Patents Represented by Attorney, Agent or Law Firm Noland J. Cheung
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Patent number: 7442277Abstract: A process for the removal of at least one volatile compound from a reactive or unreactive mixture of substances with the aid of at least one micro-evaporator, the micro-evaporator displaying channels for carrying the mixture of substances having a hydraulic diameter of 5 to 1000 ?m and a specific evaporator surface area of at least 103 m2/m3.Type: GrantFiled: July 23, 2004Date of Patent: October 28, 2008Assignee: Bayer MaterialScience LLCInventors: Kurt-Manfred Küpper, Oswald Wilmes, Hartmut Steenbeck, Almut Nagel
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Patent number: 7425516Abstract: This invention relates to solutions of polyurethaneureas in ?-butyrolactone or mixtures of ?-butyrolactone with toxicologically acceptable organic solvents. A process for coating substrates using these polyurethaneurea solutions, and substrates coated by said process are also provided. The substrates coated according to the invention are preferably textile products or leather, but materials such as wood or concrete can also be coated according to the invention.Type: GrantFiled: February 17, 2006Date of Patent: September 16, 2008Assignee: Bayer MaterialScience AGInventors: Jürgen Köcher, Gerald Kurek, Holger Casselmann, Jürgen Urban, Thomas Feller
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Patent number: 7396875Abstract: The present invention is directed to a waterborne, UV-curable polyurethane emulsion and the use thereof in producing soft touch coatings. The emulsion is prepared by a) reacting specified hydroxy-functional components with di- and/or polyisocyanates, b) forming a dispersion of the resultant product with water and reacting the dispersion with amine functional materials.Type: GrantFiled: January 20, 2004Date of Patent: July 8, 2008Assignee: Bayer MaterialScience LLCInventors: Aaron A. Lockhart, Michael J. Dvorchak, Lyubov K. Gindin
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Patent number: 7393465Abstract: A process for preparing hydrophobic polyols that includes reacting A) a mixture having an OH content of from 180 to 300 mg KOH/g, a viscosity at 23° C. of from 5000 to 20 000 mPas and an OH functionality of from 2.8 to 4.5 including from 5 to 20 wt. % of 3-pentadecadienylphenol, from 5 to 10 wt. % of 3-pentadecadienyl-recorcinol and from 1 to 5 wt. % of 2-methyl 3-pentadecadienylrecorcinol; with B) alkylene oxides (AO) with addition of the AO monomers onto the AO-reactive groups of component A); the ratio of the amounts of A) to B) being from 1:9 to 9:1; where the hydrophobic polyols have an OH number of from 140 to 220 mg KOH/g and a viscosity at 23° C. of from 1000 to 4000 mPas. The hydrophobic polyols can be used in polyurethane systems, in coatings, adhesive bonds, sealants or moulding compounds, which can be used to coat substrates.Type: GrantFiled: February 24, 2005Date of Patent: July 1, 2008Assignee: Bayer MaterialScience AGInventors: Meike Niesten, Jack Reese, Joachim Simon, Gerhard Ruttmann
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Patent number: 7381764Abstract: The present invention relates to novel radiation-curing powder coating binders containing maleic and/or fumaric acid esters and one or more amorphous or partially crystalline resins containing at least one group that reacts with ethylenically unsaturated compounds under the action of actinic radiation to form a polymer. The binders have a glass transition temperature ranging from 30 to 90° C. The binders can be used as a constituent in coating compositions.Type: GrantFiled: October 6, 2004Date of Patent: June 3, 2008Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Jan Weikard, Peter Thometzek
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Patent number: 7381785Abstract: Process for preparing binders including reacting A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds containing groups capable of participating in polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and contain isocyanate-reactive groups, followed by C) reaction with one or more hydroxyl-containing compounds other than B), wherein at least one of these compounds has an OH functionality of?2, D) in the presence of one or more compounds containing phenoxide groups, as catalysts, and E) optionally auxiliaries and additives, where the reaction with compounds of component C) proceeds at least proportionally with the formation of allophanate groups and where and including binders containing allophanate groups and groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and optionally also contain NCO-reactive groups.Type: GrantFiled: March 14, 2005Date of Patent: June 3, 2008Assignee: Bayer MeterialScience AGInventors: Christophe Dètrembleur, Jan Weikard, Dorota Greszta-Franz, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock
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Patent number: 7371463Abstract: Coating compositions for producing sol-gel coatings that include: a) one or more alkoxysilyl-containing oxalamides of the general formula (II), where R? is hydrogen or an organic C1-C10 radical, R? radicals are organic, optionally oxygen-attached C1-C10 radicals, R is an oxygen-attached radical optionally containing one or more ether groups and having 1 to 30 carbon atoms and n is an integer between 0 and 2, b) optionally further crosslinkers, c) one or more catalysts and d) water. The sol-gel coatings are produced by a method that includes combining a silica sol and one or more alkoxysilyl-containing oxalamides. The sol-gel coatings obtained from the above-described coating compositions can be used to coat substrates.Type: GrantFiled: February 15, 2005Date of Patent: May 13, 2008Assignee: Bayer MaterialScience AGInventors: Burkhard Köhler, Harald Kraus, Joachim Simon
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Patent number: 7371807Abstract: The present invention is directed to blocked biuret group-containing polyisocyanate compositions, wherein the blocking agent is of the formula: wherein R1, R2, R3 and R4 may be the same or different and represent a moiety selected from the group consisting of hydrogen, C1-C6-alkyl and C3-C6-cycloalkyl, R5 represents a moiety selected from the group consisting of C1-C10-alkyl and C3-C10-cycloalkyl, and B is a group according to one of the following structural formulas wherein each occurrence of R6, R7, and R8 may be the same or different and represent a moiety selected from the group consisting of C1-C6-alkyl and C3-C6-cycloalkyl and R9 is a moiety selected from the group consisting of hydrogen, C1-C6-alkyl and C3-C6-cycloalkyl.Type: GrantFiled: October 21, 2004Date of Patent: May 13, 2008Assignee: Bayer MaterialScience LLCInventors: Lanny D. Venham, Kyli Martin, Richard R. Roesler, Myron W. Shaffer, Michael K. Jeffries
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Patent number: 7361723Abstract: A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.Type: GrantFiled: March 14, 2005Date of Patent: April 22, 2008Assignee: Bayer Materialscience AGInventors: Christophe Dètrembleur, Jan Weikard, Dorota Greszta-Franz, Frank Richter, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock
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Patent number: 7345133Abstract: A branched polycarbonate and processes for its preparation are disclosed. The polycarbonate contains structural units conforming to in which R1, R2, R3 and R4 mutually independently denote C1-C10 alkyl, R5, R6 and R7 mutually independently denote hydrogen or C1-C10 alkyl, or R1 and R2, and R3 and R4, with the carbon atom to which they are attached, form a C5-C10 cycloalkyl group, wherein the cycloalkyl group may be substituted.Type: GrantFiled: November 1, 2005Date of Patent: March 18, 2008Assignee: Bayer Materialscience AGInventors: Helmut-Werner Heuer, Rolf Wehrmann, Ulrich Blaschke, Michael Erkelenz
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Patent number: 7345110Abstract: A process for the continuous production of an aqueous polyurethane dispersion based on at least one aliphatic and/or aromatic polyisocyanate is described, which is characterised by the following steps: a) production of an aqueous pre-emulsion by mixing a polyurethane prepolymer containing hydrophilic and/or potentially hydrophilic groups with water in a mixing nozzle, wherein the polyurethane prepolymer is injected into the water; b) formation of an emulsion by homogenization of the pre-emulsion from step a) in a multi-step homogenizing nozzle. Paint films containing the aqueous polyurethane dispersion produced by the process can be used to coat substrates.Type: GrantFiled: April 5, 2005Date of Patent: March 18, 2008Assignee: Bayer MaterialScience AGInventors: Rolf Gertzmann, Bernd Klinksiek, Lars Obendorf, Christoph Irle
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Patent number: 7329717Abstract: A process for preparing polyisocyanate-modified polycarboxylic acids by conversion of anhydride-group-free polycarboxylic acids with isocyanate-functional compounds. The process includes reacting A) an anhydride-group-free polycarboxylic-acid component with B) an isocyanate-functional component having an (average) isocyanate functionality of at least 1.8, at an equivalent ratio of carboxylic acid groups to isocyanate groups of from 1.2:1 to 120:1. The polyisocyanate-modified polycarboxylic acids are solid below 40° C. and liquid above 130° C., and have an average carboxylic acid functionality of at least 1.8, a content of free carboxylic acid groups of from 4.0 wt. % to 80.0 wt. % and a content of amide groups of from 0.4 wt. % to 32.5 wt. %.Type: GrantFiled: June 21, 2004Date of Patent: February 12, 2008Assignee: Bayer MaterialScience AGInventors: Hans-Josef Laas, Christoph Gürtler, Reinhard Halpaap, Michael Grahl, Peter Thometzek, James Rawlins
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Patent number: 7323532Abstract: The present invention concerns a process for producing low-viscosity polyisocyanates or secondary products thereof, which carry activated, radiation-curable double bonds and can optionally also cure thermally, and low-viscosity polyisocyanate mixtures or secondary products thereof and their use in coating compounds.Type: GrantFiled: September 29, 2003Date of Patent: January 29, 2008Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Jan Weikard, Wolfgang Fischer
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Patent number: 7321428Abstract: A process photometer which includes an insulated and a non-insulated compartment. The insulated compartment is maintained at a relatively constant, elevated temperature. The radiation source, a rotatable filter wheel, a radiation detector, and a means for converting analog output to a digital signal are among the components within the insulated compartment. The non-insulated compartment houses a power supply.Type: GrantFiled: December 22, 2004Date of Patent: January 22, 2008Assignee: Bayer MaterialScience LLCInventors: Robert N. Hunt, Atul Khettry, Matthew R. Vila
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Patent number: 7316828Abstract: The present invention relates to a process for preparing an adhesive bond by i) applying an aqueous dispersion or solution containing a) at least one isocyanate-reactive polymer and b) at least one solid surface-deactivated polyisocyanate to a ii) substrate, iii) drying the aqueous dispersion or solution at a temperature from 20 to 95° C. to form an adhesive layer and iv) treating the adhesive layer with heat at a temperature greater than the temperature used to dry the aqueous dispersion or solution. The present invention also relates to a process for preparing a bond by combining at least one substrate with the adhesive bond of the present invention. Adhesive bonds of the present invention have a shear strength at least 10% greater than the shear strength of adhesive bonds containing a substrate having at least one adhesive layer based on an aqueous dispersion or solution composed of a) and b) dried at a temperature from 20 to 95° C.Type: GrantFiled: May 21, 2001Date of Patent: January 8, 2008Assignee: Bayer MaterialScience AGInventor: Thomas P. Abend
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Patent number: 7317112Abstract: A method of dimerizing isocyanates using sulphonamide anions as a dimerization catalyst for the isocyanates and also to a process for preparing oligomeric isocyanates using such catalysts.Type: GrantFiled: August 4, 2004Date of Patent: January 8, 2008Assignee: Bayer MaterialScience AGInventors: Jürgen Köcher, Hans-Josef Laas
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Patent number: 7314897Abstract: A thermoplastic molding composition comprising polycarbonate and at least one aromatic formal is disclosed. The formal conforms to The composition that is characterized by its reduced water uptake, is useful especially for the production of optical data carriers, such as compact discs.Type: GrantFiled: August 19, 2004Date of Patent: January 1, 2008Assignee: Bayer MaterialScience AGInventors: Helmut-Werner Heuer, Rolf Wehrmann, Friedrich-Karl Bruder
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Patent number: 7309753Abstract: A process for preparing a moisture-curable, polyether urethane containing terminal cyclic urea/reactive silane groups by reacting at an NCO:OH equivalent ratio of 1.5:1 to 2.5:1 a) a hydroxyl component containing i) a polyether containing two hydroxyl groups and one or more polyether segments, wherein the polyether segments have a number average molecular weight of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, and ii) a polyether containing one hydroxyl group and one or more polyether segments having a number average molecular weight of 1000 to 15,000, with b) an isocyanate component containing i) a compound containing two isocyanate groups, and ii) a compound containing one isocyanate group, and subsequently reacting this reaction product at an equivalent ratio of isocyanate groups to isocyanate-reactive groups of 0.8:1 to 1.Type: GrantFiled: December 5, 2003Date of Patent: December 18, 2007Assignee: Bayer MaterialScience LLCInventors: Richard R. Roesler, Derek L. Crawford
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Patent number: 7307140Abstract: The present invention relates to novel polyaspartimides, their method of production and the use of these polyaspartimides as reactive components for polyisocyanates in two-component polyurethane coating compositions. The polyaspartimides are prepared by reacting a polyether amine with a maleimide.Type: GrantFiled: November 16, 2004Date of Patent: December 11, 2007Assignee: Bayer MaterialScience LLCInventors: Karsten Danielmeier, Charles A. Gambino, Rolf Gertzmann, Richard R. Roesler, Terrell D. Wayt, Edward P. Squiller, Michele E. Honko, Karen Marie Henderson
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Patent number: 7294656Abstract: The present invention is directed to a non-aqueous composition curable by UV radiation broadly comprising a mixture of two UV curable urethane acrylates. The invention is also directed to a coating process using such composition. One of the urethane acrylates is the reaction product of an isocyanate and a specific OH functional lactone ester (meth)acrylate. The other urethane acrylate is the reaction product of an isocyanate and a specific hydroxy functional (meth)acrylate.Type: GrantFiled: February 9, 2005Date of Patent: November 13, 2007Assignee: Bayer MaterialScience LLCInventors: Hermann Bach, Charles A. Gambino, Michael J. Dvorchak, Michael K. Jeffries, Richard R. Roesler, Ramesh Subramanian