Abstract: An excellent lubricant and surface conditioner layer on formed metal surfaces, particularly aluminum cans that have been previously provided with a chromium oxide conversion coating, can be formed by contacting the cans with an aqueous lubricant and surface conditioner forming composition that contains at least one oxa acid or methyl ester thereof corresponding to general formula (I):CH.sub.3 (CH.sub.2).sub.a O(CH.sub.2 CH.sub.2 O).sub.x CH.sub.2 C(O)OR(I),where each of n and x, which may be the same or different, is a positive integer and R represents H or CH.sub.3 and at least 20 weight % of the total content corresponding to general formula (I) does so when x is at least 8, and then drying the thus-treated cans.

Abstract: The uniformity of gloss of a dried autodeposited resin film on a metal surface can be increased by rinsing the wet autodeposited film initially formed with an aqueous modifying rinse having a pH from 6 to 11 and comprising from 0.2 to 10.0 g/L in total of polymers of carboxylic acid monomers having an ethylenic double bond and salts thereof.

Abstract: Substantially improved hydrophilicity can be provided to a metal substrate, particularly an aluminum alloy of the type used for heat exchanger fins, that has been previously provided with a conventional chromium oxide conversion coating, by drying into place on the surface of the chromium oxide conversion coating an aqueous liquid hydrophilicizing treatment composition containing at least one of: (i) aproduct or products of reaction between dissolved phosphoric acid and at least one of elemental metal, metal oxides, and metal hydroxides in contact therewith; (ii) tungstate ions; and (iii) at least one of sulfate or molybdate ions together with polyethyleneimine. Most preferably, a solution formed by dissolving MgO in aqueous H.sub.3 PO.sub.4 in the proper stoichiometric amount to form an aqueous solution of Mg(H.sub.2 PO.sub.4).sub.2 with a pH of 4.5-5.5 is used for the hydrophilicizing treatment.

Abstract: Concentrates containing (a) an hydroxylamine sulfate accelerator, and (b) zinc, nickel, manganese, and phosphate ions are formulated into aqueous coating solutions for treating metal surfaces, such as ferrous, zinc, and aluminum surfaces. In the process of using this solution, hydroxylamine ions become depleted or reduced in concentration in the applied solution. A replenishing solution is added for reusing the solution until the replenished coating solution reaches a sulfate level of no more than 14 g/l.

Abstract: Aluminum alloys that are susceptible to damage by High Temperature Oxidation during solution heat treatment are protected against such damage by a coating containing sodium fluoroborate and/or other fluorine-containing-gas-generating material. The coating can be one suitable for lubrication during cold working of the substrate and can remain in place after the cold working to protect the substrate during subsequent heat treatment.

Abstract: A "highlighter" liquid for detecting cosmetic defects in non-metallic surfaces, particularly those intended for high quality automotive finishes comprises organic substances each molecule of which contains at least one continuosly chemically bonded chain or ring of atoms in which there are at least two carbon atoms and at least two oxygen, nitrogen, sulfur, and phosphorus heteroatoms, the carbon atoms and heteroatoms being arranged in such an order along the chain or ring that (i) each heteroatom is bonded to at least one carbon atom and (ii) the chain does not include more than three consecutive continuosly chemically bonded carbon atoms. Particularly suitable materials include glycerin, propylene glycol, low molecular weight glycol condensation polymers, and monoethers of these glycol condensation polymers. Water is also usually present in the highlighter liquid, which has a long open time and does not damage the substrate even if left in place for a day or more.

Abstract: A chromium and ferricyanide free aqueous cleaner/deoxidizer for aluminum and titanium and their alloys contains strong acid, fluoride ions, aryl quaternary ammonium ions, and di-anionic functional substituted compounds containing at least two aryl groups per molecule. Excellent cleaning and deoxidizing with substantially no etching is achieved.

Abstract: An aqueous liquid composition containing dihydrogen phosphate salt, surfactant(s), and a dual coordinate bonding agent for iron cleans soiled metal surfaces without damaging any plastic parts that come into contact with the composition, supporting the growth of bacteria that cause unpleasant odors, or obscuring the transparency of any transparent window that it contacts. The composition is particularly useful for cleaning unpainted aluminum sided rail transport cars that have polycarbonate housings insulating electrical contact points that provide motive electric power to the cars; many conventional aqueous alkaline and acid cleaners promote stress cracking of polycarbonate plastics.

Abstract: A coating apparatus is disclosed for applying a coating material on one or more zones of a substrate material. In one embodiment, the coating applicators have fluid-wicking strips that apply the coatings directly to the substrate, while in another embodiment, the fluid-wicking strips indirectly apply the coatings to the substrate via feed rolls. Metering mechanisms supply predetermined amounts of coating material to the fluid-wicking strips. Each coating applicator has a housing with a recess for receiving one the fluid-wicking strips therein. One of the fluid-wicking strips is mounted in each housing which has a plurality of transversely spaced passageways. Each passageway of each applicator housing is fluidly coupled to its own separate air actuated metering mechanism which dispenses coating material to the portion of the fluid-wicking strip adjacent thereto. A desired quantity of coating material is simultaneously delivered via the metering mechanisms to each of the applicator housings.

Abstract: This invention relates to a process comprising the steps of contacting a metal surface with an aqueous composition comprising water and specific amounts by weight of phosphate ions, condensed phosphate ions and water soluble polymer molecules of a specific general formula, separating the contacted metal surface from the aqueous composition, rinsing with water and heating.

Abstract: A process for improving the adherence of paint applied after thin-film anodization is characterized in that the anodized metal surfaces are brought into contact with an aqueous solution containing one or more of the following components: (a) 200 to 2000 ppm of a homopolymer or copolymer of acrylic acid, methacrylic acid, and/or their esters; (b) 200 to 3000 ppm of a poly(vinyl phenol) compound in which at part of the phenol rings carry an alkylamino substituent; (c) 200 to 3000 ppm of hexafluorotitanic acid, hexafluorozirconic acid, and/or their anions.

Abstract: Defects in an initial protective coating, particularly a conversion coating, on a metal substrate can be touched up so as to at least equal the original coating in corrosion protection by use of a dry-in-place aqueous acidic liquid comprising:(A) fluorometallate anions;(B) divalent or tetravalent cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, copper, zirconium, iron, and strontium;(C) a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and(D) a component of water-soluble and/or -dispersible organic polymers and/or polymer-forming resins.

Abstract: An aqueous liquid chromate free composition for forming a protective coating on metals, particularly aluminum, is made by reacting cobalt(II) cations, carboxylate anions, at least one other type of coordinate complexing agent for cobalt(III) cations, and an oxidizing agent in an aqueous solution in which the molar ratio of carboxylate anions to cobalt(II) cations is from 0.10 to 6.8 and the aqueous solution contains no more than 1% of each of ammonia, ammonium ions, and nitrite ions.

Abstract: The use of selected cation exchange resins to remove dissolved multivalent cations ions such as iron, zinc, and chromium from used autodeposition compositions permits reuse of the autodeposition compositions without the need for added surfactant and without developing any undesirable graininess or other texture in the coatings formed. Iminodiacetate cation exchange resins are very effective for removing iron ions when they are the only multivalent ions to be removed, and can be efficiently regenerated with 0.5 to 4% by weight aqueous hydrofluoric acid. By proper choice of other cation exchange resins and operating conditions, zinc can be selectively extracted from autodeposition baths containing both iron and zinc, and either iron or zinc can be selectively displaced from the loaded ion exchange resin.

Abstract: Residue that accumulates on metallic molding surfaces during repeated molding of plastics such as PVC can be removed by cleaning with an aqueous solution of a glycol or oligo-glycol monoether, an amine, and a chelating agent. The cleaner is sufficiently effective to replace mechanical blasting that was previously required.

Abstract: A process for sealing anodized metal surfaces is characterized by bringing the anodized metal into contact with an aqueous solution at a temperature from 75.degree. C. to the boiling point of the solution for a time equal to from 0.5 to 2 minutes per micrometer of anodized layer thickness. The solution contains: a) from 0.0001 to 5 g/l of one or more alkali metal and/or alkaline earth metal ions and b) from 0.0005 to 0.5 g/l of one or more organic acids selected from: polycarboxylic acids with from 3 to 6 carboxyl groups; phosphonic acids; and/or polyphosphinocarboxylic acids, the solution containing a greater amount of metal ions of group a) than is needed to insure complete neutralization of the acids of group b).

Abstract: Aqueous acid treatment solution for the treatment of beverage cans, in particular of aluminum, for producing a corrosion-protective, friction-reducing coating which improves the ability to be enameled, which comprises 0.14 to 2.25 mmol/l of an alkylamine oxide or an alkylammonium salt with an alkyl radical having 8 to 22 C atoms, 0.25-1.5 mmol/l of hydroxycarboxylic acids having 4-7 C atoms, complex fluorides and mineral acids, and preferably tannin.

Abstract: A combination of (A) a nitrogen containing water soluble polymer, (B) a water insoluble film forming polymer, and (C) gas filled, polymer walled microballoons provides a superior thermally releasable coating that (i) can be conveniently and reliably coated from a water based solution and dispersion onto surfaces to be protected against painting, (ii) is reliably stable at ambient temperatures, (iii) even after being coated with many times its own thickness of accumulated paint particles, rapidly disintegrates, along with the accumulated paint coating formed on it, upon contact with hot water, into particles of a size that readily escapes from standard paint booth grate structures, (iv) detackifies any paint particles that escape during distintegration of the combined thermally releasable coating and paint residues accumulated thereon, and (v) disintegrates into particles that float on water, so that they can be readily removed from the grates by immersing the latter in hot water, allowing a few minutes for th

Abstract: Powdered, paste, or liquid media for cleaning and/or degreasing hard surfaces, especially surfaces of organic polymers (PVC) contain active ingredients of amino acids, carboxylic acids, and nonionic surfactants, possibly supplemented by action-reinforcing auxiliaries and/or demulsifying additives. Processes using these media are also claimed.

Abstract: A zinc phosphate conversion coating which is accelerated only with nitrogen free organic peroxides is low-polluting and able to form uniform, fine, and dense conversion coatings that exhibit an excellent paint adherence when thin and excellent lubricity/lubricant carrier quality when thick.