Abstract: An ABS polymer comprising (A) a graft copolymer formed by graft polymerizing styrene and acrylonitrile monomers onto an initially ungrafted, low gel diene rubber and (B) a copolymer of said grafted monomers in which said graft copolymer is dispersed; said diene rubber comprising 3 to 25% by weight of such polymer with the polymerized acrylonitrile content thereof being 27 to 40% by weight.

Abstract: A process for polymerizing .epsilon.-caprolactam to form a nylon-6 block copolymer in which a reactant stream containing .epsilon.-caprolactam, and a lactam polymerization initiator is brought into polymerizing admixture with a reactant stream containing .epsilon.-caprolactam and a lactam magnesium halide, wherein sufficient 2-oxo-1-pyrrolidinyl compound is added to the admixture either as 2-pyrrolidinone, 2-oxo-pyrrolidinyl magnesium halide or 2-oxo-1-pyrrolidinyl capped initiator compound to enhance the rate of polymerization of the .epsilon.-caprolactam. The lactam polymerization initiator is a telechelic oligomer or polymer containing a backbone which provides elastomeric segments in the nylon-6 block copolymer, and attached to the backbone are activated initiator groups which initiate the polymerization of .epsilon.-caprolactam in the presence of the lactam magnesium halide.

Abstract: A process for polymerizing .epsilon.-caprolactam to form a nylon-6 polymer in which a reactant stream containing .epsilon.-caprolactam and a lactam polymerization initiator is brought into polymerizing admixture with a reactant stream containing .epsilon.-caprolactam and a lactam magnesium halide, wherein sufficient 2-oxo-1-pyrrolidinyl compound is added to the admixture either as 2-pyrrolidinone, 2-oxo-pyrrolidinyl magnesium halide or 2-oxo-1-pyrrolidinyl capped initiator compound to enhance the rate of polymerization of the .epsilon.-caprolactam.

Abstract: Compositions for the preparation of block copolylactams comprising lactam, lactam polymerization initiator and an effective amount of a viscosity enhancing compound selected from the group consisting of the lactamates and .omega.-amino acid salts of barium, calcium and strontium.

Abstract: A composition containing acid halide functional materials, which are useful in the preparation of nylon block polymers, selected from the group consisting of: ##STR1## wherein, X is a halogen;a is an integer equal to 1, 2 or 3;b is an integer equal to 2 or more;R is a di- or a poly-valent group selected from hydrocarbon groups and hydrocarbon groups containing ether linkages;Z is a segment of: (1) a polyether; (2) a polyester containing polyether polyester hydrocarbon segments, (3) a hydrocarbon; (4) a polysiloxane; or (5) combinations thereof.

Abstract: A process for preparing a nylon block polymer which comprises bringing into reactive contact lactam monomer, basic lactam polymerization catalyst and a composition containing one or more acyllactam functional materials selected from the group consisting of: ##STR1## wherein, Q is ##STR2## with Y=C.sub.3 -C.sub.11 alkylene; a is an integer equal to 1, 2 or 3;b is an integer equal to 2 or more;R is a di- or a poly- valent group selected from hydrocarbon groups and hydrocarbon groups containing ether linkages;Z is a segment of: (1) a polyether or polymeric hydrocarbon; (2) a polyester containing polyether segments (3) a hydrocarbon; (4) a polysiloxane; or (5) combinations thereof.

Abstract: A process for coating a substrate with a film of cured polymer in which a mixture of a poly (.alpha., .beta.-ethylenically unsaturated) oligomer, a polyallyloxy activator compound containing an effective amount of a free radical polymerization initiator and a catalytic amount of metal drier is prepared, the admixture is applied to the substrate in an air or oxygen rich atmosphere and the coated substrate is then placed in an atmosphere substantially free of oxygen until the coating has cured to a substantially tack-free condition.

Abstract: Composition for use in preparing a nylon-6 block copolymer in which a solution comprising an acyl-lactam, epsilon-caprolactam and magnesium chloride is brought into reactive admixture with a solution of magnesium dilactam in epsilon-caprolactam. The acyl-lactam magnesium chloride solution is prepared by reaction of an acid halide functional material and magnesium dilactam.

Abstract: Tough multi-phase thermoplastic compositions consisting essentially of 55 to 99 parts by weight of a polyamide matrix and 1 to 45 parts by weight of a multiphase polymer comprising 50 to 90 parts by weight of a crosslinked elastomer core and 10 to 50 parts by weight of a rigid polymer shell comprising from about 1 to about 25 parts by weight of an interpolymerized ethylenically unsaturated carboxylic acid monomer, from about 20 to about 80 parts by weight of interpolymerized styrene, from about 0 to about 79 parts by weight of an interpolymerized C.sub.1 to C.sub.8 alkyl acrylate or methacrylate and from about 0 to about 45 parts by weight of an interpolymerized acrylonitrile. The toughened compositions are useful for making molded and extruded parts possessing impact resistance and ductility.

Abstract: A class of epoxy compounds, (i.e. polyglycidamides) are blended with polyamines and other epoxy reactive oligomers to provide crosslinkable coating systems. When the systems are cured they are tough and abrasion resistant, possess solvent, chemical and water resistance and UV stability.

Abstract: Crystallizable hot melt adhesive compositions comprising block copolyesteramides and alkali metal salts of carboxy polymers. The block copolyesteramides comprise hard or crystalline polyester blocks and soft or amorphous polyamide blocks in the weight ratio of 2:3 to 4:1. The alkali metal salts are salts of copolymers of C.sub.1 to C.sub.4 aliphatic olefins and acrylic or methacrylic acid or salts of copolymers of aromatic olefins and maleic anhydride and provide a concentration of alkali metal cation in the range of 0.1 to 15 meq per 100 parts by weight of copolyesteramide. The hot melt adhesive compositions are useful for bonding plastic parts to form plastic structures which are relatively free of bond line distortion.

Abstract: A composition containing acyllactam functional materials, which are useful in the preparation of nylon block polymers, selected from the group consisting of: ##STR1## wherein, Q is ##STR2## with Y=C.sub.3 -C.sub.11 alkylene; a is an integer equal to 1, 2 or 3;b is an integer equal to 2 or more;R is a di- or a poly- valent group selected from hydrocarbon groups and hydrocarbon groups containing ether linkages;Z is a segment of: (1) a polyether; (2) a polyester containing polyether or polymeric hydrocarbon segments; (3) a hydrocarbon; (4) a polysiloxane; or (5) combinations thereof.

Abstract: Polyblends comprising about 10 to about 90% by weight of polyphenylene oxide and about 90 to about 10% of SAN or ABS polymer comprising 8 to 17 average % by weight acrylonitrile in which the acrylonitrile compositional distribution in the SAN or ABS polymer is broad in that the standard deviation of the weight % AN about the mean value is at least about 3.5%.

Abstract: Extruded polyvinyl butyral (PVB) sheet roughness is controlled by use of PVB resin lightly cross-linked through intermolecular linkages developed through use of the hydrated form of formaldehyde.

Abstract: Molding compositions are prepared from blends of (A) a styrene-maleic anhydride-methyl methacrylate terpolymer; (B) an ABS or MBS polymer; and (C) a polycarbonate. Component A, the styrene-maleic anhydride-methyl methacrylate terpolymers may optionally contain a rubber component.

Abstract: An intermediate for use in a polyblend consisting essentially of a copolymer of monoalkenyl aromatic monomer such as styrene and a ethylenically unsaturated nitrile monomer such as acrylonitrile surface grafted onto rubber which is dispersed in a matrix copolymer of the graft copolymer monomers, the dispersed phase being monomodal in particle size distribution and the weight percent of surface-grafted nitrile monomer being less by at least 2% than the weight percent nitrile monomer in the matrix. This intermediate with mismatched nitrile monomer can be blended with another rubber graft copolymer of different particle size dispersed in ungrafted matrix which contains matched nitrile monomer in the surface graft and matrix to provide a polyblend having properties at least equivalent to those obtained by blending two rubber graft copolymers of different particle size dispersed in a matrix which each contain matched nitrile monomer levels in the surface graft and matrix.

Abstract: Coating of a resin blend on a metal substrate by electrodeposition wherein the resin blend comprises a poly(3,4-dihydro-3-substituted-1,3-benzoxazine) and a reactive polyamine. The resin blend is dispersed in an aqueous medium containing a protonating acid and is subjected to cathodic electrophoresis to deposit the blend on a metal substrate as an adherent film which is dried and cured by the application of heat. The resin blend cures at relatively low temperatures without evolution of volatile matter.

Abstract: Radiation-curable compositions comprising an ester of an ethylenically unsaturated acid and a polyhydric alcohol and an oxopropyl isocyanurate formed by the addition of from 2 to 3 moles of acrolein to 1 mole of isocyanuric acid. The compositions are useful as coatings, printing inks, adhesives and the like.

Abstract: A process for preparing improved low temperature curable coating compositions comprising (1) forming a solution of an alkoxymethylmelamine and a styrene-allyl alcohol copolymer in a solvent and (2) adding to the solution a solution of a hydroxy-containing resin.

Abstract: Crystallizable hot melt adhesive compositions comprising block copolyesteramides and alkali metal carboxylates. The block copolyesteramides comprise hard or crystalline polyester blocks and soft or amorphous polyamide blocks in the weight ratio of 2:3 to 4:1. The alkali metal carboxylates provide a concentration of alkali metal cation in the range of 0.1 to 6 meq per 100 parts by weight of copolyesteramide. The hot melt adhesive compositions are useful for bonding plastic parts to form plastic structures which are relatively free of bond line distortion.