Abstract: A superheater in a power plant that superheats steam to operation conditions exceeding an operating limit of an associated steam-producing boiler. The superheater combusts oxygen and fuel with cooled recycled combustion gas to produce a CO2-rich combustion product gas stream at a fixed temperature. The combustion gas is used as the heat transfer fluid in the superheater's heat exchanger. The CO2-rich flue gas stream allows for efficient capture of substantially pure CO2. The superheater may be retrofitted to an existing power plant as a separate component, external to the boiler. The plant may thus have its electrical power output increased, while its overall CO2 emissions per nit of generated power is decreased, even when inexpensive, readily-available fossil fuels are used as the primary fuel for filing the boiler and/or the superheater.

Abstract: Method for supplying a high purity gas product comprising providing a first gas stream including a major component and at least one impurity component, determining the concentration of the at least one impurity component, and comparing the concentration so determined with a reference concentration for that component. When the value of the concentration so determined is less than or equal to the reference concentration, the first gas stream is utilized to provide the high purity gas product. When the value of the concentration so determined is greater than the reference concentration, a second gas stream comprising the major component is provided and the first and second gas streams are mixed to yield a mixed gas stream having a concentration of the at least one impurity component that is less than the reference concentration.

Abstract: A staged steam hydrocarbon reformer is disclosed having a chamber within which convectively heated reformer stages are enclosed. The reformer stages are tubes containing steam reforming catalyst. The stages are in serial fluid communication with one another through mixing vessels positioned between each stage. The first reforming stage is fed a mixture of steam and a gaseous hydrocarbon. Partially reformed gases having increased hydrogen concentration are produced at each stage and are mixed with additional gaseous hydrocarbon and optionally steam in the mixing vessels. Collection and distribution manifolds provide fluid communication between the reformer stages and the mixing vessels. A method is also disclosed in which partially reformed gases from a preceding stage are mixed with gaseous hydrocarbon and steam having a lower steam to carbon ratio than the fresh feed to the previous stage.

Abstract: A gas flow isolation device includes a gas flow isolation valve movable from an opened condition to a closed condition. The module isolation valve in one embodiment includes a rupture disk in flow communication with a flow of gas when the module isolation valve is in an opened condition. The rupture disk ruptures when a predetermined pressure differential occurs across it causing the isolation valve to close. In one embodiment the valve is mechanically linked to the rupture disk to maintain the valve in an opened condition when the rupture disk is intact, and which permits the valve to move into a closed condition when the rupture disk ruptures. In another embodiment a crushable member maintains the valve in an open condition, and the flow of gas passed the valve upon rupturing of the rupture disk compresses the crushable member to close the isolation valve.

Abstract: An ion transport membrane system comprising (a) a pressure vessel having an interior, an inlet adapted to introduce gas into the interior of the vessel, an outlet adapted to withdraw gas from the interior of the vessel, and an axis; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region; and (c) one or more gas flow control partitions disposed in the interior of the pressure vessel and adapted to change a direction of gas flow within the vessel.

Abstract: Method of making an electrochemical device for the recovery of oxygen from an oxygen-containing feed gas comprising (a) preparing a green electrochemical device by assembling a green electrolyte layer, a green anode layer in contact with the green electrolyte layer, a green cathode layer in contact with the green electrolyte layer, a green anode-side gas collection interconnect layer in contact with the green anode layer, and a green cathode-side feed gas distribution interconnect layer in contact with the green cathode layer; and (b) sintering-the green electrochemical device by heating to yield a sintered electrochemical device comprising a plurality of sintered layers including a sintered anode-side gas collection interconnect layer in contact with the anode layer and adapted to collect oxygen permeate gas, wherein each sintered layer is bonded to an adjacent sintered layer during sintering.

Abstract: Seal assembly comprising (a) two or more seal elements, each element having having a coefficient of thermal expansion; and (b) a clamping element having a first segment, a second segment, and a connecting segment between and attached to the first and second segments, wherein the two or more seal elements are disposed between the first and second segments of the clamping element. The connecting segment has a central portion extending between the first segment of the clamping element and the second segment of the clamping element, and the connecting segment is made of a material having a coefficient of thermal expansion. The coefficient of thermal expansion of the material of the connecting segment is intermediate the largest and smallest of the coefficients of thermal expansion of the materials of the two or more seal elements.

Abstract: A diagnostic method for a gas supply system includes: determining a desired ramp rate for filling a vessel from a supply of compressed gas; monitoring the actual pressure of gas entering the vessel; and discontinuing the flow of gas into the vessel when the actual pressure deviates from the intended pressure at the desired ramp rate by an undesired amount. A system for carrying out the method includes a flow controller for controlling operation of the supply system to deliver compressed gas from a source to a vessel through a supply line at a desired ramp rate. The system employs a pressure monitor downstream of a control valve for measuring the pressure of gas directed into the vessel and transmitting pressure-related data to the flow controller, which closes the control valve to discontinue filling of the vessel if the actual pressure exceeds a permissible deviation from the intended pressure.

Abstract: Battery charging system comprising a hydrogen source module adapted to provide gaseous hydrogen; a hydrogen fuel cell power module comprising a hydrogen fuel cell and a power delivery outlet unit adapted to transfer power generated by the fuel cell to a secondary battery for recharging the secondary battery; and coupling and transfer means adapted to connect and disconnect the hydrogen source module and the hydrogen fuel cell power module.

Abstract: Hydrogen is liquefied by a process comprising pre-cooling hydrogen feed gas by indirect heat exchange against pressurized liquefied natural gas (“LNG”) to produce pre-cooled hydrogen feed gas and pressurized natural gas, further cooling at least a portion of said pre-cooled hydrogen feed gas by indirect heat exchange against at least one refrigerant to produce condensable hydrogen gas and expanding at least a portion of said condensable hydrogen gas to produce at least partially condensed hydrogen. One advantage of such a process is that the power consumed during liquefaction is significantly less than that consumed in existing hydrogen liquefaction processes which pre-cool hydrogen feed gas by indirect heat exchange against other refrigerants, e.g. liquid nitrogen.

Abstract: Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.

Abstract: Planar ceramic membrane assembly comprising a dense layer of mixed-conducting multi-component metal oxide material, wherein the dense layer has a first side and a second side, a porous layer of mixed-conducting multi-component metal oxide material in contact with the first side of the dense layer, and a ceramic channeled support layer in contact with the second side of the dense layer.

Abstract: Method of operating a pressure swing adsorption system having a plurality of parallel adsorber vessels and a plurality of valves and gas manifolds adapted to introduce gas into each adsorber vessel and withdraw gas from each adsorber vessel in a cyclic series of sequential process steps. A leaking valve may be identified by (1) determining a value of an operating parameter that is a function of the mass of gas provided to a receiving adsorber vessel or withdrawn from an adsorber vessel during a selected process step, portion of a process step, or series of process steps; (2) determining the deviation of the value of the operating parameter from a predetermined reference value; and (3) using the magnitude and direction of the deviation to determine whether any valves are leaking.

Abstract: A method and a facility for the treatment of waste from concentrated animal feed operations are disclosed. The method includes receiving manure at a central location, digesting the manure and producing therefrom combustible gases, solid matter and water containing dissolved organic pollutants. The combustible gases are used to provide energy and the water is separated from the solid matter. The solid matter is dried to produce a useful bedding material and the water is treated using an activated sludge aeration system to reduce the dissolved organic pollutants to carbon dioxide, bacteria and water. The facility includes various means for executing the method and includes an ultrasonic treatment station for disrupting bacteria cell walls to improve digestion efficiency.

Abstract: Method of operating an oxygen-permeable mixed conducting membrane having an oxidant feed side, an oxidant feed surface, a permeate side, and a permeate surface, which method comprises controlling the differential strain between the permeate surface and the oxidant feed surface at a value below a selected maximum value by varying the oxygen partial pressure on either or both of the oxidant feed side and the permeate side of the membrane.

Abstract: The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

Abstract: A process for adiabatically prereforming a feedstock, includes: providing an adiabatic reactor; providing a catalyst containing 1-20 wt. % nickel and 0.4-5 wt. % potassium, wherein the catalyst has an overall catalyst porosity of 25-50% with 20-80% of the overall catalyst porosity contributed by pores having pore diameters of at least 500 ?; providing the feedstock containing natural gas and steam, wherein the natural gas contains an initial concentration of higher hydrocarbons, and a ratio of steam to natural gas in the feedstock is from 1.5:1 to 5:1; preheating the feedstock to a temperature of 300-700° C. to provide a heated feedstock; providing the heated feedstock to the reactor; and producing a product containing hydrogen, carbon monoxide, carbon dioxide, unreacted methane, and steam, wherein said product contains a reduced concentration of higher hydrocarbons less than the initial concentration of higher hydrocarbons, to prereform the feedstock.

Abstract: Method for supplying a high purity gas product comprising providing a first gas stream including a major component and at least one impurity component, determining the concentration of the at least one impurity component, and comparing the concentration so determined with a reference concentration for that component. When the value of the concentration so determined is less than or equal to the reference concentration, the first gas stream is utilized to provide the high purity gas product. When the value of the concentration so determined is greater than the reference concentration, a second gas stream comprising the major component is provided and the first and second gas streams are mixed to yield a mixed gas stream having a concentration of the at least one impurity component that is less than the reference concentration. The mixed gas stream is utilized to provide the high purity gas product.

Abstract: Process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen gas and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula AxByOn wherein A represents at least one metallic element having an oxidation state ranging from +1 to +3, inclusive, wherein the metallic element is capable of forming a metal carbonate; x is a number from 1 to 10, inclusive; B represents at least one metallic element having an oxidation state ranging from +1 to +7, inclusive; y is a number from 1 to 10, inclusive; and n represents a value such that the complex metal oxide is rendered electrically neutral.

Abstract: The current invention relates to a means for improving heat removal from the inside of an electrochemical device to the outer surface so as to reduce thermal stresses in the device, thereby allowing for increased oxygen production. A means for conducting heat toward the outer edge is provided. The means for conducting heat comprises at least one of silver, gold, platinum, rhodium, and palladium.