Abstract: Group VIII metal modified non-acidic tin containing microporous crystalline materials which in catalysis exhibit high selectivity for dehydrogenation and dehydrocyclization are described.
Type:
Grant
Filed:
October 6, 1989
Date of Patent:
March 9, 1993
Assignee:
Mobil Oil Corporation
Inventors:
Ralph M. Dessau, Ernest W. Valyocsik, James C. Vartuli
Abstract: The invention relates to zinc and phosphorus free additives for lubricating compositions which are produced by a free radical reaction between a dimercaptothiadiazole and monomer oligomer or homologue of acrylates or methacrylate, which in minor amounts impart antiwear/extreme pressure and antioxidation properties to the lubricant.
Abstract: A Pt/Ba/USY catalyst prepared with a high SiO.sub.2 /Al.sub.2 O.sub.3 ratio USY gives improved aromatics selectivity compared to other Pt/USY containing catalysts. The improved selectivity is a result of the method of catalyst preparation which includes incorporation of a Group IIA metal after platinum incorporation.
Type:
Grant
Filed:
December 26, 1989
Date of Patent:
February 9, 1993
Assignee:
Mobil Oil Corp
Inventors:
Kenneth J. Del Rossi, Garry W. Kirker, Albin Huss, Jr.
Abstract: A thermoplastic film comprising a base layer of a thermoplastic resin which comprises polypropylene and a coating layer of an alkali metal salt of an alkyl sulfate is disclosed. The film is characterized by reduced COF and improved anti-blocking characteristics without the attendant problems associated with decreased clarity, adhesion and wettability common to films treated to improve their COF and anti-blocking characteristics. The disclosure also provides a process for making the film in which the polypropylene-coating thermoplastic resin is extruded into a sheet, said sheet oriented in the longitudinal direction to form a monoxially oriented film, said film coated with the alkali metal salt of an alkyl sulfate and said coated film oriented in the transverse direction.
Abstract: The invention relates to producing ortho isopropyl phenol catalytically by contacting phenol with isopropanol or propylene, at a temperature of from about 200.degree. C. to about 300.degree. C., with ZSM-12 and zeolite Beta; and recovering ortho isopropyl phenol.
Abstract: A catalyst comprising a molecular sieve having a lattice aluminum content in which the silica/alumina framework mole ratio is less than 55, and having a diffusion rate constant of less than about 150 sec.sup.-1 .times.10.sup.-6 is particularly useful for vapor-phase disproportionation of toluene.
Type:
Grant
Filed:
March 21, 1990
Date of Patent:
December 22, 1992
Assignee:
Mobil Oil Corporation
Inventors:
Robert P. Absil, Scott Han, David S. Shihabi, David O. Marler, Clarence D. Chang, Donna M. Mitko
Abstract: A polymer blend including from about 80 to about 98 weight percent LLDPE and from about 2 to about 20 weight percent PP having an isotacticity of from about 70 to 90 percent, the blend having a viscosity ratio of LLDPE to PP greater than 3, improves the processability of LLPDE into films without loss in film properties.
Abstract: The aging properties of Group VIII metal modified non-acidic microporous crystalline materials which in catalysis exhibit high selectivity for dehydrogenation and dehydrocyclization are improved by the incorporation therein of titanium and/or titania.
Abstract: A process for producing zeolites in a matrix material is described which comprises precipitating an oxide of silicon in the matrix to increase the silica of the matrix which is available for crystallization to a zeolite.
Abstract: Zeolites (e.g. ZSM-5 and zeolite beta) enriched with hydroxyl groups are prepared by ammonia treatment of sieves which have suffered loss of tetrahedral aluminum from framework positions followed by careful calcination (200.degree.-450.degree. C.). The hydroxyl group created by this method are stable only to 500.degree. C.
Abstract: The invention relates to catalysts for ethylene polymerization or copolymerization to produce film quality product which exhibits improved FDA hexane extractables. The invention also relates to catalysts for ethylene polymerization or copolymerization to produce film quality product which exhibits improved dart impact resistance. The invention relates to catalysts for ethylene polymerization or copolymerization to produce film quality product which exhibits improved MD tear properties.
Type:
Grant
Filed:
August 6, 1991
Date of Patent:
August 18, 1992
Assignee:
Mobil Oil Corporation
Inventors:
Pam J. Cook, Robert O. Hagerty, Per K. Husby, Thomas E. Nowlin
Abstract: Polyethylene modified to contain chromophores which absorb at greater than 200 nm. are used to accelerate the degradaton of polyethylene on exposure to ultraviolet radiation.
Abstract: In accordance with the invention, the process comprises substantially eliminating distributor plate fouling in fluid bed reactor alpha olefin polymerizations, by removing oligomers from the recycle feeds to the fluid bed reactor. In accordance with the invention, the process comprises substantially eliminating gel production in the low pressure production of polymers and copolymers of ethylene. Unexpectedly, the process of the invention, which substantially eliminates distributor plate fouling also results in polymer products which are substantially free of gels.
Type:
Grant
Filed:
November 19, 1991
Date of Patent:
June 30, 1992
Assignee:
Mobil Oil Corporation
Inventors:
Quentin S. Cooke, Glyarpuram N. Prasad, John J. Schlueter, Jr., Grace O. Tsien
Abstract: A process for producing monosubstituted monoalkylaromatics from C.sub.8 +n-paraffins-containing feeds, by contacting the feeds with a non-acid catalyst comprising a microporous crystalline material containing tin, indium, thallium or lead, is disclosed.
Type:
Grant
Filed:
October 11, 1989
Date of Patent:
June 23, 1992
Assignee:
Mobil Oil Corporation
Inventors:
Ralph M. Dessau, Ernest W. Valyocsik, Randall D. Partridge
Abstract: A metal selected from the group consisting of ruthenium, iridium or rhenium on non-acidic microporous crystalline materials also containing a dehydrogenation/hydrogenation metal enhances the aging characteristics and stability of the base catalyst.
Abstract: Supported olefin, e.g., alpha-olefin, polymerization catalyst compositions, such as Ziegler-Natta catalysts, are modified by using porous, polymer particles having an average pore diameter of at least about 10 .ANG. as the catalyst support. The resulting catalyst composition is more active than refractory oxide-supported catalysts and it is not susceptible to deactivation by catalyst poisons, such as oxygen or water. Additionally, the polymer particles need not be calcined prior to the catalyst synthesis.
Abstract: The invention relates to the synthesis of a precursor containing silicon and aluminun and an organic directing agent for zeolite syntheses and its use in zeolite production.
Abstract: The invention is a catalytic process for isomerizing an olefin under catalytic isomerization conditions, in the presence of an olefin isomerization catalyst comprising MCM-22. The light olefins are linear and/or branched olefins containing greater than three carbon atoms. The olefins can be contained in a fraction having a boiling range of from C.sub.5 + to 390.degree. F.
Abstract: The invention relates to a catalytic dehydrogenation of alcohols to produce ketones and/or aldehydes. The catalyst comprises a dehydrogenation metal and a non-acidic microporous crystalline material as a support. The support may contain indium, tin, thallium or lead, when the dehydrogenation metal is a Group VIII metal.
Abstract: Hydroxyl rich zeolites containing 0.1 to 20 weight percent of a hydrogenation/dehydrogenation metal are described which have increased hydrogen adsorption capacity.
Type:
Grant
Filed:
January 9, 1991
Date of Patent:
April 7, 1992
Assignee:
Mobil Oil Corporation
Inventors:
William S. Borghard, Stuart D. Hellring