Abstract: A phenylenediamine compound can be converted, with high selectivity, into its corresponding quinonediimine by reacting the phenylenediamine with a hypochlorite oxidation reactant.

Abstract: A hydroxyphenylamine compound can be converted, with high yield and high selectivity, into its corresponding quinoneimine by reacting the hydroxyphenylamine with a hypochlorite oxidation reactant.

Abstract: A hydroxyphenylamine compound can be converted, with high selectivity, into its corresponding quinoneimine by reacting the hydroxyphenylamine with hydrogen peroxide in the presence of a catalyst.

Abstract: The present invention relates to a process for preparing a hydroprocessing catalyst comprising the steps of subjecting a spent hydroprocessing catalyst comprising carbonaceous and sulphurous deposits to a thermal treatment to remove at least part of said deposits, grinding the thus obtained spent catalyst, mixing the ground hydroprocessing catalyst with at least one additive, and shaping the mixture of additive and ground hydroprocessing catalyst to form particles of a new hydroprocessing catalyst, with the spent hydroprocessing catalyst being subjected to a high-temperature calcination step carried out at a temperature in the range of 550-1000.degree. C. for a period sufficient to increase the MPD of the spent catalyst by at least 0.5 nm.The process according to the invention is particularly suitable for preparing ebullated bed catalysts from spent hydroprocessing catalysts.

Abstract: A phenylenediamine compound can be converted, with high selectivity, into its corresponding quinonediimine by reacting the phenylenediamine with oxygen and a metal catalyst or a salt thereof.

Abstract: The invention pertains to an optical recording medium comprising a homeotropically oriented liquid crystalline polymer film having a T.sub.g between 75-100.degree. C. and a T.sub.c between 110-140.degree. C. and comprising at least one dichroic dye. This homeotropic orientation along with the presence of dichroic dye makes it possible to employ a different technique for writing out and reading data. For, in this case contrast is obtained by the dichroic dye contained in the film being aligned in the same direction as the mesogenic groups of the liquid crystalline polymer. In a virgin film the mesogenic groups, and hence the dichroic dye molecules, are oriented perpendicular to the film's surface, and there is only low absorption of the incident light by these molecules. By local heating or irradiation of the film (e.g., with a laser) the homeotropic orientation is converted to an isotropic one.

Abstract: This invention provides a method for preparing 4-ADPA by charging nitrobenzene into a reaction zone under hydrogen pressure in the presence of a strong organic base and a catalyst for hydrogenation. The method provides the convenience and economy of a one-step process, while producing improved yields and selectivities. The invention further provides for various embodiments of the foregoing which are suitable for the production of 4-ADPA, and the hydrogenation or reductive alkylation to produce PPD. Important to the invention are the molar ratios of aniline to nitrobenzene and nitrobenzene to the strong organic base and the choice and use of hydrogenation catalyst.

Abstract: A phenylenediamine compound can be converted, with high selectivity, into its corresponding quinonediimine by reacting the phenylenediamine with oxygen in the presence of a modified activated carbon catalyst in an aqueous system.

Abstract: A process for manufacturing continuous polyester filament yarn for technical applications from a polymer over 90% of the chains of which are composed of-ethylene terephthalate units, via a one-step spinning process, with the undrawn filaments having a crystallinity smaller than 16% and the yarn being wound at a rate larger than 6000 m/min. The yarn obtained in this fashion is particularly suitable for use as reinforcing material in rubber articles, notably as reinforcing material in pneumatic tires for cars. The polyester filament yarn can be used to make cords of uncommonly high dimensional stability and a unique combination of breaking tenacity, shrinkage, and breaking toughness.

Abstract: A p-aramid microfilament yarn and a process for manufacturing the same. In the p-aramid yarn, which has a yarn linear density of at least 300 dtex, comprising a bundle of filaments with a linear density of less than 0.8 dtex, the g value is higher than 2.5 GPa, the elongation (EAB) is higher than 3.4%, and the L002 value is higher than 350 .ANG.. More particularly, the filament linear density is 0.3 to 0.8. The yarn according to the invention has surprisingly favorable properties, such as a high internal shear modulus. The invention also pertains to a process for manufacturing such a microfilament yarn in which p-aramid is subjected to an air gap-wet spinning process of the known type, in which the draw ratio in the air gap combined with the diameter of the capillaries through which the polymer is extruded ensures that microfilament yarn having the desired properties is obtained.

Abstract: The invention relates to non-linear optically active (NLO) polycarbonates and to NLO active waveguides containing these polycarbonates. Waveguides containing these NLO polycarbonates have a low loss of signal, a high glass transition temperature and good polability and a high stability of the Pockel's coefficient.

Abstract: Mesoporous, alumina compositions having an average pore diameter substantially ranging from about 15 .ANG. to about 40 .ANG. and an average surface area of no less than about 500 meter square/gram are disclosed. These materials can be formed by treating an aluminum source that is derived from an aluminum alkoxide in an organic-aqueous solution with an organic structured directing agent to form meso-sized micelles followed by calcination of the resulting composition. Appropriate organic structural directing agents are alkyl carboxylic acids.

Abstract: The present invention is in the field of optical components, more particularly, polymeric optical components, even more particularly, thermo-optical components, electro-optical components or passive components. The present invention pertains to an optical component having an at least penta-layered polymer structure on a substrate comprising:A) a low refractive index lower cladding layer,B) a core-matching refractive index lower cladding layer,C) a core layer,D) a core-matching refractive index upper cladding layer, andE) a low refractive index upper cladding layer.With this specific layer structure an optimum traversal confinement can be obtained, which results in less loss of light and an improved switching efficiency.

Abstract: The invention is directed to a cellulose filament yarn having a breaking tenacity of higher than 600 mN/tex and containing more than 400 filaments and a cord made therefrom.

Abstract: The present invention relates to a process which comprises the non-hydrolytic transformation of an aluminoxane precursor composition, comprising carbon-to-oxygen bonds which can be alkylated by an alkylaluminum moiety, into a catalytically useful aluminoxane composition. In one embodiment of this invention, the catalytically useful aluminoxane composition is a polymethylaluminoxane composition substantially free of trimethylaluminum. The intermediate precursor is formed by the reaction of a trialkylaluminum compound, or a mixture of trialkylaluminum compounds, and a compound containing a carbon-to-oxygen bond, such as an alcohol, ketone, carboxylic acid, or carbon dioxide. Either unsupported or supported polymethyl-aluminoxane compositions can be formed.

Abstract: The present invention relates to a corrosion resistant metal article which comprises: (a) a metal body normally prone to corrosion when subjected to potentially corrosive conditions; and (b) a coating of neutral, undoped polyaniline in the emeraldine base form on a portion of the metal body (e.g., a side coating or undercoating) of the neutral, undoped polyaniline in the emeraldine base form on the metal body, where the distance (for example, not more than about one centimeter) between coated and uncoated portions of the metal is effective to protect the uncoated portion of the metal as well as the coated portion.

Abstract: The invention relates to a resin composition comprising epoxy resin, a cross linking agent for the epoxy resin in the form of a carboxylic anhydride, and at least one allyl network forming compound. According to the invention, the anhydride-functional compound is a copolymer of an ethylenically unsaturated anhydride and a vinyl compound. Notably suitable are styrene-maleic anhydride copolymers known as SMA Type 1. Surprisingly, it was found that the presence of at least 2 wt.% of triallyl cyanurate (TAC) results in an increase in Tg, such that even with simple difunctional epoxy compounds resins can be obtained which have a glass transition temperature of 130.degree. C. and higher. It was further found that the processing as prepreg of epoxy resins cross-linked using anhydride-vinyl copolymers will be greatly enhanced by the presence of at least 10 % of allyl.

Abstract: The invention pertains to an adduct obtainable by condensation of a bisepoxy compound and a P-guanamine according to the formula ##STR1## wherein X is CR.sub.3 R.sub.4 --(CR.sub.1 R.sub.2).sub.n --CR.sub.5 R.sub.6 or o-phenylidene, n is 0 or 1, and R.sub.1 -R.sub.8 may be the same or different and represent H, methyl or ethyl, and the molar ratio P-guanamine: bisepoxide is 0.60 to 0.35. The adduct is used in the manufacture of synthetic materials, notably printed wiring boards (PWBs).

Abstract: An optically anisotropic solution containing cellulose and inorganic acids of phosphorus contains 94-100 wt % of the following constituents: cellulose; phosphoric acid and/or its anhydrides; and water; and 0-6 wt % of other constituents. This solution can be prepared in an apparatus in which intensive mixing is made possible by the shearing forces generated by mixers and kneaders in the apparatus. The solution can be used in making pulp, hollow fibres, staple fibre, membranes, nonwovens, or films.

Abstract: Celluloe extrudates can be made from an optically anisotropic solution containing 94-100 wt % of: cellulose; phosphoric acid and/or its anhydrides; and water by extruding the solution, coagulating the formed extrudates, and then aftertreating those extrudates so that they have a degree of acidity which at least equals 7. Fibres obtained by such a process possess particularly good thermal stability and are suitable for use as a reinforcing material.