Patents Represented by Attorney, Agent or Law Firm Mark E. Waddell
  • Patent number: 5904148
    Abstract: Delayed release flavorant compositions containing flavor-release additives, namely 1,2-diols of the formula ##STR1## wherein R.sup.1 is one of the radicals ##STR2## where R.sup.2 is H, lower alkylR.sup.3, R.sup.4 are H, lower alkyl, lower alkoxy, hydroxy, or R.sup.3 +R.sup.4 together are methylenedioxy,R.sup.5 is lower alkyland the broken lines represent in the ring one additional bondand in the side chain an optional bond.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: May 18, 1999
    Assignee: Givaduan-Roure (International) SA
    Inventor: Denise Anderson
  • Patent number: 5874576
    Abstract: A light screening agent, which contains a compound of the general formula ##STR1## wherein R and R' are alkyl, hydroxyalkyl, alkenyl, alkynyl, or alkyl ether radicals substituted by one or more hydroxy and/or alkoxy groups andAr represents one of the residues ##STR2## in which R.sup.2 is hydroxy, alkyl, alkenyl, alkynyl, or an alkyl, alkenyl, alkynyl ether residue or polyalkyl ether residue optionally substituted by one or more hydroxy and/or alkoxy groups and R.sup.3 is hydrogen or signifies a residue R.sup.2 and in which the hydroxy group is present in the .alpha.-position to the bonding to the triazine nucleus, with the number of C and O atoms present in R and R' being a total of 8 to 42, especially 8 to 18, and the number of O atoms corresponding to at most half of the C atoms.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: February 23, 1999
    Assignee: Givaudan-Roure (International) SA
    Inventor: Ulrich Huber
  • Patent number: 5849551
    Abstract: A microbiological process for the production of .gamma.-decalactone. According to this process, a culture of the fungus of a particular species of the genus Mucor is incubated with the particular substrate, which is an organic carboxylic acid ester, to produce fermentatively the .gamma.-decalactone. Exact conditions have now been discovered under which .gamma.-decalactone can be prepared in high yields. These conditions are based upon the fermentative incubation of a fungus of the genus Mucor in conjunction with the appropriate substrate in order to obtain the high yield of the desired lactone.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: December 15, 1998
    Assignee: Givaudan-Roure (International) SA
    Inventors: Bruno Kumin, Thomas Munch
  • Patent number: 5840282
    Abstract: Photostable, cosmetic light-screening compositions for the protection of the human epidermis and the hairs against the ultraviolet rays of wavelengths between 320 and 400 nm, and between 320 and 400 nm respectively, comprising, in a cosmetically acceptable vehicle containing at least one fatty phase, about 0.75 to about 5%, in particular about 1 to about 4% by weight, of a dibenzoylmethane type UV-A screening agent and at least about 0.5% to about 2%, in particular about 0.5 to about 1% by weight, of a benzylidene type stabilizer of the general formula ##STR1## represents a bridged cyclic compound having the camphor (1,7,7-trimethyl-bicyclo?2.2.1!heptan-2-one), norcamphor (bicyclo?2.2.1!heptan-2-one), nopinone (6,6-dimethyl-bicyclo?3.1.1!heptan-2-one), pinocamphone (4,6,6-trimethyl-bicyclo?3.1.1!heptan-3-one), verbanone (4,6,6-trimethyl-bicyclo?3.1.1!heptan-2-one, thujone (1-isopropyl-4-methyl-bicyclo?3.1.0!hexan-3-one) or the 4,7-methano-octahydro-inden-5-one structure, and wherein R.sup.1, R.sup.2, R.sup.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: November 24, 1998
    Assignee: Givaudan-Roure (International) SA
    Inventors: Hans Ulrich Gonzenbach, Peter Gygax, Bernhard Hostettler, Ulrich Huber
  • Patent number: 5837671
    Abstract: Methyl (E)-4,7-octadienoate ?(E)-4,7-octadienoic acid methyl ester! (1), as well as odorant and/or flavorant compositions containing compound (1) as an organoleptic active substance and the manufacture of compound (1).
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: November 17, 1998
    Assignee: Givaudan-Roure (International) SA
    Inventor: Roman Kaiser
  • Patent number: 5707961
    Abstract: The invention is concerned with novel odorants, including the compounds of the formula ##STR1## wherein R.sup.1 .dbd.R.sup.4 .dbd.CH.sub.3 and R.sup.2 .dbd.R.sup.3 .dbd.H orR.sup.1 .dbd.R.sup.2 .dbd.R.sup.3 .dbd.H and R.sup.4 .dbd.CH.sub.3, orR.sup.1 +R.sup.2 .dbd.--CH.sub.2 CH.sub.2 -- and R.sup.3 .dbd.H and R.sup.4 .dbd.CH.sub.3, orR.sup.1 .dbd.R.sup.4 .dbd.CH.sub.3 and R.sup.2 +R.sup.3 .dbd.--CH.sub.2 -- orR.sup.1 .dbd.CH.sub.3 and R.sup.2 .dbd.R.sup.3 .dbd.H and R.sup.4 .dbd.CH.sub.2 CH.sub.3 orR.sup.1 .dbd.R.sup.2 .dbd.R.sup.4 .dbd.CH.sub.3 and R.sup.3 .dbd.H and R.sup.5 .dbd.H (preferred) or CH.sub.3.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: January 13, 1998
    Assignee: Givaudan-Roure (International) SA
    Inventors: Jerzy A. Bajgrowicz, Alain Bringhen, Georg Frater, Urs Muller
  • Patent number: 5703250
    Abstract: Compounds of the formula: ##STR1## in which R.sup.1, R.sup.2 represent H or methyl and R.sup.3, R.sup.4 represent H, C.sub.1-4 alkyl or C.sub.2-4 alkenyl; R.sup.3 and R.sup.4 together can also be butylidene are interesting camphor derivatives. They exhibit valuable odor characteristics.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 30, 1997
    Assignee: Givaudan-Roure (International) SA
    Inventor: Jerzy A. Bajgrowicz
  • Patent number: 5676880
    Abstract: A liquid crystal display cell comprising a chiral ferroelectric smectic liquid crystal layer whose helix structure is influenced by the action of an electric field such that its optical anisotropy alters; a pair of transparent plates between which the liquid crystal is disposed and which have a surface structure for aligning the molecule of the liquid crystal and are provided with electrodes to produce an electric field therein; and one polariser each before and after the liquid crystal: such ratio d/p of the thickness d of the liquid crystal layer to the pitch height p of the helical twisting is greater than 5, the smectic tilt angle .theta..sub.o is being between 22.5.degree. and 50.degree. and the product d.multidot..theta..sub.o.sup.2 .multidot..DELTA.n.multidot.l/.lambda. (phase factor) of the thickness d, the square of the tilt angle .theta..sub.o, the value of the birefringence .DELTA.n and the reciprocal of the wavelength .lambda. of light bedding is greater than 0.45 .mu.m.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 14, 1997
    Assignees: Rolic AG, Niopic Moscow Research & Production Association
    Inventors: Leonid A. Beresnev, Nina I. Chernova, Vladimir G. Chigrinov, Dmitry I. Dergachev, Alexander V. Ivashchenko, Marina V. Loseva, Boris I. Ostrovskiv, Arnold Z. Rabinovich, Evgeniv P. Pozhidaev, Martin Schadt, Victor V. Titov
  • Patent number: 5665696
    Abstract: Novel odorant compositions which are characterized by a content of one or more compounds selected from the group consisting of tetrahydrofurans of structures 1 or 2, or tetrahydropyrans of structure 3. ##STR1## wherein R can be an acyclic, where acyclic refers to a chain of at least four carbon atoms substituted with at least three methyl groups in the chain, carbocyclic, where carbocyclic refers to a ring of 5-8 carbon atoms, and with at least two methyl groups on the ring, or bicyclic where bicyclic refers to two carbon tings, each ring having between 5-8 carbon atoms fused together, substituted with at least two methyl groups, and where R.sub.1 =CH.sub.3, or higher alkyl group, R.sub.2 =H, CH.sub.3, or higher alkyl group, R.sub.3 =H, or CH.sub.3, R.sub.4 and R.sub.5 =H, CH.sub.3, or higher alkyl group.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: September 9, 1997
    Assignee: Givaudan-Roure (International) SA
    Inventor: Paul David Noire
  • Patent number: 5661104
    Abstract: The use of novel compositions for preserving aqueous systems normally subject to spoilage is disclosed. The compositions incorporate an antimicrobial agent into an inert and biodegradable carrier. The resulting compositions are stable, active, non-toxic, non-corrosive, biodegradable, compatible with ecosystems while having a flash point above 200.degree. F. and a pleasant odor.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: August 26, 1997
    Assignee: Givaudan-Roure (International) SA
    Inventor: Joseph A. Virgilio
  • Patent number: 5637255
    Abstract: Chiral dopants of the formula ##STR1## in which n represents the number 0 or 1; R.sup.3 denotes a group of the general formula ##STR2## A.sup.1, A.sup.2 and A.sup.3, independently of one another, represent 1,4-phenylene which is unsubstituted or substituted by halogen, cyano and/or methyl and in which 1 or 2 CH groups may be replaced by nitrogen, or represent trans-1,4-cyclohexylene, trans-1,3-dioxane-2,5-diyl or naphthalene-2,6-diyl, and ring A.sup.2 additionally represents 1,4-biphenylene; Z.sup.1 and Z.sup.4, independently of one another, denote a single covalent bond or --CH.sub.2 CH.sub.2 --; Z.sup.2 and Z.sup.3, independently of one another, denote a single covalent bond, --CH.sub.2 CH.sub.2 --, --COO--, --OOC--, --CH.sub.2 O--, --OCH.sub.2 --, --C.tbd.C--, --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.3 O--, --O(CH.sub.2).sub.3 -- or the trans-form of --CH.dbd.CH--CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 --CH.dbd.CH--, --CH.dbd.CH--CH.sub.2 --O-- or --O--CH.sub.2 --CH.dbd.CH--; with the proviso that, if R.
    Type: Grant
    Filed: January 28, 1991
    Date of Patent: June 10, 1997
    Assignee: Rolic AG
    Inventors: Stephen Kelly, Martin Schadt
  • Patent number: 5635471
    Abstract: The invention is concerned with the 7R/7S-diastereoisomer mixture of the formula ##STR1## in pure form, essentially free of the corresponding (4R)-isomers. The invention also concerns the 2R/2S-diastereoisomer mixture of the formula ##STR2## in pure form which is useful as an intermediate for producing I. In addition, the invention concerns a process for obtaining I by subjecting II to isochromane ring closure. Odorant compositions containing I and the use of I as an odorant are also described.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: June 3, 1997
    Assignee: Givaudan-Roure (International) SA
    Inventors: Georg Frater, Urs Muller, Martin Petrzilka
  • Patent number: 5585343
    Abstract: Oil-in-water (O/W) and water-in-oil (W/O) microemulsions of fragrance product formulations are provided. The microemulsions are clear or at least translucent, sprayable, and non-sticky. Novel combinations of anionic surfactant components (a) and hydrophilic coactives (highly water soluble component (b) or a mixture of highly water soluble (b)(i) and less water soluble polar (b)(ii) components) are used to obtain fragrance product formulations that are free or substantially free of ethanol. The anionic surfactants have a hydrophilic-lipophilic balance ("HLB") modified by the use of classes of anionic surfactant components (a) and commercially available hydrophilic component coactives ((b) or mixture of (b)(i) and (b)(ii)), not previously recognized as effective in this type of system.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: December 17, 1996
    Assignee: Givaudan-Roure Corporation
    Inventors: Thomas McGee, Saroja Narasimhan, Caryl E. Yeager
  • Patent number: 5536453
    Abstract: Light screening compositions which contain a compound of the formula ##STR1## wherein R.sup.1 represents H, C.sub.1-19 -alkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl,R.sup.2 represents H, C.sub.1-29 -alkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl,R.sup.3 represents H, C.sub.1-19 -alkyl, C.sub.1-19 -hydroxyalkyl, C.sub.1-19 -polyhydroxyalkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl or optionally lower-alkyl or oxy-lower alkyl substituted pyridyl, a polyether residue, a phenylsulphonic acid residue andR.sup.2 and R.sup.3 together with the N atom can also form a ring.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: July 16, 1996
    Assignee: Givaudan-Roure Corporation,
    Inventor: Ulrich Huber
  • Patent number: 5525589
    Abstract: The present invention is concerned with novel odorant compositions which are characterized by a content of cyclic compounds of the formula ##STR1## From this group of compounds the compounds I' with the meanings b), d), f) and g) are novel compounds.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: June 11, 1996
    Assignee: Givaudan-Roure Corporation
    Inventors: Franz Etzweiler, Daniel Helmlinger
  • Patent number: 5510325
    Abstract: A process for the preparation of hypoallergenic moss oils, comprising reacting the starting moss oil, a concrete or preferably an absolute thereof, with an aldehyde reducing agent, in an organic solvent medium.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: April 23, 1996
    Assignee: Givaudan-Roure Corporation
    Inventors: Charles Ehret, Martin Petrzilka
  • Patent number: 5510326
    Abstract: Novel odorant compositions which are characterized by a content of one or more compounds selected from the group consisting of tetrahydrofurans of structures 1 or 2, or tetrahydropyrans of structure 3. ##STR1## wherein R can be an acyclic, where acyclic refers to a chain of at least four carbon atoms substituted with at least three methyl groups in the chain, carbocyclic, where carbocyclic refers to a ring of 5-8 carbon atoms, and with at least two methyl groups on the ring, or bicyclic where bicyclic refers to two carbon rings, each ring having between 5-8 carbon atoms fused together, substituted with at least two methyl groups, and where R.sub.1 .dbd.CH.sub.3, or higher alkyl group, R.sub.2 .dbd.H, CH.sub.3, or higher alkyl group, R.sub.3 .dbd.H, or CH.sub.3, R.sub.4 and R.sub.5 .dbd.H, CH.sub.3, or higher alkyl group.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: April 23, 1996
    Assignee: Givaudan-Roure Corporation
    Inventor: Paul D. Noire
  • Patent number: 5495039
    Abstract: Novel organosiloxane compounds have at least one unit ##STR1## any other units being present in this organosiloxane are ##STR2## wherein R is a C.sub.1-8 alkyl or aryl, R.sup.1 is H or a C.sub.1-5 alkyl, R.sup.2 is H, C.sub.1-5 alkyl or OR.sup.1, R.sup.3 is a C.sub.1-5 alkyl, R" is H, a monovalent C.sub.1-8 hydrocarbon or halogenated hydrocarbon group, a is 0, 1 or 2, b 0, 1, 2 or 3 and n 1 to 6, provided the--C(R.sup.1).dbd.CH--(CR.sub.2.sup.1).sub.n --O--group and the two R.sup.2 groups are linked to the aromatic ring at the para- and meta-positions in relation to the group --CH.dbd.C[C(O)OR.sup.3 ].sub.2.The compounds are useful as UV sunscreens. Compositions containing them are also included.
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: February 27, 1996
    Assignee: Givaudan-Roure Corporation
    Inventors: Georg Frater, Rolf Schwarzenbach, Stephane F. M. Van Oycke
  • Patent number: 5481001
    Abstract: Light screening compositions which contain a compound of the formula ##STR1## wherein R.sup.1 represents H, C.sub.1-19 -alkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl,R.sup.2 represents H, C.sub.1-29 -alkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl,R.sup.3 represents H, C.sub.1-19 -alkyl, C.sub.1-19 -hydroxyalkyl, C.sub.1-19 -polyhydroxyalkyl, C.sub.2-29 -alkenyl, C.sub.2-29 -alkynyl, optionally lower-alkyl or oxy-lower alkyl substituted phenyl or optionally lower-alkyl or oxy-lower alkyl substituted pyridyl, a polyether residue, a phenylsulphonic acid residue andR.sup.2 and R.sup.3 together with the N atom can also form a ring.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: January 2, 1996
    Assignee: Givaudan-Roure Corporation
    Inventor: Ulrich Huber
  • Patent number: 5470991
    Abstract: The invention is concerned with a process for the manufacture of substituted furans which are, in particular, flavorants; thereby 4-hydroxy-2-yn-1-ones or acetals or ketals thereof are cyclized with nucleophilic S-compounds to 3-S-furans, whereby this 3-S atom can be optionally substituted, and the acetylene derivatives, the 4-hydroxy-2-yn-1-ones, can be optionally 1- and/or 4-alkyl or alkenyl substituted.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: November 28, 1995
    Assignee: Givaudan-Roure Corporation
    Inventor: Ulrich Huber