Abstract: The present invention relates to novel compounds of the naphthopyran type which have a perfluoroalkyl group (X) in position 5. These compounds are of formula (I) given below: These compounds (I) possess interesting photochromic properties. The invention also relates to their preparation, their applications as photochromes as well as the compositions and matrices containing them.

Abstract: The object of the present invention is novel photochromic [indole]naphthopyran compounds and their methods of preparation.

Abstract: The invention relates to novel naphthopyran-type compounds having a lactam-type 6-membered ring annelated in position C5-C6. These compounds have the formula (I) given below: These compounds (I) have interesting photochromic properties. The invention also relates to their preparation, to their applications as photochromes, as well as to the compositions and (co)polymer matrices containing them.

Abstract: A method of replicating a nanoscale pattern which comprises forming the pattern on the outer surface of a cylindrical roller, providing a surface upon which the pattern is to be replicated, and transferring the nanoscale pattern from the cylindrical roller onto the surface to provide at least one replication of the pattern on that surface. The roller is adapted to carry the pattern on its outer surface and transfer the pattern to a substrate. The ultimate product may be a grating polarizer.

Abstract: The objects of the present invention are: a self-light-stabilized photochromic thermoplastic or thermoreticulated polymer carrying non-cyclic tertiary amide-functionalized pendant groups; its preparation method; photochromic articles constituted, wholly or in part of such a polymer. Said polymer is obtained advantageously by radical co-polymerization of a composition containing an effective amount of at least one monomer of the formula: in which: R1 is hydrogen or a methyl group; n is 2 or 3; R2 and R3 are identical or different and represent independently a methyl or ethyl group; and are advantageously identical; said monomer providing said photostabilizing non-cyclic tertiary amine-functionalized pendant groups.

Abstract: The object of the present invention is a photochromic composition incorporating: +2-(p-dimethylaminophenyl)2-(p-methoxyphenyl)-5-methyl-7,9-dimethoxy-[2H]-naphtho[1,2-b]pyran (compound (I)), and +3-(p-methoxyphenyl)-3-phenyl-6-morpholino-3H-naphtho-[2,1-b]pyran (compound (II)). The invention also relates to said compounds (I) and (II) per se, (co)polymer matrices containing same, advantageously in a mixture, as well as finished products constituted wholly or in part of such matrices and/or containing one and/or the other of said compounds (I) and (II).

Abstract: This invention is directed to the preparation of alloy articles consisting essentially of 65 wt. % or more glass and high temperature organic thermoplastic or thermosetting polymers having working temperatures which are compatible with that of the glass and/or the precursor glass for the glass-ceramic. The glass and polymer are combined at the working temperature to form an intimate mixture; i.e., the glass and polymer are in a sufficiently fluid state to be blended together to yield a body exhibiting an essentially uniform, fine-grained microstructure wherein, desirably, there is at least partial miscibility and/or a reaction between the glass and the polymer to promote adhesion and bonding therebetween. A body is shaped from the mixture and cooled to room temperature.

Abstract: The invention relates to photochromic transparent organic materials particularly useful for the production of photochromic organic ophthalmic lenses. The material includes an optical-quality polymer matrix and at least one coloring agent giving photochromic properties to the matrix. The coloring agent is chosen from the group of the spirooxazins the spiropyrans, and the chromenes. The polymer of the matrix is chosen from the group of homopolymers of ethyoxylated bisphenol A dimethacrylate with formula I: in which R is H or CH3, and m and n independently represent 1 or 2, and of the copolymers of this dimethacrylate containing at most 30 wt % of an aromatic monomer with vinyl, acrylic or methacrylic functionality.

Abstract: The main aim of the present invention is a method of preparing photochromic or non-photochromic organic pieces of optical quality and especially organic lenses, by radical polymerisation of a mixture of radically polymerisable monomers, characterised in that it comprises: a) adjusting, by pre-polymerisation, the viscosity of said mixture, to a value between 0.4 and 2 Pa.s; b) pouring said pre-polymerised mixture into a mould; c) photogelifying, in said mould, said pre-polymerised mixture until its gel point; d) completing the polymerisation of said pre-polymerised and gelified mixture in said mould, by heat treatment; adding effective amounts of at least one thermal catalyst and of at least one photoinitiator intervening in said mixture of monomers for the implementation of said pre-polymerisation, photogelification and polymerisation; said photoinitiator(s) intervening in an amount less than or equal to 0.009 parts by weight per 100 parts by weight of said mixture of monomers.

Abstract: The invention relates to transparent, photochromic or nonphotochromic organic materials, which have a refractive index higher than 1.55 and which are free of optical distortions, consisting of a copolymer of: (a) 50-90 wt. % of at least one monomer represented by the formula, in which R═H or CH3, and m and n are independently 1 or 2; (b) 10-30 wt. % of at least one aromatic monovinyl monomer represented by formula, R1═H or CH3; and (c) 1-20 wt. % of at least one (meth)acrylic monomer represented by formula, CH2=C(R)—COOR′ in which R═H or CH3 R′ is a straight-chain or branched C4 to C16 alkyl radical, an alkylaryl radical, or a polyoxyethoxylated group with formula —(CH2—CH2O)nR″ in which n=1 to 10 and R″═CH3 or C2H5. Optionally, the photochromic material may contain up to 10 wt. % of at least one photochromic coloring agent to impart desired photochromic properties.

Abstract: The present invention relates to novel naphthopyrans having a cyclic group annelated in position 6,7. These naphthopyrans have formula (I) given below: These compounds (I) have advantageous photochromic properties. The invention also covers a method of preparing these naphthopyrans, as well as their applications as photochromes and compositions and (co)polymers matrices comprising them.

Abstract: Disclosed are naphthopyran-type compounds having a pyrrole group annelated in position 5.6, as well as compositions and particularly (co)polymer matrices containing them. These compounds, compositions, and matrices have photochromic properties. These [pyrrole]naphthopyran compounds have the general formula: Articles containing these photochromic compounds, such as ophthalmic and/or solar glasses, lenses, glazing, devices, and the like, are also disclosed.

Abstract: Disclosed are photochromic contact lenses which include transparent organic materials having an index of refraction of more than 1.55. The material is prepared by radical polymerization of a polymerizable composition which includes (a) 80-95 wt % of at least one monomer represented by the general formula (I): where R is H or CH3 and m and n are independently 1 or 2; (b) 5-20 wt % of at least one aromatic monovinyl monomer; (c) an effective amount of at least one dye that imparts photochromic properties to the materials, selected from the groups of spiroxazines, spiropyrans and chromenes; (d) an effective quantity of a chain transfer agent; and (e) an effective quantity of a radical polymerization initiator. The chain transfer agent is a linear alkanethiol, and the radical polymerization initiator is a diazo compound.

Abstract: The present invention has for subjects, novel benzopyran derivatives, substituted in position 2 with an adamantyl group as well as the compositions and (co)polymer matrices containing such derivatives. Said derivatives possess interesting photochromic properties.

Abstract: The invention relates to photochromic compounds of general formula (I), in which: R3 and R5 are C1-C6 alkoxy groups and the rest of the R groups represent various substituents.

Abstract: The invention relates to photochromic transparent organic materials presenting an index of refraction of more than 1.55, which are free of optical distortions and are prepared by radical polymerization of a polymerizable composition comprising:a) 80-95 wt % of at least one monomer represented by the general formula (I): ##STR1## where R=H or CH.sub.3, and m and n are independently 1 or 2; b) 5-20 wt % of at least one aromatic monovinyl monomer represented by the general formula (II): ##STR2## c) an effective quantity of at least one dye that imparts photochromic properties to the material, selected from the groups of spiroxazines, spiropyrans and chromenes;d) an effective quantity of a chain transfer agent; ande) an effective quantity of a radical polymerization initiator, characterized in that the chain transfer agent is a linear alkanethiol and the radical polymerization initiator is a diazo compound.

Abstract: The invention concerns photochromic compounds having a formula (I), where R.sup.1 is a polycyclo group formed by at least one alicyclic group linked to, bridged or condensed, with at least one other aliphatic or aromatic ring.

Abstract: The present invention has for subjects novel compounds of the [benzofuran]naphthopyran type as well as the compositions and (co)polymer matrices containing them. Said compounds possess interesting photochromic properties.

Abstract: The invention concerns photochromic compounds with the following Formula: ##STR1## in which: R.sup.1 is a asymmetric aliphatic monocyclic group with the Formula, ##STR2## where l=1-12, and R.sup.9 is H or an alkyl, alkoxy, dialkylamino, alkyl ester or CN group with the condition that at least one of the R.sup.9 groups is not H,R.sup.2 -R.sup.7 can have a variety of meanings, A represents a (hetero)aromatic ring which can be substituted and n is a whole number.Application to the production of photochromic articles made of organic polymer, notably lenses.

Abstract: The invention relates to photochromic transparent organic materials particularly useful for the production of photochromic organic ophthalmic lenses. The material includes an optical-quality polymer matrix and at least one coloring agent giving photochromic properties to the matrix. The coloring agent is chosen from the group of the spirooxazins the spiropyrans, and the chromenes. The polymer of the matrix is chosen from the group of homopolymers of ethyoxylated bisphenol A dimethacrylate with formula I: ##STR1## in which R is H or CH.sub.3, and m and n independently represent 1 or 2, and of the copolymers of this dimethacrylate containing at most 30 wt % of an aromatic monomer with vinyl, acrylic or methacrylic functionality.