Abstract: A process for producing a magnesium containing support for titanium comprising contacting magnesium metal, a halogenated hydrocarbon and a compound represented by the formula X'.sub.m C(OR').sub.4-m wherein X' is a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.10 alkyl, aryl, cycloalkyl or halogenated alkyl, aryl, cycloalkyl group, R' is a C.sub.1 -C.sub.20 alkyl, aryl or cycloalkyl group and m is 0, 1 or 2 to form a magnesium-containing solid represented by the formula R'OMgX and thereafter contacting the magnesium-containing solid with a Lewis base or a compound which can form an ester such as benzoyl chloride and a titanium compound such as titanium tetrachloride. The obtained magnesium supported titanium composition is useful as a catalyst component in combination with a co-catalyst organoaluminum compound for the polymerization of olefins.

Abstract: Thin films of about 1 to 5 mil thick of poly(parabanic acid) (PPA-M form) containing halogenated flame retardants have the flame retardancy enhanced by the addition of small amounts (generally about 0.1 to 3.0 weight percent) of a copper chelate compound.

Abstract: An improvement in a reciprocating engine used in an energy recovery system wherein the inlet valves to the cylinders of the engine are operated by independently time adjustable actuating means.The system for recovering energy from a pressured reactor comprising a reactor, a reciprocating engine connected to the reactor to receive reaction effluent from said reactor thereby driving the pistons of the reciprocating engine by expansion of the effluent and recovery apparatus downstream of the engine for recovering products from the effluent.The expanding reactor effluent is used to drive the pistons which are especially valved in conjunction with the effluent inlet port in the cylinder to facilitate handling the effluents to adjust the flow into an expansion chamber to obtain maximum recovery, the pistons in turn operate a crankshaft through a crosshead which may power compressors or operate a generator to produce electricity.

Abstract: Normally intractable polymers of the structure: ##STR1## wherein X is O or NH, provided at least one X is O, such as poly(parabanic acids) are made extrudable by composition with from 10 to 60 weight percent of diaryl ketone.

Abstract: A supported titanium catalyst is produced by cogrinding, in combination, a magnesium halide, tetravalent titanium halide, organic acid ester, and an organic halogen compound. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.

Abstract: A polyolefin composition comprising a modified polyolefin obtained by adding an unsaturated carboxylic acid or an anhydride thereof to a polyolefin or mixtures of said modified polyolefin and an unmodified polyolefin, an inorganic filler, one or more nucleating agents or a combination thereof with one or more heat deterioration inhibitors, said polyolefin composition evidencing reduced deterioration by heat or reduction of its mechanical strength during a molding operation.

Abstract: A supported titanium catalyst, adaptable for use in the polymerization of alpha-olefins, is produced by treating a supported titanium-containing solid obtained by co-pulverization of a magnesium halide, a tetravalent titanium halide which may also comprise an electron donor compound and/or a halogen compound with an organohalogen compound. The component is thereafter treated with an organoaluminum compound and an electron donor compound. The resulting supported titanium catalyst, one employed as a titanium component with an organoaluminum catalyst component results in a catalyst system useful for the polymerization of alpha-olefins and particularly alpha-olefins.

Abstract: Crystalline co-polybenzyls are prepared by the polymerization of 2,5-dimethylbenzyl chloride with a benzyl halide of the same series.

Abstract: Polyolefin granules having an average particle size diameter greater than 600 microns, preferably about 1000 microns or greater are obtained by polymerizing monoolefins in the presence of a titanium catalyst having an average particle size diameter of greater than about 35 microns and preferably 40 to 65 microns. The titanium catalysts are obtained by reducing titanium tetrahalide in the presence of a suitable organometallic reducing compound such as diethylaluminum chloride under controlled conditions of temperature, reduction rate and concentrations to obtain a titanium halide reduced solids product seeds having an average particle size diameter of about 20 microns or greater and thereafter simultaneously and without interruption adding to the seeds containing system titanium tetrahalide and organometallic reducing compound such as diethyl aluminum halide at a rate such that the reduction of titanium tetrahalide to titanium trihalide is about 6.times.10.sup.-4 to about 0.

Abstract: Normally intractable polymers of the structure: ##STR1## wherein Y is 0 or NH, provided at least one X is 0, such as poly(parabanic acids) are made extrudable by composition with from 10 to 60 weight percent of an ester of aromatic (carboxylic acid).

Abstract: Normally intractable polymers of the structure: ##STR1## wherein X is O or NH, provided at least one X is O, R is an organic moiety, such as poly(parabanic acids) are plasticized by composition with from 15 to 60 weight percent of an aromatic sulfone or aromatic sulfoxide such as diphenyl sulfone, diphenyl sulfoxide or dibutyl-4,4'-sulfonyl dibenzoate.

Abstract: Normally intractable polymers of the structure: ##STR1## wherein X is O or NH, provided at least one X is O, such as poly(parabanic acids) are made extrudable by composition with from 10 to 60 weight percent of an aromatic nitrile.

Abstract: A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated hydrocarbon having two carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.

Abstract: A supported titanium catalyst, adaptable for use in the stereoregular polymerization of .alpha.-olefins, is produced by treating a supported titanium-containing solid, obtained by cogrinding a magnesium halide, tetravalent titanium halide and organic acid ester, with a hydrocarbon, organo halogen compound or mixture thereof with heating. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.

Abstract: Specific thermoplastic compositions which are formulated to be exceptionally useful for adhesion to copper-containing metals are prepared from either glycidyl acrylate grafts of polypropylene based formulations with a minor elastomeric component or low density polyethylene based formulations grafted with acrylic acid and/or glycidyl acrylate and containing a minor elastomeric component.

Abstract: A titanium trichloride catalyst component containing a minor amount of prepolymerized alpha-olefin and useful in the polymerization of alpha-olefins is produced by reducing titanium tetrachloride with an organoaluminum compound at low temperatures and then treating the resulting reduced solids product with about 1 to 1,000 wt. % alpha-olefin so as to obtain a prepolymerized titanium trichloride reduced solid. The prepolymerized reduced solid can thereafter be activated to a highly active prepolymerized titanium trichloride by treating the prepolymerized reduced solid with a halogenated hydrocarbon and a Lewis base complexing agent or titanium tetrachloride and a Lewis base complexing agent. The prepolymerized reduced solid and the prepolymerized activated titanium trichloride manifests substantially no evidence of friability upon being subjected to mechanical shearing forces.

Abstract: In an improved die-nose assembly for a melt-blowing process wherein molten resin is extruded from a series of die-holes while heated gas is blown out through slots on either side of the die nose associated therewith, spacers which are movable widthwise of the die assembly are provided in the gas slots to provide effective uniformity in the gas streams across the width of the die.

Abstract: Organic amides, solutions of polymers thereof, which polymers are subject to hydrolysis and degradation in the presence of amines, and polymers isolated therefrom are stabilized by the presence of aromatic sulfonic acid esters of aliphatic, arylaliphatic and alicyclic alcohols and polyols.

Abstract: A system for recovering energy from a pressured reactor comprising a reactor, a reciprocating engine connected to the reactor to receive reaction effluent from said reactor thereby driving the pistons of the reciprocating engine by expansion of the effluent and recovery apparatus downstream of the engine for recovering products from the effluent.The expanding reactor effluent is used to drive the pistons which are especially valved in conjunction with the effluent inlet port in the cylinder to facilitate handling the effluents, the pistons in turn operate a crankshaft through a crosshead which may power compressors or operate a generator to produce electricity. It is reasonable to expect recovery in a directly usable form, such as electricity, of over 25% of the energy theoretically available in the pressured reactor effluent in some cases.

Abstract: An improved coat hanger die is provided wherein the manifold is curved and wherein the manifold radius, coat hanger slit part thickness and the form of the coat hanger die are determined by a formula which is disclosed all in relation to the radius of the manifold at its inlet. The radius of the manifold at its inlet is selected in consideration of the flow characteristics of the resin melt to provide a low melt velocity at the inlet.