Patents Represented by Attorney Nelson Littell, Jr.
  • Patent number: 4547318
    Abstract: This invention is directed to a process for the preparation of color-stable, light-colored aqueous salt pastes of wash-active esters of .alpha.-sulfofatty acids with monohydric C.sub.1 -C.sub.8 -alcohols by a combined bleaching treatment of dark-colored .alpha.-sulfofatty acid ester salt paste with hydrogen peroxide and alkali metal hypochlorite. According to the process, dark-colored .alpha.-sulfofatty acid ester salt paste is first subjected in a preliminary bleaching step to bleaching with alkali metal hypochlorite in a neutral to mildly alkaline aqueous medium, any excess metal hypochlorite is removed, and the paste is subjected in a final bleaching step to bleaching in a mildly acidic medium with hydrogen peroxide or with one or more compounds which yield hydrogen peroxide.
    Type: Grant
    Filed: April 26, 1984
    Date of Patent: October 15, 1985
    Assignee: Henkel KgaA
    Inventors: Dietrich Kloetzer, Karl-Heinz Linde, Klaus Ojust
  • Patent number: 4545984
    Abstract: The invention concerns cosmetic agents containing compounds of the general formula (I) ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 represent independently of one another a hydrogen atom, an intermediate alkyl group with 3 to 10 carbon atoms, a halogen atom, preferably a chlorine atom, a hydroxy group, an aryl group, an alkoxy group with 1 to 20 carbon atoms, substituted, if needed, with aryl, hydroxy, amino, alkoxy as well as aryloxy groups, or a carboxyl group esterified with an intermediate-chain alkyl group with 2 to 12 carbon atoms or with an aralkyl group, or two of the radicals R.sup.1 --R.sup.3 represent a naphthalene ring together with the benzene ring, and Y stands for an alkoxy group with 1 to 12 carbon atoms or an aralkoxy group. The compounds are used in amounts of 0.01 to 20, preferably 1 to 10, percent by weight, calculated with regard to the total preparation.
    Type: Grant
    Filed: November 15, 1982
    Date of Patent: October 8, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hinrich Moller, Siegfried Wallat, Friedhelm Bartnik
  • Patent number: 4539117
    Abstract: A method for improving the separating action in the ultrafiltration of aqueous solutions containing high-molecular-weight organic compounds including water-soluble anionic and/or non-ionic surface-active compounds consisting essentially of subjecting an aqueous solution containing high-molecular-weight organic compounds including water-soluble anionic and/or non-ionic surface-active compounds to an ultrafiltration through a porous membrane in the presence of olefinically-unsaturated C.sub.16-22 fatty acids or water-soluble salts thereof, in a weight ratio of surface-active compound to fatty acid or salt of from 20:1 to 1:1 and recovering said aqueous solution substantially separated from said high-molecular-weight organic compounds. The retention power for water-soluble tensides can be 0.9 or more with this measure (without the addition, .ltoreq.0.1 to 0.5).
    Type: Grant
    Filed: July 31, 1981
    Date of Patent: September 3, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter Meyer, Christian Rossmann, Friedbert Zetzsche
  • Patent number: 4536325
    Abstract: Stable oil-in-water emulsions containing more than 60% by weight of non-aqueous phase may be prepared using water-soluble salts of monoacyl cyanamides, of which the acyl radical contains from 10 to 20 carbon atoms, as emulsifiers. The monoacyl cyanamides of C.sub.12 -C.sub.18 fatty acids are preferably used in the form of their sodium salts. The oil-in-water emulsions preferably contain from 70 to 95% by weight of non-aqueous phase and from 0.1 to 3% by weight of emulsifier.
    Type: Grant
    Filed: January 24, 1984
    Date of Patent: August 20, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Gerhard Borggrefe, Christian Hase
  • Patent number: 4533490
    Abstract: A process for producing in situ foams based on alkali metal silicates characterized in that an aqueous alkali metal silicate solution on the one hand and a hardener solution on the other hand are accomodated in separate pressurized containers A and B, prior to use the hardener solution in container B is added to and mixed with the silicate solution in container A in the presence of a suitable emulsifier for foam formation and a propellent gas liquid under high pressure between 0.degree. and 50.degree. C., and, on actuation of the discharge valve of container A, an alkali metal silicate foam is discharged. The alkali metal silicate foams formed are distinguished by non-inflammability, high temperature stability and good heat-insulating properties and are used as a filling, construction and insulating material or the like in the building industry.
    Type: Grant
    Filed: July 19, 1983
    Date of Patent: August 6, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hermann Kluth, Bernhard Roderhoff, Wolfgang Friedemann, Jurgen Wegner, Wolfgang Dierichs
  • Patent number: 4528286
    Abstract: Aryl-mercapto-lower-alkanamides having the following formula ##STR1## wherein R.sup.1 is selected from the group consisting of phenyl, C.sub.1-4 -alkylphenyl, halophenyl, hydroxyphenyl, C.sub.1-4 -alkoxyphenyl, aminophenyl, acetamidophenyl, naphthyl, diphenyl; R.sup.2 and R.sup.3, independently represent hydrogen or C.sub.1-14 -alkyl; Y represents NR.sup.4 R.sup.5 wherein R.sup.4 and R.sup.5 independently represent hydrogen, C.sub.1 -6-alkyl, C.sub.2-3 -hydroxyalkyl, benzyl, anilyl, and taken together represent piperidyl or morpholinyl are useful for reducing cell sebum production in a mammal in the form of a topical cosmetic preparation.
    Type: Grant
    Filed: November 15, 1982
    Date of Patent: July 9, 1985
    Assignee: Henkel Kommanditgesellschaft (KGaA)
    Inventors: Hinrich Moller, Siegfried Wallat
  • Patent number: 4527992
    Abstract: This invention relates to a process for producing waterproof leathers and skins by tanning, retanning, dyeing, stuffing, and fixing which is characterized in that, after tanning and, optionally, dyeing, stuffing agents (A) in the form of oxidized or oxidized and partly sulfonated long-chain hydrocarbons of waxes and impregnating agents (B) in the form of copolymers or from 60 to 95 mol percent of (meth) acrylic acid and from 5 to 40 mol percent of an ester, amide or nitrile of (meth) acrylic acid having a molecular weight of from 800 to 10,000 in salt form are successively used in the same bath, followed by acidification, fixing and finishing. The co-use of the impregnating agents (B) with the particular stuffing agents (A) results in much greater degree of resistance to water penetration than that obtained by the use of the stuffing agent (A), alone.
    Type: Grant
    Filed: September 8, 1983
    Date of Patent: July 9, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Herbert Friese, Wolfgang Prinz
  • Patent number: 4528149
    Abstract: Hollow, spherical bodies of solidified alkali metal silicates having the general formulaM.sub.2 O:x.SiO.sub.2where M is an alkali metal and x has a value greater than 3.6 and less than 12, said hollow bodies having an external diameter of from 1 to 5 mm, shell thickness of from 0.2 to 0.6 mm, a water content of from 10% to 30% by weight and a solids content of at least 70% by weight, the M.sub.2 O content of the shell of said hollow bodies being greater internally and less toward the exterior surface, as well as the process of producing said hollow, spherical bodies of solidified alkali metal silicate. The hollow spheres are expandable resulting in the formation of foam spheres having a loose surface. The hollow spheres are useful to give a uniform filling of narrow cavities and in the covering of liquids by floatable, optionally surface-active silicate-containing materials.
    Type: Grant
    Filed: December 30, 1983
    Date of Patent: July 9, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Winfried Wichelhaus, Christine Schroder
  • Patent number: 4526694
    Abstract: A composition for coating a flexible textile sheet for the treatment of moist wash in a mechanical clothes drier, consisting essentially of: an active substance selected from the group consisting of textile softening agents, antistatic substances, fragrances, mixtures of the above and mixtures of the above with nonionic emulsifiers and additives, where said textile softening agents and antistatic substances are selected from the group consisting of quaternary nitrogen compounds derived from ammonia or imidazoline and having from 1 to 2 long chain hydrocarbyl groups with from 8 to 26 carbon atoms and mixtures of said quaternary nitrogen compounds with up to 80% by weight of the mixture of the condensation product of a higher fatty acid triglyceride with a hydroxy lower alkylpolyamine, wherein said composition contains from 0.2% to 5% by weight of at least one aliphatic low-molecular-weight hydroxycarboxylic acid, as well as, optionally, from 0.
    Type: Grant
    Filed: December 14, 1983
    Date of Patent: July 2, 1985
    Assignee: Henkel Kommanditgesellschaft (Henkel KGaA)
    Inventors: Rolf Puchta, Hans Nusslein, Alexander Boeck, Benno Streschnak
  • Patent number: 4525234
    Abstract: This invention is directed to a process for preparing an adhesive, pre-gelled plastisol composition which comprises the steps of(a) mixing polyvinyl acetate or copolymers of vinyl acetate with one or more comonomers selected from the group consisting of vinyl alcohol C.sub.3 -C.sub.18 -carboxylic acid esters, ethylene, propylene, butylene, and vinyl chloride with conventional non-gelled plastisol mixtures based upon (i) polyvinyl chloride and/or polymethyl methacrylate and (ii) one or more suitable plasticizers in a ratio of from about 10 to 200 parts by weight of polyvinyl chloride or copolymers of vinyl acetate to 100 parts by weight of polyvinyl chloride and/or polymethyl methacrylate,(b) heating the mixture from step (a) to a temperature of from about 80.degree. to 130.degree. C.The resulting composition is useful in joining, sealing, or stiffening automobile body components.
    Type: Grant
    Filed: August 21, 1984
    Date of Patent: June 25, 1985
    Assignee: Henkel Kommanditgesellschaft (KGaA)
    Inventors: Julius Herold, Ingeborg Geisen
  • Patent number: 4524010
    Abstract: A spray-dried, high-sudsing detergent granulate is disclosed having a bulk density of not more than 450 gm/l and a high content of anionic tensides, which is characterized by a granule structure resistant to mechanical and climatic influences. The detergent granulate contains a tenside component of alkylbenzene sulfonates and, possibly, fatty alcohol sulfates, a builder component of sodium tripolyphosphate, finely crystalline sodium aluminosilicate (zeolite NaA) and sodium silicate. For the preparation, an aqueous slurry is sprayed in spray-drying equipment. The obtained spray-dried product has a porous granule structure with a mean granule size of 0.4 to 0.8 mm. The bulk density is preferably in the range from 250 to 400 gm/l.
    Type: Grant
    Filed: November 16, 1982
    Date of Patent: June 18, 1985
    Assignee: Henkel Kommanditgesellschaft (KGaA)
    Inventors: Herbert Reuter, Wolfgang Seiter, Ingo Wegener
  • Patent number: 4522740
    Abstract: Polyethylene glycol ethers of the type obtained by the addition of from 4 to 20 parts by weight of ethylene oxide onto 1 part by weight of polyglycerol having a hydroxyl number in the range from 900 to 1200 and subsequent etherification of the free hydroxyl groups with linear or branched alkyl halides containing from 4 to 8 carbon atoms, and their use as foam-inhibiting additives for low-foam cleaning agents.
    Type: Grant
    Filed: April 18, 1984
    Date of Patent: June 11, 1985
    Assignee: Henkel Kommanditgesellschaft
    Inventors: Karl Schmid, Horst Baumann, Jurgen Geke, Hans-Gunther Germscheid, Werner Ludecke, Robert Piorr, Christian Rossmann, Rolf Scharf, Hans-Joachim Schlussler
  • Patent number: 4520831
    Abstract: In order to neutralize the electrostatic charging of the hair which occurs where a plastic comb is used, the comb is made up of at least one section which negatively charges the hair during combing and at least one section which positively charges the hair during combing.
    Type: Grant
    Filed: March 16, 1984
    Date of Patent: June 4, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Henning Schumann, Peter Busch, Detlef Fischer, Klaus Thiele
  • Patent number: 4519949
    Abstract: New .DELTA.1,4,9(11)-pregnatrien-3-one-2o-carboxlic acid compounds are described, corresponding to general formula I below: ##STR1## in which X represents halogen, particularly chlorine or bromine or NH.sub.2. There is also described the process for producing compounds corresponding to general formula I by dehydrating the corresponding saturated starting compounds hydroxylated in the 11-position to form the 9(11)-ene-bond, after which the product obtained is, if desired, subjected to chemical transformation into the end products corresponding to general formula I. In particular, it is possible to carry out formation of the 20-acid halides and dehydration in the 9(11)-position in a single process step.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: May 28, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Wolfgang Preuss
  • Patent number: 4511487
    Abstract: A detergent paste for use in dishwashers comprised of a pasty, thixotropic cleaning agent with a viscosity of at least 30 Pa.s at 20.degree. C. as determined with a rotational viscosimeter at a spindle speed of 5 revolutions per minute and(A) essentially a mixture of hydrated sodium tripolyphosphate and hydrated sodium metasilicate in the form of sodium tripolyphosphate hexahydrate and sodium metasilicate pentahydrate as finely ground substances having an average particle size of less than 0.3 mm,(B) an optional active chlorine compound and(C) a thickening agent compatible therewith for example foliated silicates of the hectorite type and a method of washing dishes in a dishwasher.
    Type: Grant
    Filed: August 22, 1983
    Date of Patent: April 16, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst Pruhs, Theodor Altenschopfer
  • Patent number: 4503244
    Abstract: A topical cosmetic preparation for the treatment of seborrhea containing a sebosuppressively effective amount of at least one alkoxybenzoic acid ester having the formula ##STR1## wherein R.sup.1 represents a C.sub.6-20 -n-alkyl and R.sup.2 is a member selected from the group consisting of --CH.sub.2 OR.sup.3, --C.sub.2 H.sub.4 OR.sup.3, --CH.sub.2 OC.sub.2 H.sub.4 OR.sup.3, --CH.sub.2 OH, --C.sub.2 H.sub.4 OH, --CH(CH.sub.3)OH, --CH.sub.2 NR.sup.3 R.sup.4, --C.sub.2 H.sub.4 NR.sup.3 R.sup.4, --CO.sub.2 R.sup.3 and --CH.sub.2 CO.sub.2 R.sup.3, wherein R.sup.3 and R.sup.4 are C.sub.1-4 -alkyl, as an antiseborrheic, and further containing conventional vehicles and additives for topical application; as well as the process for reducing sebaceous cell sebum production in a mammal in need thereof using the above cosmetic preparation; and the alkoxybenzoic acid esters of the above formula.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: March 5, 1985
    Assignee: Henkel Kommanditgesellschaft
    Inventors: Hinrich M/o/ ller, Siegfried Wallat
  • Patent number: 4486314
    Abstract: Process for the treatment of sewage by using conventional precipitants and flocculants, like silicates, iron- or aluminum salts or organic polymers, and in addition about 0.1-10 (0.03-3) g/l sewage of X-ray amorphous or crystalline, finely-divided alkali- and/or alkaline earth-alumosilicates of the formula:x cat.sub.2/n.Al.sub.2 O.sub.3.y SiO.sub.2where x=0.7-1.5; y=0.8-6; cat=Na, K, Mg or Ca; n=1-2. The compounds contain preferably bound water. The alumosilicate is added preferably in the form of an aqueous suspension (pH 3.5-5.0) to the sewage to be treated, adjusted if necessary to a weakly alkaline to weakly acid pH-value (5-10). The pH-value is preferably adjusted with strong acids, preferably sulfuric acid.In sewage from laundries, which can already contain x g alumosilicates, the amount is reduced by x g.Advantage: Compared to known processes, the dirt elimination rate is greater and/or the consumption of precipitants is reduced.
    Type: Grant
    Filed: February 23, 1984
    Date of Patent: December 4, 1984
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Edgar Koppelmann, Gerd Krapp, Klaus Schumann, Heinz G. Smolka
  • Patent number: 4485027
    Abstract: This invention is directed to a process for cleaning solid surfaces with aqueous alkaline cleaning compositions comprising (a) strongly alkaline active-substance concentrates and (b) acidic active-substance concentrates comprising dispersions of boric acid or alkali metal borates in orthophosphoric acid. Component (a) is present in an excess over component (b) sufficient to cause an alkaline medium.
    Type: Grant
    Filed: September 30, 1983
    Date of Patent: November 27, 1984
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Christian Rossmann, Helga Burger
  • Patent number: 4476037
    Abstract: An aqueous concentrate of a tenside of the sulfate and sulfonate type containing at least about 20% by weight of a water-soluble salt of at least one anionic tenside selected from the group consisting of alkyl polyalkylene ether glycol sulfates, alkaryl polyalkylene ether glycol sulfates, alkyl polyalkylene ether glycol sulfosuccinates, alkaryl polyalkylene ether glycol sulfosuccinates, alkyl sulfates, alkaryl sulfonates and alkyl sulfosuccinates and a viscosity reducing amount of a water-soluble salt of a polyglycol ether sulfate selected from the group consisting of monosulfates of poly-lower alkylene ether glycols having a molecular weight of at least 600, disulfates of poly-lower alkylene ether glycols having a molecular weight of at least 600 and mixtures thereof and from 0 to a viscosity reducing amount of a poly-lower alkylene ether glycol having a molecular weight of at least 1,500; as well as the process of improving the flow behavior of difficultly pourable aqueous concentrates of at least one tensi
    Type: Grant
    Filed: February 24, 1983
    Date of Patent: October 9, 1984
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Uwe Ploog, Ingo Wegener, Johann Glasl, Werner Erwied, Bernhard Bartnick, Rainer Hofer
  • Patent number: 4465718
    Abstract: This invention is directed to compounds of the formula ##STR1## wherein R is a radical derived from an organic diisocyanate or triisocyanate and n is 2 or 3, and the preparation thereof. The compounds are especially useful in anaerobic adhesives and sealants.
    Type: Grant
    Filed: November 29, 1983
    Date of Patent: August 14, 1984
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Werner Gruber