maintained by means of a pump, to from 25 to 60.degree. C and is mixed with the amount of fresh methyl formate required for steady-state operation, after which the appropriate amount of gaseous ammonia is introduced into the stream of liquid through a jet, by the sucking-jet principle, and the stream of liquid is recycled to the reactor.Type: GrantFiled: May 5, 1977Date of Patent: January 16, 1979Assignee: BASF AktiengesellschaftInventors: Heinz Hohenschutz, Max Strohmeyer, Manfred Herr, Hans Kiefer
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Patent number: 4133911Abstract: The invention relates to an improved process for the manufacture of magnetic discs carrying very thin magnetic layers, by applying a fluid dispersion of magnetic materials in a binder mixture to rigid base discs by the spin-coating process. Above the side of the base disc which is to be provided with the magnetic layer, there are arranged means which produce an aerodynamic boundary layer above the discs during rotation of the latter. This avoids the formation of surface irregularities and of coating streaks during production of the layer by spin-coating.Type: GrantFiled: December 16, 1975Date of Patent: January 9, 1979Assignee: BASF AktiengesellschaftInventors: Eberhard Koester, Paul Deigner, Roland Falk, Karl Uhl, Dieter Schaefer, Dieter Mayer, Herbert Motz, Peter Felleisen
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Patent number: 4133946Abstract: New polymers which contain 1,6,6-trimethylnorpinanyl-2-methyl or 3-pinanylmethyl groups, i.e. macromolecular compounds in which the side chains contain optically active groups, so that the polymers may also be optically active. The new polymers may be used for the production of moldings, coatings and adhesives and as optical modifiers for films.Type: GrantFiled: March 20, 1978Date of Patent: January 9, 1979Assignee: BASF AktiengesellschaftInventors: Hardo Siegel, Herbert Naarmann
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Patent number: 4133828Abstract: Dimethylaminobenzenesulfonates are manufactured by reacting nitrobenzenesulfonates with formaldehyde and hydrogen in the presence of a hydrogenation catalyst containing a metal of atomic number from 24 to 29 and of phosphoric acid and water at a pH of from 2 to 3.5, at from 50 to 150.degree. C, under a pressure of at least 40 bars, with a residence time of from 1 to 15 minutes. The products are starting materials for the synthesis of dyes, especially of rhodamine dyes, oxazine dyes and reactive dyes, and also of pharmaceuticals and pesticides.Type: GrantFiled: July 22, 1976Date of Patent: January 9, 1979Assignee: BASF AktiengesellschaftInventors: Horst Scheuermann, Helmut Hoch
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Patent number: 4133806Abstract: Azo dyes represented by the formula ##STR1## in which R.sup.2 represents alkyl of 1 to 4 carbon atoms or may also represent ethyl or propyl substituted by hydroxy or alkoxy of 1 to 4 carbon atoms, and R.sup.3 is C.sub.4 H.sub.9 --, CH.sub.3 OCH.sub.2 CH.sub.2 --, CH.sub.3 (CH.sub.2).sub.4 --, CH.sub.3 (CH.sub.2).sub.5 --, CH.sub.3 (CH.sub.2).sub.7 --, ##STR2## or cycloalkyl of 5 to 8 carbon atoms. These dyes have excellent fastness properties and are especially useful for dyeing cellulose ester and polyester fibrous materials.Type: GrantFiled: June 3, 1974Date of Patent: January 9, 1979Assignee: BASF AktiengesellschaftInventor: Gerhard Gnad