Abstract: The rubber mixtures according to the present invention comprising uncrosslinked butyl rubbers and nitrile-containing rubber gels as well as optionally, conventional additives and auxiliary substances, are suitable for the production of vulcanizates and molded rubber bodies of all kind having low gas permeability, low weight and acceptable mechanical properties, the mixtures exhibiting good processability.
Abstract: The present invention relates to transition metal organometallic compounds with an indenyl ligand attached in position 2 and fused in position 5,6, to a process for the production thereof and to the use thereof as catalysts for the (co)polymerization of olefinic and/or diolefinic monomers.
Type:
Grant
Filed:
January 23, 2001
Date of Patent:
September 2, 2003
Assignee:
Bayer Aktiengesellschaft
Inventors:
Sigurd Becke, Heinrich Lang, Thomas Weiss
Abstract: The invention relates to a process for the production of 2,2′-dithiazolyl disulfides by oxidation of 2-mercaptothiazoles with peroxidic compounds in an aqueous suspension in a specific pH range.
Abstract: The invention discloses an improved process for the production of cross-linked rubber particles. The cross-linking agents are added to the aqueous rubber dispersions and converted at relatively high temperatures without inertization of the reaction mix and without pressurizing of an inert gas.
The cross-linked rubber particles are suitable, for example, for the production of technical rubber products and for various tire components.
Abstract: The present invention relates to a catalyst system for the production of polyurethane comprising catalysts for polyurethane formation and sterically hindered carbodiimides, which system is capable of lessening the “fogging” problem in the production of polyurethane materials, without impairing in particular the aging properties of the polyurethane materials thus produced.
Abstract: Disclosed herein is a process for the production of hydrogenated nitrile rubber. The appearance of corrosion in the plant equipment in which hydrogenated nitrile rubber is produced is due to the unexpected presence of relatively large amounts of HCl, generated, surprisingly, by the hydro-dehalogenation of the monochlorobenzene solvent under the reaction conditions. The addition of a compatible weakly basic additive, such as Epoxidized Soy Bean Oil (ESBO), to the reaction mixture has alleviated this serious problem.
Abstract: The present invention concerns new organic silicon networks, their production process and use in silica-containing rubber compounds and vulcanizates manufactured from them.
Type:
Grant
Filed:
September 12, 2001
Date of Patent:
July 15, 2003
Assignee:
Rhein Chemie Rheinau GmbH
Inventors:
Rüdiger Herpich, Thomas Früh, Ludger Heiliger, Kurt Schilling
Abstract: The invention provides modifiers for the anionic polymerization of conjugated dienes or of conjugated dienes with vinylaromatic compounds, wherein the modifiers are specific aminoethers.
Type:
Grant
Filed:
November 6, 2001
Date of Patent:
June 24, 2003
Assignee:
Bayer Aktiengesellschaft
Inventors:
Michael Grün, Thomas Knauf, Wilfried Braubach
Abstract: The invention provides rubber mixtures of at least one double bond-containing rubber, rubber gels and additives of inorganic peroxides and also optionally further fillers and rubber auxiliary substances.
Rubber mixtures according to the present invention are characterized in the uncrosslinked state by good processability (compound viscosity ML 1+4/100° C.<60 ME) and in the vulcanized state by improved mechanical properties in particular with regard to the product of the modulus at 100% extension and the elongation at break (S100×D) and also by improved tensile strengths. In addition, vulcanizates prepared from rubber mixtures according to the present invention have a relatively low density, which has an advantageous effect on the weight of the rubber molded items prepared from the rubber mixtures.
The vulcanizates are suitable for producing industrial rubber articles and for tire components.
Abstract: The present invention relates to a catalyst system for gas phase polymerization of conjugated dienes, consisting of a rare earth compound, an aluminum organic compound, a further Lewis acid, optionally a conjugated diene, an inert inorganic or organic support and a co-catalyst applied to an inorganic support, in order to improve the flowability of rubber thus produced.
Type:
Grant
Filed:
July 13, 2000
Date of Patent:
June 10, 2003
Assignee:
Bayer Aktiengesellschaft
Inventors:
Michael Dauben, Jürgen Schneider, Gerd Sylvester, Nobert Steinhauser
Abstract: The invention relates to a process for the preparation of polybutadienes with a reduced solution viscosity/Mooney viscosity ratio by using polydienyl compounds, the polybutadienes which can be prepared in this process, the use of the polybutadienes according to the present invention for the preparation of rubber mixtures, the use of the rubber mixtures for the production of all types of shaped articles, and the compound dimethyldi-2,4-pentadienyl-(E,E)-silane as an intermediate product.
Abstract: This invention relates to a mixture containing one or more olefin rubbers and one or more nitrile rubbers, to a process for the production thereof, to a vulcanizable mixture and to a process for the production thereof as well as to moldings of all kinds producible from the mixtures.
Abstract: The present invention relates to a novel dendrimic compounds, to a method for the production thereof and to the use thereof as catalysts for the production of polymers, in particular to the use thereof as co-catalysts for metallocenes for polymerizing unsaturated compounds.
Type:
Grant
Filed:
September 22, 2000
Date of Patent:
May 27, 2003
Assignee:
Bayer Aktiengesellschaft
Inventors:
Sigurd Becke, Uwe Denninger, Michael Mager, Heike Windisch
Abstract: Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on monocyclopentadienyl compounds of vanadium and alumoxanes in the presence of aromatic vinyl compounds as the solvent at temperatures of −30 C. to +80 C. By means of the process according to the invention, it is possible to straightforwardly produce solutions of polydiolefins, such as polybutadiene, having 1,2 unit contents of 10 to 30% in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.
Type:
Grant
Filed:
January 11, 2001
Date of Patent:
May 20, 2003
Assignee:
Bayer Atkiengesellschaft
Inventors:
Heike Windisch, Werner Obrecht, Gisbert Michels, Norbert Steinhauser
Abstract: Rigid polyurethane or polyisocyanurate foams are produced by reacting an organic polyisocyanate with an amine-based polyether polyol in the presence of a catalyst, a hydrogen-containing fluorocarbon, water and carbon dioxide.
Abstract: The present invention provides a novel process for the preparation of isoolefin copolymers in the presence of zirconium halides or hafnium halides or mixtures thereof and organic nitro compounds, especially for the preparation of butyl rubbers, as well as isoolefin copolymers composed of isobutene, isoprene and, optionally, further monomers.
Abstract: Reaction mixtures which form polyurethane foamed material, with production conditions which are varied during production, e.g. variation of the proportion of foaming agent, variation of the ratio of reaction components, variation of the throughput, or fine adjustment, can be produced by employing an improved apparatus which comprises a depressurisation element (creamer) (10), wherein a perforated plate or sieve plate constructed as a first throttle plate (24), and a second perforated or sieve plate, which is constructed as a throttle plate (26, 27, 28) and which is disposed downstream thereof, are disposed in the creamer (10), wherein the spacing a between these two throttle plates (24, 26) can be varied during operation in accordance with the variable production conditions, and wherein a calming element (29) is disposed after the second throttle plate (26) in the direction of flow.
Abstract: The present invention relates to halogenated, low-gel, high molecular weight isoolefin multiolefin copolymers, in particular to halogenated, low-gel, high molecular weight butyl rubbers, and halogenated, low-gel, high molecular weight isoolefin multiolefin copolymers synthesized from isobutene, isoprene and optionally further monomers, with a multiolefin content of greater than 2.5 mol %, a molecular weight Mw of greater than 240 kg/mol and a gel content of less than 1.2 wt. % and a process for their preparation.
Type:
Grant
Filed:
December 10, 2001
Date of Patent:
April 8, 2003
Assignee:
Bayer Aktiengesellschaft
Inventors:
Gerhard Langstein, Martin Bohnenpoll, Anthony Sumner, Marc Verhelst
Abstract: This invention relates to a rubber mixture containing a nitrile rubber, a metal salt of an acrylate, a liquid acrylate and optionally other additives, a process for its preparation, and use for all types of molded articles, in particular roller coatings.
Abstract: A process for treating particles comprising the steps of: (i) contacting the particles with a compound of Formula (I) wherein at least one of R1, R2 and R3 is hydroxyl or a hydrolysable group; and (ii) contacting the particles with a compound of Formula (II) wherein X is an anion and R4 is either: a divalent group —(CyH2y)—, branched jor unbranched, wherein y is a whole number from 1 to 40, or a C6-C40 aromatic group, and t is either 0 or 1.