Abstract: The invention described novel compounds of formula ##STR1## wherein the general symbols are as defined in claim 1, as stabilisers for protecting organic materials, in particular polymers and lubricants, against thermal, oxidative or light-induced degradation.
Type:
Grant
Filed:
February 26, 1996
Date of Patent:
June 30, 1998
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Peter Nesvadba, Samuel Evans, Christoph Krohnke, Jurg Zingg
Abstract: A photopolymerizable composition comprising (a) at least one ethylenically unsaturated photopolymerizable compound, and (b) alkoxyphenyl-substituted bisacylphosphine oxides of the formula I ##STR1## in which R.sub.1 and R.sub.2 are identical or different and are a radical of the formula II ##STR2## in which R.sub.4 and R.sub.5 independently of one another are C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.12 alkoxy, andR.sub.6, R.sub.7 and R.sub.8 independently of one another are hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy or halogen,R.sub.3 is a radical of the formula III ##STR3## in which R.sub.9 is C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl, naphthyl, phenyl-C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.12 alkenyl, --CF.sub.3 or ##STR4## or R.sub.9 is a radical of the formula IV or V ##STR5## in which X is for example C.sub.1 -C.sub.16 alkylene, C.sub.4 -C.sub.12 alkenylene or is xylylene,R.sub.10 is for example hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.
Abstract: The invention relates to a color-photographic recording material which comprises a magenta coupler and, as stabilizer, at least one compound of formula (Ia), (Ib) or (II), where the radicals are as defined in claim 1, and to the novel stabilizers.
Abstract: o-Hydroxyphenyl-s-triazines are described which contain at least two alkoxyphenyl substituents. They have the formula (1). The compounds according to the invention are suitable as stabilizers for textile fiber materials, in particular polyester fiber materials, and for organic polymers. Furthermore, they are suitable for use as sunscreens in cosmetic preparations.
Type:
Grant
Filed:
September 17, 1996
Date of Patent:
June 2, 1998
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Jean-Luc Birbaum, Jurgen Kaschig, Dieter Reinehr, Manfred Rembold, Andre Schmitter, Helmut Luther, Bernd Herzog, Dietmar Huglin
Abstract: Compounds selected from the series consisting of the perylenecarboximide, quinacridone, isoindoline, indigoid, azo, benzodipyrrolone, benzodifuranone, furanofuran, pyrrolo?2,5-b!pyrrole and bianthraquinone chromophores containing at least one grouping of formula ##STR1## wherein each A may be N--CN or O, with the proviso that at least one A must be N--CN, X is --N(R)--, --O-- or --S--, R is hydrogen, C.sub.1 -C.sub.18 alkyl, unsubstituted or halogen- or C.sub.1 -C.sub.4 alkyl-substituted phenyl, benzyl or phenethyl, and m and n are each independently of the other 0 or 1.Depending on the nature of their substituents, these compounds can be used as polymer-soluble dyes or as pigments for coloring high molecular weight organic material. They are distinguished by a surprisingly high solid-state fluorescence.
Type:
Grant
Filed:
March 22, 1996
Date of Patent:
May 26, 1998
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
John S. Zambounis, Zhimin Hao, Abul Iqbal
Abstract: Coatings comprisingA) a binder based on an organic polymer andB) as stabilizer against damage by light, heat and oxygen, a 2-(2'-hydroxyphenyl)-1,3-pyrimidine of the formula I ##STR1## in which the radicals R.sub.1 to R.sup.6 are as defined in claim 1 have an outstanding resistance to the damaging effects of light, oxygen and heat. Compounds of the formula Ib defined in claim 18 are suitable in general for the stabilization of organic material.
Type:
Grant
Filed:
June 7, 1996
Date of Patent:
May 19, 1998
Inventors:
Andreas Valet, Jean-Luc Birbaum, Gerhard Rytz, Norbert Wurms
Abstract: This invention is a process for the preparation of a pyrocarbonic acid diester of formula (I) ##STR1## wherein R.sub.1 and R.sub.1 ' are each, independently of the other, an optionally substituted branched or straight-chain C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 alkenyl, C.sub.3 -C.sub.24 alkynyl, C.sub.4 -C.sub.12 cycloalkyl, C.sub.4 -C.sub.12 cycloalkenyl or C.sub.7 -C.sub.24 aralkyl,by reacting at least one ester carbonate of formula (II) ##STR2## with 40-50 mol % of a sulfochloride of formula (IV) ##STR3## in the presence of 0.8-5 mol % of a catalyst of formula (V) ##STR4## and with minor amounts of a heterocyclic aromatic amine in a nonpolar inert solvent,in which process the amount of heterocyclic aromatic amine is 1-3 mol % and the reaction is carried out in the temperature range from -10.degree. C. to +25.degree. C., all molar amounts being based on 100 mol % of ester carbonate of formula (II).
Abstract: A polyester/polycarbonate (PES/PC) blend having enhanced properties as virgin material and as recyclate comprisesa) at least one phosphite,b) at least one sterically hindered phenol,c) at least one compound promoting the reaction of an epoxy resin with a PES/PC blend which is a Lewis base, andd) at least one difunctional epoxy resin, with 0.01 to 10 parts of component c) being used per 100 parts of PES/PC blend.
Type:
Grant
Filed:
November 25, 1996
Date of Patent:
April 28, 1998
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Rudolf Pfaendner, Kurt Hoffmann, Heinz Herbst
Abstract: An aqueous composition for the pretanning of hide pelts or for the retanning of leather comprises (A) an aliphatic dialdehyde containing 2 to 8 carbon atoms, (B) an anionic aromatic tanning agent, (C) water and, if desired, (D) an acid. The leather tanned or pretanned with this aqueous composition exhibits a good degree of whiteness and has a high shrinkage temperature.
Abstract: The present invention provides a composition comprising copper phthalocyanine containing 0-4 chlorine atoms having a crystal size in the range of from 0.01 to 0.2 .mu.m, and from 10 to 15% by weight of an ionic complex formed from copper phthalocyanine sulphonic acid and a quaternary amine of the formula (I) ##STR1## where R.sub.1 is a C.sub.1 -C.sub.6 alkyl group; R.sub.2 is a C.sub.1 -C.sub.18 alkyl group; R.sub.3 is the same as R.sub.2 or is a hydroxyethyl or ethoxylated ethyl group having up to 5 ethyleneoxy units: R.sub.4 is a hydroxyethyl or ethoxylated ethyl group having up to 5 ethyleneoxy units; and X is a halogen atom.
Abstract: The instant invention relates to novel compounds of formula (II) ##STR1## wherein R, R.sup.2 and x are as defined in the Specification. These compounds retard oxidation of, confer protection under extreme pressures to and reduce frictional wear of lubricants and hydraulic fluids.
Abstract: n and m are independently of one another 0 or 1,R.sub.1, R.sub.2, R.sub.3, R.sub.4 and X are as defined in claim 1,are suitable as photoinitiators for the polymerization of ethylenically unsaturated compounds.
Abstract: Compounds of the formula I ##STR1## in which the general symbols are as defined in claim 1, as stabilizers for organic materials against thermal, oxidative or light-induced degradation are described.
Abstract: The invention relates to a method of protecting surfaces of wood against damage by light by treatment with a coating composition comprising a benzophenone of the formula I ##STR1## in which the substituents are defined as in claim 1.
Abstract: The invention relates to mixed crystals of 1,4-diketopyrrolo?3,4-c!pyrroles, consisting of 1 mol each of two different compounds of formulae ##STR1## as well as single-phase solid solutions of two different compounds of formulae I and II, wherein the diketopyrrolopyrrole having the smaller geometrical constitution is present in an amount of 53 to 70 mol %. A and B are as defined in claim 1. The novel mixed crystals as well as the novel solid solutions are admirably suited for pigmenting organic material of high molecular weight.
Type:
Grant
Filed:
September 28, 1995
Date of Patent:
January 13, 1998
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Zhimin Hao, Abul Iqbal, Bernhard Medinger, Olof Wallquist
Abstract: Water-emulsifiable or -dispersible physical forms of sterically hindered mines, UV absorbers and antioxidants and their use for thermal and photochemical stabilization of materials of plastics, textile coatings, imitation leather and leather are described. The physical forms comprisea) a sterically hindered amine,b) a UV absorber and/orc) an antioxidant andd) if appropriate, water and other additives.
Type:
Grant
Filed:
June 10, 1996
Date of Patent:
January 6, 1998
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Franz Wyss, Vladimir Arnold, Helena Dbaly, Gisbert Leuschner, Manfred Rembold, Alois Puntener
Abstract: Novel dihydrotriazine compounds corresponding to formula (2') ##STR1## wherein R'.sub.1, R'.sub.2 and R'.sub.3 are each independently of one another hydrogen, halogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or --C.tbd.N, with the proviso that R'.sub.1, R.sub.'2 and R'.sub.3 are not simultaneously hydrogen. The above dihydrotriazines are useful as starting compounds for the preparation of UV absorbers.
Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilisers, heat stabilisers and oxidation stabilisers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.
Abstract: The present invention relates to novel liquid phenolic antioxidants, to organic materials stabilized with said compounds against thermal, oxidalive and/or actinic degradation, and to the use of said novel compounds as stabilizers.
Abstract: A process for the preparation of mixed crystals of 1,4-diketopyrrolo?3,4-c!pyrroles, consisting of 1 mol each of two different compounds of formula ##STR1## by heating a corresponding mixture in solid form to the temperature range from 220.degree. to 380.degree. C.A and B are, for example, each a group of formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently hydrogen, chloro, bromo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylamino, phenyl or --CN, G is --O--, --NR.sub.7 --, --N.dbd.N-- or --SO.sub.2 --, R.sub.3 and R.sub.4 are hydrogen, and R.sub.7 is hydrogen, methyl or ethyl.The mixed crystals and solid solutions obtained are excellently suited for pigmenting high molecular weight material.
Type:
Grant
Filed:
September 12, 1996
Date of Patent:
December 2, 1997
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Jin Mizuguchi, Zhimin Hao, Olof Wallquist, Abul Iqbal