Patents Represented by Attorney Mary E. Picken
  • Patent number: 6045057
    Abstract: One aspect of the present invention is a spray gun adapted for spray-applying fiber-reinforced resins with ceramic fiber loadings of at least about 55 wt-%. Such novel spray gun has an inlet for admitting the fiber-reinforced resin; an air inlet for atomizing the fiber-reinforced resin; a catalyst inlet; and an outlet for expelling catalyzed fiber-reinforced resin from the spray gun. The spray gun also has a straight-line delivery channel in fluid communication with the resin inlet, the catalyst inlet, and the outlet. A flow actuator is provided for selectively actuating admission of the fiber-reinforced resin and the catalyst into the spray gun. The resin inlet and the catalyst inlet are disposed for admitting resin and catalyst, respectively, in line into the straight-line delivery channel.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: April 4, 2000
    Inventors: Ronald C. Moor, Robert E. Arnold
  • Patent number: 6025410
    Abstract: The liquid oligomeric compositions of this invention are made by the Michael addition reaction of acetoacetate functional donor compounds with multifunctional acrylate receptor compounds where the equivalent ratios of multifunctional acrylate to acetoacetate vary from .gtoreq.1:1 to .gtoreq.13.2:1 depending on the functionality of both multifunctional acrylate and acetoacetate. Unuseable gelled or solid oligomer products occur below the claimed ranges. The liquid oligomers of this invention are further crosslinked to make coatings, laminates and adhesives.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: February 15, 2000
    Assignee: Ashland Inc.
    Inventors: Thomas M. Moy, Laurence Dammann, Roman Loza
  • Patent number: 5965646
    Abstract: This invention is a preapplied liquid adhesive whose components, when dried and heated, react to form a polymer. Laminates made with the thermoset adhesive withstand exposure to 240.degree. F. (116.degree. C.). The adhesive combines urethane dispersions, carboxyl functional acrylic latices and tertiary amine blocking agent.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: October 12, 1999
    Assignee: Ashland Inc.
    Inventor: David B. Norby
  • Patent number: 5955199
    Abstract: This invention is the addition of an polyaldimine or polyketimine to the curative component of a two part polyurethane structural adhesive for bonding car, boat and truck parts.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: September 21, 1999
    Assignee: Ashland Inc.
    Inventors: Randy Allen Johnson, Timothy Allen Tufts
  • Patent number: 5945489
    Abstract: The liquid oligomeric compositions of this invention are made by the Michael addition reaction of acetoacetate functional donor compounds with multifunctional acrylate receptor compounds where the equivalent ratios of multifunctional acrylate to acetoacetate vary from .gtoreq.1:1 to .gtoreq.13.2:1 depending on the functionality of both multifunctional acrylate and acetoacetate. Unuseable gelled or solid oligomer products occur below the claimed ranges. The liquid oligomers of this invention are further crosslinked to make coatings, laminates and adhesives.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: August 31, 1999
    Assignee: Ashland, Inc.
    Inventors: Thomas M. Moy, Laurence Dammann, Roman Loza
  • Patent number: 5932666
    Abstract: This invention is a thermoplastic saturated polyester low profile additive (low profile additive) useful in sheet molding compounds for parts, especially vehicle parts. The additive has a major component derived from aromatic compounds such as terephthalic acid including recycled polyethylene terephthalate. Asymmetrical glycols are an important ingredient and can be used to digest recycled PET to make oligomeric glycols which are reacted with acids having fewer than 12 carbon atoms to make one of the low profile additives of this invention.
    Type: Grant
    Filed: March 25, 1998
    Date of Patent: August 3, 1999
    Assignee: Ashland Inc.
    Inventor: Dennis Herbert Fisher
  • Patent number: 5880180
    Abstract: This invention is the addition of an aldimine to enhance the ability of thermoplastic low profile additives to improve the surface quality of cured sheet molding compound vehicle parts.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: March 9, 1999
    Assignee: Ashland Inc.
    Inventor: Cynthia L. Smith
  • Patent number: 5861466
    Abstract: Vinyl ester resins processed until low epoxy values are reached are storage stable for two weeks at 54.degree. C. (130.degree. F.). Adding a copper salt inhibitor also provides two weeks storage stability at 54.degree. C. (130.degree. F.). A synergistic effect is observed if both low epoxy values are reached and copper naphthenate inhibitor is used, extending shelf life stability to two months at 54.degree. C. (130.degree. F.).
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: January 19, 1999
    Assignee: Ashland Inc.
    Inventor: Danny G. Hartinger
  • Patent number: 5837089
    Abstract: This invention is a method of using a heat activatable adhesive for laminating vinyl sheet to wood. The organic solvent-free adhesive combines a reactive styrene-acrylic latex emulsion, an ethylene vinyl acetate copolymer emulsion, and a wax. After application to the vinyl substrate the adhesive is heat activated at temperatures as low as 160.degree. F. (71.degree. C.) and the laminate resists delamination at 190.degree. F. (88.degree. C.).
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: November 17, 1998
    Assignee: Ashland Inc.
    Inventor: Glenn Robert Magrum
  • Patent number: 5763555
    Abstract: A tacky pressure sensitive water-borne acrylic emulsion adhesive composition prepared with >1% multifunctional monomer has Tg<0.degree. C., >90% gel content and is web coatable. The dried adhesive film anchors readily and remains easily removeable from diverse substrates.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: June 9, 1998
    Assignee: Ashland Inc.
    Inventor: Michael J. Skoglund
  • Patent number: 5756554
    Abstract: This invention is a thermoplastic saturated polyester low profile additive (low profile additive) useful in sheet molding compounds for parts, especially vehicle parts. The additive has a major component derived from aromatic compounds such as terephthalic acid including recycled polyethylene terephthalate. Asymmetrical glycols are an important ingredient and can be used to digest recycled PET to make oligomeric glycols which are reacted with acids having fewer than 12 carbon atoms to make one of the low profile additives of this invention.
    Type: Grant
    Filed: February 2, 1996
    Date of Patent: May 26, 1998
    Assignee: Ashland Inc.
    Inventor: Dennis Herbert Fisher
  • Patent number: 5716701
    Abstract: This adhesive for laminating vinyl face stock to solid substrates has good initial peel strength, retains peel strength and is emulsion polymerized and compounded in the absence of sodium or lithium cations.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: February 10, 1998
    Assignee: Ashland Inc.
    Inventors: Michael J. Skoglund, Shang Lee
  • Patent number: 5671591
    Abstract: This invention is an integrated system for making containers and filling them with ultra high purity chemicals all within a cleanroom environment so that the chemicals avoid contamination and meet semiconductor manufacturing purity standards.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: September 30, 1997
    Assignee: Ashland, Inc.
    Inventor: Bruce Forester Fleenor
  • Patent number: 5643983
    Abstract: The method of this invention makes multi-ply wood composite laminates from several wood veneer sheets using a 100% solids single component adhesive mixture, prepared in the absence of water, of isocyanate terminated prepolymer, polymeric diisocyanate and polysiloxane or aliphatic cyclosaturated C.sub.14 -C.sub.30 hydrocarbon.
    Type: Grant
    Filed: August 30, 1995
    Date of Patent: July 1, 1997
    Assignee: Ashland Inc.
    Inventor: Shang Lee
  • Patent number: 5552478
    Abstract: This invention is a thermoplastic saturated polyester low profile additive (low profile additive) useful in sheet molding compounds for parts, especially vehicle parts, the additive has a major component derived from aromatic compounds such as terephthalic acid including recycled polyethylene terephthalate. Asymmetrical glycols are an important ingredient and can be used to digest recycled PET to make oligomeric glycols which are reacted with acids having fewer than 12 carbon atoms to make one of the low profile additives of this invention.
    Type: Grant
    Filed: February 2, 1996
    Date of Patent: September 3, 1996
    Assignee: Ashland Inc.
    Inventor: Dennis H. Fisher
  • Patent number: 5548056
    Abstract: This invention is a method of making a laminated untreated fiberglass reinforced polyester substrates and a cured polyureaurethane adhesive composition. The prepolymer component of the adhesive is the reaction product of a slowly reacting polyisocyanate and a polyol.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: August 20, 1996
    Assignee: Ashland Inc.
    Inventor: Daniel A. Chung
  • Patent number: 5521232
    Abstract: The invention is a molding composition and molding process for use in the manufacture of lightweight composite vehicle parts and construction parts having smooth surfaces. The molding process may be at low pressures. The composition includes kaolin clay filler and, optionally, hydrophilic fumed silica thixotrope.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: May 28, 1996
    Assignee: Ashland Inc.
    Inventors: Gilbert M. Gynn, David W. Hearn
  • Patent number: 5504151
    Abstract: This invention is the polycapped oligomer adduct of a long chain fatty acid with a multi hydroxy functional or multi epoxy functional compound. This polycapped oligomer is useful in resin compositions to enhance the performance of thermoplastic low profile additives which improve the surface quality of molded composites such as automotive body panels.
    Type: Grant
    Filed: November 8, 1994
    Date of Patent: April 2, 1996
    Assignee: Ashland Inc.
    Inventors: Dennis H. Fisher, Timothy A. Tufts, C. Timothy Moss
  • Patent number: D369499
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: May 7, 1996
    Assignee: Ashland Inc.
    Inventors: Paul G. Scott, Thomas C. Starner, Zach Hatcher
  • Patent number: D429255
    Type: Grant
    Filed: February 19, 1998
    Date of Patent: August 8, 2000
    Assignee: Marathon Ashland Petroleum LLC
    Inventors: J. Michael Wilder, Phillip G. Collins, Franklin T. Pleasants