Abstract: A fluid catalytic cracking (FCC) process and apparatus which employs relatively more elutriatable catalyst particles comprising intermediate pore zeolite, particularly ZSM-5, and relatively less elutriatable catalyst particles comprising large pore zeolite, preferably zeolite Y. The process and apparatus employ a first stripping vessel which also separates a more elutriatable first portion of catalyst from a less elutriatable second portion of catalyst. The more elutriatable first portion passes to a second stripping vessel, and subsequently recycles to a fluid catalytic cracking reactor riser. The second portion of less elutriatable catalyst passes from the first stripping vessel to a fluid catalytic cracking regenerator vessel and, after being regenerated, recycles to the reactor riser. The more elutriatable first portion contains a higher ratio of intermediate pore catalyst particles to large pore catalyst particles than does the second portion.
Type:
Grant
Filed:
November 15, 1988
Date of Patent:
February 5, 1991
Assignee:
Mobil Oil Corporation
Inventors:
Joseph A. Herbst, Hartley Owen, Paul H. Schipper
Abstract: Butadiene is polymerized alone or with a monomer such as styrene in a dispersion in propane, butane or its mixtures with minor amounts of other C.sub.4 -C.sub.6 alkanes, e.g., n-pentane and a dispersant which is preferably a styrene/hydrogenated isoprene block copolymer to achieve stable dispersions at higher solids and butadiene levels possible with similar alkane dispersants.
Abstract: An olefin, particularly alpha-olefin, supported catalyst composition, containing a transition metal or a compound thereof and an activator, has an average pore diameter of about 20 to about 300 Angstroms, at a substantially constant catalyst particle size for a given range of average pore diameters. The catalyst produces polymers having gradually decreasing molecular weight distribution with decreasing pore size of the catalyst at a constant particle size.
Abstract: Small effective amounts of camphorquinone incorporated into polyethylene accelerates the degradation of polyethylene on exposure to ultraviolet light.
Abstract: Non-acid microporous crystalline indium containing materials are combined with Group VIII metal such as platinum to produce catalysts which exhibit high selectivity for dehydrocyclization of C.sub.5.sup.+ paraffins and which exhibit little, if any, cracking activity for hexane and heptane.
Abstract: Improved polymer gels for oil reservoir permeability control have a continuous, cross-linked polymer phase having a relatively low density of cross-linking with domains of clustered, high density cross-linking. The clustered high density cross-linkings contribute to the gel's shear stability and gel strength while the continuous, low density phase contributes to good injectivity. Gels of this kind are produced by cross-linking a base polymer with a relatively low density of cross-linking sites with a reinforcing polymer having a higher cross-linking site density. Suitable polymers have ligand groups which are capable of forming coordination cross-linkages with polyvalent metals, especially chromium and include polyacrylamides as base polymers and polyacrylic acids as reinforcing polymers.
Abstract: A dispensing system for a package of a continuous, severable sheet material comprising a number of individual severable members, such as plastic bags, separated by transverse pre-weakened regions, such as perforations, is composed of a storage container holding the package and a dispensing device. The dispensing device is separate from and is located at a location remote from the storage container. The continuous severable sheet material is conducted to the dispensing device and is threaded therethrough until the pre-weakened separating two consecutive members emerges through the exit of the device. A sufficient force is then applied to the continuous, severable sheet material to separate the two consecutive members from each other at the pre-weakened region.
Abstract: A process for increasing the volume of feed throughput to the catalytic cracker by decreasing hydrogen and total gas volume production, under catalytic cracking conditions temperature of 950.degree. F. to about 1150.degree. F., a catalyst to feed ratio of 3:1 to 10:1 and a catalyst contact time of from about 1 to about 20 in the presence of catalyst comprising ZSM-20 and a matrix.
Abstract: Zeolite catalysts containing gallium, the gallium is primarily present in the framework of the catalyst and the catalyst contains little or no non-framework gallium; and methods for producing such catalysts by varying the reaction molar ratios of SiO.sub.2 /Ga.sub.2 O.sub.3 ; and the use of such catalysts to produce high octane aromatics.
Abstract: A catalytic cracking process is described featuring multiple risers in which a variety of hydrocarbon conversion reactions take place, a stripping unit in which entrained hydrocarbon material is removed from catalyst and a regeneration zone in which spent cracking catalyst is regenerated, which comprises:(a) catalytically cracking a relatively high boiling hydrocarbon charge material in a first riser in the presence of both a first catalyst component which is an amorphous cracking catalyst and/or a large pore crystalline cracking catalyst and a second catalyst component which is selected from zeolite Beta and/or medium pore crystalline silicate zeolite catalyst to provide a variety of products including naphtha and C.sub.3 and/or C.sub.4 olefin;(b) thermally cracking a C.sub.
Type:
Grant
Filed:
March 30, 1989
Date of Patent:
October 30, 1990
Assignee:
Mobil Oil Corporation
Inventors:
Joseph A. Herbst, Hartley Owen, Paul H. Schipper
Abstract: Long chain (C.sub.7+) paraffins are isomerized over a large pore, highly siliceous zeolite catalyst such as zeolite Y or ZSM-20 having a structural silica:alumina ratio of at least 10:1. The use of the highly siliceous zeolite inhibits the degree of cracking and also permits weaker hydrogenation components such as palladium to be used in the catalyst.
Type:
Grant
Filed:
December 5, 1988
Date of Patent:
October 9, 1990
Assignee:
Mobil Oil Corporation
Inventors:
Rene B. LaPierre, Randall D. Partridge, Stephen S. Wong
Abstract: The invention is a fluid catalytic cracking process in which reduced catalyst to petroleum feed contact times at high catalytic cracking temperatures are afforded. The catalytic cracking conditions provide olefinic gasoline product with reduced coke make.
Abstract: The use of a catalyst containing Mn, a large pore crystalline molecular sieve, and optionally rare earths in catalytic cracking is disclosed. This catalyst gives high gasoline selectivity with low coke yields and is suitable for either gas oil or resid cracking applications.
Type:
Grant
Filed:
December 22, 1988
Date of Patent:
September 11, 1990
Assignee:
Mobil Oil Corporation
Inventors:
Philip J. Angevine, Robert G. Bundens, Joseph A. Herbst, Albin Huss, Jr., Sadi Mizrahi
Abstract: A zeolite, its method of preparation and use is disclosed. The zeolite is characterized by a silica to alumina mole ratio greater than 12 and a Constraint Index of 1 to 12. The zeolite undergoes controlled alumina extraction by treatment with, e.g., strong mineral acid or chelating agent. Removal of aluminum increases the acid activity of the zeolite.
Abstract: The invention is directed to aromatization of hydrocarbons of low octane value to produce aromatics over a catalyst composition comprising a zeolite type material which has been treated with the chloride of an oxophilic element such as Si on Ti.
Abstract: Zeolitic catalysts containing framework displaced aluminum, e.g., steamed or spent catalysts, are activated by contact with aqueous fluoride solution under mild conditions. The treatment can enhance catalytic activity, ion-exchange capacity and crystallinity by replacing aluminum in the zeolitic framework.
Type:
Grant
Filed:
October 14, 1988
Date of Patent:
July 24, 1990
Assignee:
Mobil Oil Corporation
Inventors:
Clarence D. Chang, Scott Han, Bruce P. Pelrine
Abstract: An improved, low-pressure dehydrocyclization and/or reforming process based on a non-acidic metal containing crystalline microporous tin catalyst, in which the feed is rich in low octane hydrocarbons, such as paraffins, and in which the product has increased aromatic content and increased octane value over that of the feed.
Type:
Grant
Filed:
January 11, 1989
Date of Patent:
June 19, 1990
Assignee:
Mobil Oil Corporation
Inventors:
Ralph M. Dessau, Randall D. Partridge, Ernest W. Valyocsik, James C. Vartuli
Abstract: Cellulosic materials are converted to hydrocarbons by hydrolyzing cellulosic materials to produce a mixture of fermentable sugars and unfermentable furfural, fermenting the mixture to obtain a fermented mixture containing fermented product and unfermented furfural and contacting the fermented mixture with a highly siliceous crystalline zeolite catalyst under conditions of temperature and pressure to convert the fermented mixture to a hydrocarbon-containing product. Preferably, an oxygenated organic compound such as methanol, ethanol or dimethylether is mixed with the fermented mixture prior to contact with the catalyst.
Abstract: A process for increasing the volume of feed throughput to the FCC by decreasing coke make under catalytic cracking conditions including a temperature of 950.degree. F. to about 1150.degree. F., a catalyst to feed ratio of 3:1 to 10:1 and a catalyst contact time of from about 1 to about 20 seconds in the presence of catalyst comprising framework silicon enriched ZSM-20.
Abstract: Crystalline microporous thallium or lead containing silicate isostructural with zeolites, as catalysts, exhibit high selectivity for dehydrogenation, dehydrocyclization, and reforming.