Abstract: A process for the manufacture of copolymers of ethylene with tert-butyl acrylate and acrylic acid at from 200.degree. to 350.degree. C under pressures above 800 atmospheres using mean residence times of up to at most 100 seconds, in which the reaction mixture obtained from the polymerization is kept for from 2 to 10 minutes at from 200.degree. to 250.degree. C under a pressure of not more than 500 atmospheres. Terpolymers are obtained which may be used as hot-melt adhesives in the form of thin and extremely homogeneous films.
Type:
Grant
Filed:
November 1, 1976
Date of Patent:
October 24, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Pfleger, Klaus Boettcher, Wieland Zacher, Dirk Juza
Abstract: In the manufacture of flocked textiles by applying a polymer emulsion, flocking and drying, a heat-sensitized polymer emulsion is used and the emulsion coat is first only gelled, by heating, in the zone adjoining the textile substrate, and is then flocked and dried at an elevated temperature.
Type:
Grant
Filed:
May 5, 1975
Date of Patent:
October 24, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Fickeisen, Gert Elschnig, Hanns-Dietmar Haertl, Kurt Wendel, Klaus Eisentraeger
Abstract: Cyclic esters of 3,4-dihydroxy-thiophene-1,1-dioxide and of the corresponding cyclopentadienone compound, and their manufacture. The compounds can be used as "solid forms" of phosgene, thiophosgene or oxalyl chloride, or as acyl transfer agents.
Type:
Grant
Filed:
May 31, 1977
Date of Patent:
October 24, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Steglich, Oswald Hollitzer, Alfred Seewald
Abstract: Production of new 2-(o-alkylthiophenyl)-1,3-diazacycloalkene hydrohalides by reaction of a benzo-thietane-2-spiro-2'-(1',3'-diazacycloalkane) with an alkyl halide, and the new 2-(o-alkylthiophenyl)-1,3-diazacycloalkene hydrohalides which are pharmaceuticals, auxiliaries for the textile and rubber industries, plant protection agents and starting materials for the production of pharmaceuticals, plant protection agents and dyes.
Type:
Grant
Filed:
June 17, 1977
Date of Patent:
October 24, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Helmut Hagen, August Amann, Hubert Giertz
Abstract: A process for the manufacture of a titanium-containing component of a catalyst for the polymerization of monoolefins by the Ziegler-Natta method by milling (a) a titanium trichloride/aluminum trichloride complex and (b) a particular ether with one another, in which process (1) a vibratory ball mill producing a particular milling acceleration is used, (2) until from 6 to 85% of the aluminum trichloride originally present in a bonded form in the titanium-containing compound (a) have been eliminated from the said compound (a). Polyolefins of high stereoregularity can be obtained in a high specific yield by means of the catalyst component manufactured according to the invention.
Type:
Grant
Filed:
November 30, 1977
Date of Patent:
October 17, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Mueller-Tamm, Hans Schick, James F. R. Jaggard, Johann Nickl
Abstract: To isolate ammonia from gas mixtures containing ammonia and carbon dioxide, the gas mixture is first partially absorbed in a solvent, with residence times of at most 0.1 second, and the non-absorbed gas is then separated from the solution obtained. The solution is then subjected to a first desorption stage, in which only the ammonia present in an excess over a molar ratio of 3 parts of ammonia to 1 part of carbon dioxide is expelled by heating, and the entrained carbon dioxide is washed out of the expelled ammonia by means of solutions containing free ammonia. The solution remaining after the first desorption stage is substantially freed from ammonia and carbon dioxide in a second desorption stage and the expelled gas, containing solvent, together with fresh gas mixture is fed to the adsorption stage, while the solvent obtained from the second desorption stage is employed for the absorption.
Type:
Grant
Filed:
October 12, 1977
Date of Patent:
October 17, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans Gettert, Hermann Dieter Fromm, Martin Molzahn, Ernst-Juergen Schier, Hans Henning Schneehage
Abstract: A process for the simultaneous texturizing and entangling of filament bundles by treating filament bundles of synthetic, high-molecular weight materials with a heated fluid in two tubular treatment chambers, in which process spatial or periodic irregularities are produced, in the treatment zones, in the flow of fluid and/or filament bundles. Preferably, a certain range of values of a volume mass flow factor is adhered to.
Type:
Grant
Filed:
December 22, 1976
Date of Patent:
October 17, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Martin, Wolfgang Bauer, Dieter Herion, Hermann Linge, Hans Knopp
Abstract: Storage-stable, liquid, only slightly colored polyisocyanates possessing carbodiimide groups and having an isocyanate content of from about 25 to 35% by weight, based on total weight; these products are obtained by condensing polyisocyanates in the presence of phospholines, phospholidines and/or their oxides, and stopping the condensation and stabilizing the condensation products with the Lewis acids, aromatic carboxylic acid halides, aromatic sulfonic acid esters and/or alkyl sulfates.
Type:
Grant
Filed:
January 28, 1977
Date of Patent:
October 17, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Frank Peter Woerner, Peter T. Kan, Georg Falkenstein
Abstract: A process for the manufacture of reactive polymers of vinyl monomers by reacting the latter, or the polymers formed therefrom, with compounds which form free radicals.The latter compounds are tetrakis-(organylthio)-methanes, 1,1,2,2-tetrakis-(organylthio)-ethanes or hexakis-(organylthio)-ethanes.The polymers obtained can readily be modified, e.g. by oxidation or quaternisation.
Type:
Grant
Filed:
May 2, 1977
Date of Patent:
October 17, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Pohlemann, Herbert Naarmann, Dieter Seebach
Abstract: New acetals, containing a 6-membered ring, of 2-methyl-2,4-dialkoxy-3-buten-1-al, are obtained by reacting the corresponding 2-methyl-2-alkoxy-3-butyn-1-al-acetals with a mixture of the appropriate alcohol and an alkali metal alcoholate of the said alcohol at from 100.degree. to 200.degree. C. The acetals are intermediates for the preparation of carotinoid-based physiologically safe food dyes.
Abstract: A polyamide-imide precondensate which is solid at room temperature, but is fusible and soluble in polar solvents. It is manufactured by first condensing 1 mole of diamine with 2 moles of tricarboxylic acid anhydride in a diol as the solvent, to give a diimide-dicarboxylic acid, then esterifying the diimide-dicarboxylic acid with the diol and finally effecting the polycondensation by adding 1 mole of diamine per mole of diester. The precondensate may be used, as a melt, as a solution in organic solvents or as an aqueous dispersion, for coating electrical conductors.
Type:
Grant
Filed:
June 7, 1976
Date of Patent:
October 17, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Jenoe Kovacs, Hans Jung, Matthias Marx, Herbert Spoor
Abstract: P-aminoazo dyes of the formula: ##STR1## in which D is a benzoisothiazolyl group;B.sup.1 is hydrogen, methyl, ethyl, methoxy, ethoxy;B.sup.2 is hydrogen, methyl, ethyl, methoxy, ethoxy, chloro, bromo, C.sub.1 to C.sub.4 alkanoylamino or C.sub.1 to C.sub.4 alkoxycarbonylamino;R.sup.1 is the radical ##STR2## C.sub.1 to C.sub.4 alkyl optionally bearing hydroxy, C.sub.1 to C.sub.4 alkoxy, C.sub.1 to C.sub.4 alkanoyloxy, C.sub.1 to C.sub.4 alkoxycarbonyl, C.sub.1 to C.sub.4 alkanoylamino or chloro as a substituent, phenylethyl, phenoxyethyl or cyclohexyl and the group -A.sup.1 --CO--A.sup.2 represents acyl, acyloxy or acylamino derived from a carbonic acid derivative in which A.sup.
Type:
Grant
Filed:
February 9, 1976
Date of Patent:
October 10, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Guenter Hansen, Hermann Kaack, Norbert Grund
Abstract: Apparatus and process for thermal treatment of thermoplastic polymer multifile filaments embodying at least one stuffing chamber for forming at least one multifile filament into at least one tightly coherently packed filamentary body, feeding one or more of said filamentary bodies onto gas-permeable, slowly rotating drum on which it or they are conveyed in a side-by-side, spiral orientation by the rotating drum while a fluid, e.g., air is drawn through the filamentary bodies, said filamentary bodies being conveyed from the stuffing chamber at a constant rate and being deflected at a predetermined pitch angle before or during initial contact with the drum surface.
Abstract: A process for the manufacture of 6-aminocaproamide, wherein methyl or ethyl 5-cyanovalerate is reacted with excess ammonia at temperatures of from 25.degree. to 200.degree. C and the resulting 5-cyanovaleramide is hydrogenated at temperatures of from 25.degree. to 200.degree. C and pressures of from 50 to 300 bars in the presence of ammonia and of supported cobalt and/or nickel catalysts. 6-Aminocaproamide is suitable for the manufacture of caprolactam.
Type:
Grant
Filed:
December 27, 1976
Date of Patent:
October 10, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Martin Weitz, Rolf Fischer, Franz Josef Broecker
Abstract: In a secondary battery employing an aqueous lead salt solution as the electrolyte, salts of manganese, cobalt, nickel, copper, thallium, bismuth and/or antimony are additionally present in concentrations of from 0.1 to 100 mmole/l.
Abstract: An azo compound useful in copying processes of the formula ##STR1## where R.sup.1 is hydrogen or alkyl of 1 to 4 carbon atoms, R.sup.2 and R.sup.3 are each alkyl of 1 to 4 carbon atoms, or one of the radicals R.sup.1, R.sup.2 and R.sup.3 is unsubstituted phenyl or phenyl substituted by alkyl of 1 to 4 carbon atoms, methoxy or ethoxy, and A denotes ##STR2## where R.sup.4 and R.sup.5 are each hydrogen; alkyl of 1 to 8 carbon atoms which may be substituted by hydroxy, alkoxy, halogen or alkoxycarbonyl; cyanoethyl; alkylcarbonyl with 1 to 3 carbon atoms in the alkyl; cyclohexyl; phenalkyl of 7 to 10 carbon atoms; or substituted or unsubstituted phenyl, or R.sup.4 is N,N-dialkylaminoalkyl or N,N-bisphenalkylaminoalkyl, or the group ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring which may contain an --O-- or --S-- group as ring member, Y is hydroxy, alkyl, alkoxy, chlorine, bromine or alkylcarbonylamino, n is 0, 1 or 2, R.sup.6 and R.sup.
Abstract: Dyes of the formula ##STR1## where X is chlorine or bromine, Y is ##STR2## and n is 0, 1 or 2. On synthetic fiber materials, the dyes give clear blue colorations which are very fast to thermofixing and fast to light.
Type:
Grant
Filed:
May 2, 1977
Date of Patent:
October 10, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Gerhard Epple, Walter Himmele, Werner Fliege
Abstract: Formaldehyde is manufactured by oxidative dehydrogenation of methanol in the presence of a silver catalyst and of certain amounts of steam and formaldehyde, some formaldehyde and a part of the water being withdrawn from the reaction mixture and recycled. The formaldehyde manufactured by the process may be used as a disinfectant, tanning agent, reducing agent and starting material for the manufacture of synthetic resin, adhesives and plastics.
Type:
Grant
Filed:
September 16, 1975
Date of Patent:
October 10, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Albrecht Aicher, Hans Haas, Hans Diem, Christian Dudeck, Fritz Brunnmueller, Gunter Lehmann
Abstract: Pavement joint structures utilizing laterally spaced, elongated metal frames with a four-sided, compartmented, elongated, elastomer seal locked in the frames and spanning the space, the seal having a double arch, nadir-to-apex internal web structure.
Abstract: Methacrylic acid and methyl methacrylate are manufactured by reacting, respectively, propionic acid and methyl propionate with dimethoxymethane in the presence of catalysts based on phosphates and/or silicates of magnesium, calcium, aluminum, zirconium, thorium and/or titanium, and in the presence of from 0 to 0.5 mole of water per mole of the acetal.
Type:
Grant
Filed:
March 25, 1977
Date of Patent:
October 3, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Gerd Fouquet, Franz Merger, Rolf Platz, Karl Baer