Abstract: A process for preparing homogeneous and stable heavy-duty liquid detergent compositions which comprises forming a blend of a solution of a builder salt and an emulsifying agent at an elevated temperature above about 60.degree. C. and cooling said blend to a lower temperature below about 45.degree. C., the amount of said builder salt dissolved in said solution at the elevated temperature being greater than the solubility of said salt in water at the lower temperature, the nature and amount of the emulsifying agent being such as to maintain the builder salt in stable dispersion in said blend at the lower temperature. The finished composition contains a water-soluble detergent surface active agent.
Abstract: Novel sulfosuccinates of 2-hydroxy alkyl tertiary alcohol amines having the structural formula: ##STR1## wherein R.sub.1 is a monovalent aliphatic hydrocarbon radical of 8 to 24, preferably 10 to 20 carbon atoms; R.sub.2 is an alkyl or alkylol (hydroxy substituted alkyl) radical containing 1 to 6 carbon atoms, and R.sub.3 is an alkylol radical containing 1 to 6 carbon atoms, and salts thereof. The reaction mixture consists of sulfonated mono-, di-, and/or tri-esters, depending on the number of reactive hydroxyl groups in the alcoholamine and the amount of dicarboxylic acid utilized. These novel esters and salts thereof uniquely possess both detergency and softening properties.
Abstract: An apparatus for conditioning fibrous materials includes an automatic laundry dryer, usually of the substantially horizontally rotating tumbling drum type, having a substantially vertical door which closes the drum, which door has fastened to the inside thereof a conditioning article from which conditioning agent is removable on contact with the tumbling fibrous materials and becomes deposited on them. Also disclosed is a method of conditioning fibrous materials in such an apparatus.
Abstract: Novel fabric conditioning compounds are formed by reacting a higher alkyl-1, 2-epoxide with a lower alkanediamine. The compounds may be incorporated into a laundry product and used in the wash cycle or may be applied in either the wash cycle or the rinse cycle.
Abstract: A non-yellowing fabric softening composition having improved whitening properties comprising a cationic softener, preferably a quaternary ammonium softener, and a perphthalic acid in the weight ratio of 4:1 to 1:1 of cationic:perphthalic acid.
Abstract: A copolymer adapted be used for applying a non-permanent soil-release finish to fabrics comprising a copolymer of acrylic acid and 1,1 -- dihydroperfluorooctyl methacrylate. A ratio of one monomer to the other is respectively about 21:1 to 5:4 by weight. The composition is particularly useful for applying a soil-release finish in the rinse cycle of a home laundry process.
Abstract: Novel pyridazine-2-oxide derivatives inclusive of 3-mercaptopyridazine-2-oxides, disulfides thereof, metal salts thereof, and 3-(2-oxopyridazinyl)isothiouronium compounds having particular utility as antimicrobial agents per se and in skin cleansing detergent compositions, shampoos, hair dressing and the like.
Abstract: An improved article for conditioning fabrics includes at least one fabric conditioning compound, such as a softening agent, and a reinforcing, strengthening or extending material. The fabric conditioning compound and the article comprising it are usually of a waxy nature and are abradable or otherwise transferable to damp, warm fabrics by repeated contacts therewith experienced during tumbling effected in a drying zone, as of an automatic laundry dryer, through which hot drying air normally circulates. When such a softening article is rubbed against fabrics with which it comes in contact in the heat of the drying zone, softener is rubbed off onto the fabrics to be conditioned, after which the fabrics and laundry containing them are dried. The reinforcing or strengthening material is also dried at that time and is either removed from the fabrics by exiting drying air or is desirably held onto the fabrics that were treated, in conjunction with the softening agent.
Type:
Grant
Filed:
October 18, 1973
Date of Patent:
August 9, 1977
Assignee:
Colgate-Palmolive Company
Inventors:
Russell Edward Compa, Marvin Liebowitz, Ralph Paul Messina
Abstract: Detergent compositions using only alkali metal citrate and carbonate builder salts are disclosed. The detergent compositions disclosed have a lower alkalinity than phosphate-free detergents employing high concentrations of silicates.
Abstract: A non-staining aerosol antiperspirant comprising a suspension of an aluminum antiperspirant powder in an anhydrous system containing as the stain preventative, an effective amount of an electrolyte selected from the class consisting of alkali metal borates, polyphosphates, metaphosphates, citrates, silicates and tri-sodium nitrilotriacetate.
Abstract: An improved aerosol spray starch formulation is prepared by combining a starch component, a polyhydric material, a nonionic surfactant and a mixture of boric acid and borax in an aqueous medium together with a normally gaseous liquefied propellant. The starch formulation provides after pressing an excellent starching effect, that is, stiffness without roughness, without flaking or aerosol clogging.
Abstract: An article for conditioning fibrous materials includes a dispensing container of liquid fabric conditioning composition which has an opening in the wall thereof through which the conditioning composition is gradually dispensed into contact with fibrous materials to be conditioned. The conditioning composition is usually an aqueous solution of a surface active synthetic organic anionic, nonionic or cationic fabric conditioning agent, which is a softening agent that usually also makes the treated fabrics non-static. The container of conditioning composition usually includes a plurality of small dispensing openings therein and the viscosity of the solution of conditioning agent may be such that dispensing is preventable until the container comes into contact with materials to be treated or is subjected to shocks, as in tumbling of the container in contact with laundry being dried in an automatic laundry dryer.
Abstract: Wax polishing compositions in the form of a double emulsion wherein the continuous phase comprises organic solvent, organopolysiloxane and water-in-oil emulsifier and the discontinuous phase comprises aqueous particles having dispersed particles of wax therein. Compositions are prepared by adding at room temperature an aqueous media containing emulsified wax to a solvent solution containing organopolysiloxane and water-in-oil emulsifier, also at room temperature.
Type:
Grant
Filed:
September 27, 1974
Date of Patent:
March 22, 1977
Assignee:
Colgate-Palmolive Company
Inventors:
Marvin Liebowitz, Eugene Howard Brandli
Abstract: A biodegradable heavy duty dry detergent composition including a higher fatty alkyl polyethoxy sulfate and a nonphosphate builder, the composition exhibiting outstanding hard water resistance. A preferred composition includes a compound of the formula RO(C.sub.2 H.sub.4 O).sub.3 SO.sub.3 Na wherein R is a mixed fatty alkyl of from 12-15 carbon atoms and a non-phosphate builder selected from carbonates, silicates, citrates, oxydiacetates, polycarboxylates, etc.
Abstract: A 45 r.p.m. type flat spindle adapter is provided for use with a small diameter record changer spindle of the type having means for laterally shifting a record mounted thereon. The adapter has no moving parts and is provided with means to secure the adapter against rotation relative to the spindle so that the line of movement of the lateral shifting means of the spindle and the line defining the longer cross-sectional dimension of the adapter form an angle of about 5.degree. to 45.degree..This invention relates to the automatic record changer art, and more particularly, to new, useful and outstanding improvements in separate and detachable adapter for those record changers and phonographs which are manufactured with the so-called standard, small diameter spindles adapted to receive records which are provided with small holes of about 0.281 inch in diameter.
Abstract: There is disclosed antimicrobial compositions based upon the combination of an antimicrobially effective poly (quaternary ammonium) compound and an antimicrobially effective simple anionic component. There is also disclosed methods of making the same and products made therefrom.
Abstract: Skin treatment with a composition containing an unsymmetrical ether of the formula R.sub.1 --o--R.sub.2 wherein R.sub.1 is alkyl or alkenyl of about 8 to 20 carbon atoms and R.sub.2 is C.sub.1-3 alkyl or C.sub.2-3 alkenyl.
Abstract: A heavy duty built synthetic organic detergent powder is made without the need for phosphates or carbonates in the formulation thereof by preparing a base product, such as by spray drying an aqueous mix of an anionic synthetic organic detergent and alkali metal silicate, for example, a crutcher mix of higher linear alkyl benzene sulfonate, sodium silicate, sodium sulfate and water, in certain proportions, spraying a nonionic detergent onto the dry base and blending with it a powdered anti-redeposition agent. The product made is a free-flowing detergent of desired density and particle size and the process is readily effected in a tumbling drum or twin shell blender without producing excessive lumping or tackiness.
Type:
Grant
Filed:
May 13, 1974
Date of Patent:
February 1, 1977
Assignee:
Colgate-Palmolive Company
Inventors:
Edward J. Kenney, Frank R. Smith, Jr., Walter A. DiSalvo
Abstract: In a process for removing stains from fabrics by washing in an aqueous medium containing a peroxygen compound and an acylamide activator, extremely small amounts of the activator, e.g., about 5 to 50 ppm., are effective if the medium contains about 100 to 300 ppm of trisodium nitrilotriacetate or ethylene diamine tetraacetic acid sodium salt and an amount of the peroxygen compound representing about 3 to 80 ppm of active oxygen and substantial excess of active oxygen over that stoichiometrically equivalent to the amount of activator.
Abstract: The odor of technical N-alkyl (C.sub.12 -C.sub.22)-1,3-propylene diamines may be improved by treating the diamine with maleic anhydride. The addition of small amounts of urea and/or sugar to the treated N-alkyl-1,3-propylene diamine further improves the fabric softening properties of the diamines and reduces fabric discoloration.