Patents Represented by Attorney Kevin T. Mansfields
  • Patent number: 6515175
    Abstract: Novel perfluoroalkyl-substituted mono-, di- and poly-amide compounds which are reaction products of a mono-, di- or polyamine of 60 to 2000 molecular weight with a perfluoroalkyl substituted unsaturated acid or its corresponding lower alkyl ester and optionally a non-fluorinated amino-reactive compound such as an acid, ester, anhydride, epichlorohydrin, isocyanate or urea, are useful as internally or externally applied paper sizes to impart oil and grease resistance to paper, and as oil proofing coatings on textiles, wood, masonry and the like, or as high-performance surface active agents.
    Type: Grant
    Filed: October 15, 2001
    Date of Patent: February 4, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Karl F. Mueller, Michael Bochnik, Marlon Haniff, John Jennings, Shobha Kantamneni
  • Patent number: 6514950
    Abstract: A description is given of the use of polyanionic and polyanionically-derivatised natural polysaccharides or non-derivatised natural polysaccharides for inhibiting alkaline phosphatase and of oral compositions for preventing bacterial plaque, which comprises (a) 0 to 10% by weight of at least one linear molecularly dehydrated polyphosphate salt, and (b) 0.0001 to 5% by weight of a polyanionic or polyanionically-derivatised natural polysaccharide.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: February 4, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Werner Baschong, Dietmar Hüglin, Peter Fankhauser, Gerd Heinemann
  • Patent number: 6511535
    Abstract: The invention relates to a method for printing fibrous textile materials using the ink-jet printing technique, wherein the fibrous materials are printed with an aqueous ink that comprises at least one acid dye according to claim 1 and that has a viscosity of from 1 to 40 mPa·s.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: January 28, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Roger Lacroix, Peter Scheibli, Mickael Mheidle
  • Patent number: 6503449
    Abstract: The present invention relates to a process for the elimination of microbial contamination from water-based suspensions of solid particles, especially organic and inorganic pigment dispersions, and the colourant formulations containing such suspensions.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: January 7, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Derek Stewart Hunter Smith
  • Patent number: 6504016
    Abstract: Reactive dyes of the formula (1) wherein the variables are as defined in the specification are especially suitable for dyeing cotton and yield dyeings having good all-round fastness properties.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: January 7, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Bruno Cortese
  • Patent number: 6500247
    Abstract: Black-dyeing aqueous inks having good black shades without a shade change in artificial light and outstanding lightfastness comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) the dye (B) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) and the dye (C) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formulae (V), (VI), (VII) or (VII) and one or more radicals of the f
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: December 31, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Althanassios Tzikas, Marcel Frick
  • Patent number: 6495122
    Abstract: The invention describes the use of micronized organic UV filters for preventing tanning and for lightening human skin and hair, and their use in cosmetic and pharmaceutical formulations. The micronized UV filters used according to the invention cover a broad UV spectrum and therefore have excellent sunscreen properties.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: December 17, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Fankhauser, Helmut Luther, Werner Baschong
  • Patent number: 6491731
    Abstract: A mixture of yellow azo- and azoxystilbene dyes having the shade of a C.I. Direct Yellow 11 dye is obtainable from the self-condensation of 4,4′-dinitro-2,2′-stilbenedisulfonic acid in the presence of an alkali metal hydroxide and an excess of formaldehyde beyond that needed for the conversion of 4,4′dinitro-2,2′-stilbenedisulfonic acid to Direct Yellow 6. Concentrated aqueous solutions of the dyes are obtainable by converting the sparingly soluble alkali metal salt of the dye into a water-soluble alkanolammonium salt by a double cation exchange via a lipophilic ammonium salt, in which process the double ion exchange is carried out in a two-phase system of methyl isobutyl ketone/water and using, for the first ion exchange a trialkylamine containing a total of 12 to 40 carbon atoms and, for the second ion exchange, a mono-, di- or trialkanolamine containing 2 to 4 carbon atoms in each alkyl moiety. The dyes are especially useful for dyeing paper.
    Type: Grant
    Filed: May 25, 2000
    Date of Patent: December 10, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Frederick Harold Gouzoules
  • Patent number: 6486110
    Abstract: The present invention provides a process for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: November 26, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Frank Bachmann, Josef Dannacher, Martin Studer, Beat Freiermuth, Cornelia Makowka, Peter Weingartner, Grit Richter, Gunther Schlingloff
  • Patent number: 6485559
    Abstract: The present Application relates to pigment colourants of formula wherein R1 is C1-C6alkyl, C1-C6alkoxy, phenoxy or halogen, R2 is hydrogen, C1-C6alkyl, C1-C6alkoxy, phenoxy, halogen, acylamino, —CH2NHacyl or the radical and R3 is C1-C6alkyl, C1-C6alkoxy, phenoxy or halogen, the ring A may be further substituted by —SO3−M+, wherein M+ is a cation, and the rings B and C may be unsubstituted or further mono- or poly-substituted by halogen, hydroxy, —SH, amino, C1-C6alkylamino, C1-C6alkyl, C1-C6alkoxy, phenoxy, acylamino, C1-C6thioalkyl or by thiophenyl, and the ring B may be substituted in the 5- or 8-position by a radical of formula wherein R1, R2 and R3 are as defined above, to a process for their preparation, and to their use in the mass-coloring of synthetic materials.
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: November 26, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Jean-Marie Adam
  • Patent number: 6482241
    Abstract: The present invention provides, as a first aspect, an asymmetric compound having the formula: in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; Xa and Xb are the same or different and each is NH2; NH(C1-C4alkyl); NH(C2-C4alkoxyalkyl); N(C1-C4alkyl)2; N(CH2CH2OH)2; a group NH—Z—NR1R2 in which Z is C2-C14alkylene or optionally substituted arylene, and R1 and R2 are the same or different and each is C1-C12alkyl or R1 and R2, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; an aminoacid residue; C1-C4alkoxy; hydroxy-substituted-C2-C4alkoxy; and Ya and Yb are the same or different and each is a substituted amino group having both UVA and UVB-absorbing properties having the formula: in which R3 is CN; SO2R5 in which R5 is, C1-C12alkyl, C1-C12alkoxy, NH2, NH(C1-C4alkyl), N(C1-C4alkyl)2, N(CH2CH2OH)2, C1-C4alkoxy or hydroxy-substituted-C2-C4alkoxy;
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: November 19, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Georges Metzger, Dieter Reinehr, Claude Eckhardt, Fabienne Cuesta
  • Patent number: 6472550
    Abstract: A process for the preparation of a stabilizer mixture containing a low amount of chloride comprising a) 50-80% by weight of tetrakis(2,4-di-tert-butylphenyl)biphenylene diphosphonite and its isomers, b) 5-25% by weight of bis(2,4-di-tert-butylphenyl)biphenylene monophosphonite and its isomers, and c) 5-25% by weight of a tris(2,4-di-tert-butylphenyl) phosphite, and where the sum of components (a), (b) and (c) is not greater than 100% by weight, by reacting biphenyl under Friedel-Crafts condition with phosphorus trichloride and aluminium trichloride and by reacting the product mixture with 2,4-di-tert-butyl-phenol in the presence of a tertiary amine or an aromatic amine and a solvent, separating the formed two layers, which process comprises treating the solvent layer with water, a base and a desiccant, separating the precipitate from the solution containing the stabilizer mixture and evaporating the solvent.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: October 29, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Vien Van Toan, Ronald Salathé
  • Patent number: 6464735
    Abstract: The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is gl
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: October 15, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr
  • Patent number: 6465554
    Abstract: The invention relates to compositions of hexacoordinated ruthenium and osmium carbenes with a carbonyl group as ligand and a vinyl group as substituent on the carbene group as catalysts for the photoinduced ring-opening metathesis of strained cycloolefins. It also relates to novel hexacoordinated ruthenium and osmium carbenes having a carbonyl group as ligand and a vinyl group as substituent on the carbene group, to compositions of the catalyst with cycloolefins, and to the polymerization process.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: October 15, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paul Adriaan Van Der Schaaf, Roman Kolly, Andreas Mühlebach, Andreas Hafner
  • Patent number: 6464832
    Abstract: A simplified method for the optical brightening of paper either in the pulp mass, the size or metering press or by coating by the use of a formulation of an optical brightening agent together with a swellable layered silicate.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: October 15, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Thomas Engelhardt, Peter Rohringer
  • Patent number: 6458169
    Abstract: The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is gl
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: October 1, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, Georges Metzger, Dieter Reinehr
  • Patent number: 6451072
    Abstract: Reactive dyes of formula (1) wherein A is phenyl or naphthyl, each of which is unsubstituted or substituted by halogen, C1-C4alkyl, C1-C4alkoxy, carboxy, sulfo or a fiber-reactive group of formula (2a), (2b), (2c), (2d) or (2e) —SO2—Y  (2a), —NH—CO—(CH2)l—SO2—Y  (2b), —CONH—(CH2)m—SO2—Y  (2c), —NH—CO—CH(Hal)—CH2Hal  (2d) or —NH—CO—C(Hal)═CH2  (2e), B is an aliphatic linking group, D is the radical of a diazo component of the benzene or naphthalene series, R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, R2 is hydrogen, cyano, carbamoyl or sulfomethyl, R3 is hydrogen or C1-C4alkyl, R is hydrogen or unsubstituted or substituted C1-C4alkyl or corresponds to a radical of formula (3)  wherein B, D, R2 and R3 have the meanings cited above, X1 is halogen, hydroxy, C1-C4alkoxy, unsubstituted o
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: September 17, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Rolf Deitz
  • Patent number: 6448208
    Abstract: A description is given of products obtainable by reacting components a), b), c) and, if desired, d), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II, component c) is a component of the formula IIIa and/or of the formula IIIb or a mixture of compounds of the formula IIIa and/or IIIb, and component d) is a compound of the formula IV or a mixture of compounds of the formula IV, in which the general symbols are as defined therein, where the compound of the formula I is, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,2-propanediol, diethylene glycol, triethylene glycol, 1,1,1-tris(hydroxymethyl)ethane, 2,2-dimethyl-1,3-propanediol or glycerol, the compound of the formula II is, for example, methyl 3-(3′,5′-di-tert-butyl-4′-hydroxyphenyl)propionate or methyl 3-(3′-tert-butyl-4′-hydroxy-5′-methylphenyl)-pro
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: September 10, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paul Dubs, Roger Martin, Samuel Evans, Stephan Allenbach, Marc Ribeaud
  • Patent number: 6443569
    Abstract: A method for printing fibrous textile materials according to the ink-jet printing technique, which method includes printing the fibrous materials with an aqueous ink including a) a pigment dye b) a water-dispersible or water-soluble mixture of pigment dye binders wherein one component of the mixture is based on the polymerization product of acrylic acid and another component of the mixture is based on the polymerization product of acrylic acid and urethane, and c) glycerol, propylene glycol or diethylene glycol.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: September 3, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Mickael Mheidle, Bénédicte Galéa
  • Patent number: 6436306
    Abstract: Perfluoroalkyl-substituted amino acid oligomers or polymers obtainable from (A) an aliphatic diamino acid having 3 to 10 carbon atoms such as lysine, (B) a chain extender such as epichlorohydrin, a dihalide or an aliphatic diepoxide, (C) an amino-reactive allyl compound and (D) a perfluoroalkyl iodide, and, optionally, other reactants, are useful as grease-proofing agents for paper and are excellent foam stabilizers for Aqueous Fire-Fighting Foam (AFFF) formulations used on polar solvent fires.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: August 20, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: John Jennings