Patents Represented by Attorney R. Bruce Blance
  • Patent number: 4546147
    Abstract: The present invention provides compositions which comprise a blend of: p0 (a) from about 10 to about 97 percent by weight of the composition of a polyamide resin having a minimum molecular weight of about 5,000; p0 (b) from about 3 to about 90 percent by weight of the composition of an elastomeric polymer which(1) is selected from a group consisting of poly(ethylene oxide), poly(propylene oxide), polycaprolactone, polytetrahydrofuran, polybutadiene, polyisoprene, polyisobutylene, poly(C.sub.1 -C.sub.8 alkylene acrylate), poly(C.sub.1 -C.sub.4 dialkylene siloxane), poly(ethylene-co-propylene), poly(ethylene-co-carbon monoxide), polyethylene-co-vinyl chloride, and poly(ethylene-co-vinyl acetate) polymers and copolymers and combinations thereof; and(2) contains a minimum of about 0.055 milliequivalents of acyllactam groups per gram of said elastomeric polymer.
    Type: Grant
    Filed: November 10, 1982
    Date of Patent: October 8, 1985
    Assignee: Monsanto Company
    Inventors: James C. Woodbrey, Marlowe V. Moncur, Ross M. Hedrick
  • Patent number: 4545504
    Abstract: Apparatus for dispensing a hot melt thermoplastic consists of a hopper containing granular thermoplastic, an extruder for melting the molten thermoplastic and delivering it to a manifold and then to an applicator for dispensing the molten thermoplastic. Optionally an accumulator can be attached to allow the molten thermoplastic to accumulate during off-periods of the applicator. Operation of the applicator controls operation of the extruder and the accumulator.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: October 8, 1985
    Assignee: Monsanto Company
    Inventors: David A. Fabel, John C. Hoagland, Chester L. Woodworth
  • Patent number: 4542047
    Abstract: A process for bonding a reinforced plastic structure which comprises coating reinforced plastic parts of sheet molding compounds or bulk molding compound with a primer coat and bonding together with a thermoplastic block copolymer.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: September 17, 1985
    Assignee: Monsanto Company
    Inventors: Donald D. Donermeyer, Joseph G. Martins, David A. Fabel
  • Patent number: 4520184
    Abstract: Compositions comprising a non-air-drying polyacrylyl monomer and a polyetherene selected from the group consisting of oligomers of allyl glycidyl ether. The compositions provide hard, clear, glossy, abrasion resistant polymers.
    Type: Grant
    Filed: June 3, 1983
    Date of Patent: May 28, 1985
    Assignee: Monsanto Company
    Inventor: Donald N. Van Eenam
  • Patent number: 4517327
    Abstract: A process for preparing an improved low temperature curable water dispersed coating compositions comprising (1) forming a solution of an alkoxymethylmelamine and a styrene-allyl alcohol copolymer in a polar solvent and (2) adding to the solution an aqueous solution or dispersion of a hydroxyl-containing resin.
    Type: Grant
    Filed: January 26, 1984
    Date of Patent: May 14, 1985
    Assignee: Monsanto Company
    Inventors: John F. Heaps, Dennis E. Erickson
  • Patent number: 4507428
    Abstract: An aqueous dispersion comprising a poly(3,4-dihydro-3-substituted-1,3 benzoxazine) and a protonated reactive polyamine, wherein the polyamine is at least difunctional, its reactive groups being primary or secondary amine and is protonated with an inorganic or organic acid and wherein the poly(dihydrobenzoxazine) is the reaction product of about 1 equivalent of a primary amine, about 1 equivalent of a phenol and about two equivalents of formaldehyde. The dispersions can be dried and cured to provide useful surface coatings and primers. The curing step occurs without evolution of volatile matter.
    Type: Grant
    Filed: February 17, 1984
    Date of Patent: March 26, 1985
    Assignee: Monsanto Company
    Inventors: Harold P. Higginbottom, Manuel F. Drumm
  • Patent number: 4501864
    Abstract: A polymerizable composition comprising a poly(3,4-dihydro-3-substituted-1,3 benzoxazine) and a reactive polyamine, wherein the polyamine is at least difunctional and its reactive groups are primary or secondary amine and wherein the poly(dihydrobenzoxazine) is the reaction product of about 1 equivalent of a primary amine, about 1 equivalent of a phenol and about two equivalents of formaldehyde. The compositions are useful as potting, encapsulating and laminating resins and as surface coatings.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: February 26, 1985
    Assignee: Monsanto Company
    Inventor: Harold P. Higginbottom
  • Patent number: 4474938
    Abstract: Thermotropic polyesters consisting essentially of units derived from diphenols and aromatic dicarboxylic acids are prepared via monocarboxylic acid esters of the diphenols by acidolysis in two steps. The first step is a melt prepolymerization to form a prepolymer of inherent viscosity in the range of 0.12 to 0.16 dl g.sup.-1. The second step is a melt polymerization by a single pass through a wiped film reactor, in which the film of polymer melt is subjected to a high rate of shear and to a temperature in the range within which the polyester forms an anisotropic melt phase. The polyester product has an inherent viscosity of at least about 0.5 dl g.sup.-1.
    Type: Grant
    Filed: August 4, 1983
    Date of Patent: October 2, 1984
    Assignee: Monsanto Company
    Inventor: John C. Richardson
  • Patent number: 4473616
    Abstract: Molded articles comprising glass fiber reinforced styrene polymer wherein the weight ratio of glass fiber to styrene polymer is in the range of about 55:45 to about 75:25. The molded articles are prepared by a transfer molding process in which glass fiber mat containing 1 to 5 weight percent of an unsaturated polyester binder is impregnated with styrene monomer and the mold is subjected to conditions which induce fast polymerization of the styrene monomer. The molded articles possess resistance to heat distortion.
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: September 25, 1984
    Assignee: Monsanto Company
    Inventor: Leo E. Rademacher
  • Patent number: 4473615
    Abstract: Molded articles comprising fiber reinforced polyether modified styrene polymer wherein the weight ratio of glass fiber to styrene polymer is in the range of about 55:45 to about 75:25. The molded articles are prepared by a transfer molding process in which glass fiber mat containing 1 to 5 weight percent of an unsaturated polyester binder is impregnated with styrene monomer mixture containing an unsaturated polyether and the mold is subjected to conditions which induce fast polymerization of the monomer mixture. The molded articles possess resistance to heat distortion.
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: September 25, 1984
    Assignee: Monsanto Company
    Inventors: Leo E. Rademacher, Edward F. Tokas
  • Patent number: 4454354
    Abstract: Formaldehyde manufacture by oxidative-dehydrogenation of methanol over a silver or copper catalyst. Aqueous formaldehyde solution is obtained from the reaction and is stripped of a mixture of methanol, formaldehyde and water by a low energy process at relatively low temperature and low reflux in a still comprising at least about 1.5 theoretical plates, the stripping conditions being selected to allow substantial reduction of the methanol content of the aqueous formaldehyde solution and recycle of the methanol to the reactor.
    Type: Grant
    Filed: August 2, 1982
    Date of Patent: June 12, 1984
    Assignee: Monsanto Company
    Inventors: Theodore V. Ferris, Richard C. Kmetz
  • Patent number: 4448807
    Abstract: A process for making an electrographic recording material which comprises applying to a conductive support an electrically insulating layer comprising an intimate blend of a vinyl ester interpolymer latex and up to 500 parts of an inert finely divided pigment per 100 parts by weight of latex interpolymer. The vinyl ester interpolymer comprises about 3 to about 7 weight percent of carboxylic acid groups supplied by an interpolymerized C.sub.4 -C.sub.10 vinylene monobasic carboxylic acid monomer.
    Type: Grant
    Filed: May 16, 1983
    Date of Patent: May 15, 1984
    Assignee: Monsanto Company
    Inventor: Irving Serlin
  • Patent number: 4447594
    Abstract: Heat-curable compositions comprising an ester of an ethylenically unsaturated acid and a polyhydric alcohol, an oxopropyl isocyanurate formed by the addition of from 2 to 3 moles of acrolein to 1 mole of isocyanuric acid and a free radical or ionic initiator. The compositions are useful as coatings, adhesives and the like.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: May 8, 1984
    Assignee: Monsanto Company
    Inventors: Saul M. Cohen, John R. LeBlanc
  • Patent number: 4444980
    Abstract: Disclosed are liquid crystal copolyesters prepared from p-hydroxybenzoic acid, isophthalic acid, hydroquinone and 2,2-bis(4-hydroxyphenyl) propane.
    Type: Grant
    Filed: March 15, 1983
    Date of Patent: April 24, 1984
    Assignee: Monsanto Company
    Inventor: Oliver D. Deex
  • Patent number: 4444945
    Abstract: Low-salt containing aqueous solutions of melamine formaldehyde condensation products having anionic sulfo groups are prepared in a two stage process. In the first stage melamine, formaldehyde, and bisulfite are condensed in an aqueous solution at atmospheric reflux and pH 8-10 for 1-5 hours. In the second stage, condensation is continued at pH 6-7 and atmospheric reflux for 2-6 hours. The product is cooled and adjusted to pH 7-9.
    Type: Grant
    Filed: February 15, 1983
    Date of Patent: April 24, 1984
    Assignee: Monsanto Company
    Inventor: George E. Sheldrick
  • Patent number: 4443518
    Abstract: A bonded reinforced plastic structure which comprises reinforced plastic parts of sheet molding compound or bulk molding compound, coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises a moisture-curable polyisocyanate. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.
    Type: Grant
    Filed: February 4, 1983
    Date of Patent: April 17, 1984
    Assignee: Monsanto Company
    Inventors: Joseph G. Martins, Donald D. Donermeyer, David A. Fabel
  • Patent number: 4443519
    Abstract: A bonded plastic structure which comprises plastic parts of reaction injection molded polyurethane or reaction injection molded nylon coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises a moisture-curable polyisocyanate. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.
    Type: Grant
    Filed: February 4, 1983
    Date of Patent: April 17, 1984
    Assignee: Monsanto Company
    Inventors: Donald D. Donermeyer, Joseph G. Martins, David A. Fabel
  • Patent number: 4433143
    Abstract: A partially methylated partially methylolated melamine composition comprising a fraction of highly polar monomers characterized by liquid chromatography elution ratios. The composition is useful as a crosslinking agent for coating resins and provides curable coating systems capable of fast cure response at relatively low curing temperatures.
    Type: Grant
    Filed: September 9, 1981
    Date of Patent: February 21, 1984
    Assignee: Monsanto Company
    Inventors: J. Owen Santer, George T. Spitz
  • Patent number: 4425466
    Abstract: Coating compositions comprising a partially methylated partially methylolated melamine and a polyfunctional compound containing on average at least two functional groups per molecule selected from the group consisting of carboxy, hydroxy, primary and secondary amide and urethane. The partially methylated partially methylolated melamine comprises a fraction of highly polar monomers characterized by liquid chromatography elution ratios. The coating compositions are stable at ambient temperature and capable of fast cure response at relatively low curing temperatures.
    Type: Grant
    Filed: September 9, 1981
    Date of Patent: January 10, 1984
    Assignee: Monsanto Company
    Inventors: J. Owen Santer, George T. Spitz
  • Patent number: 4400554
    Abstract: Bis(hydroxyphenyl)methanes are prepared by reaction of phenol and formaldehyde in a two-phase mixture containing aqueous phosphoric acid. The reaction conditions can be selected to provide high yields of bis(hydroxyphenyl)methanes or to yield bis(hydroxyphenyl)methanes containing a high concentration of the 4,4'-isomer.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: August 23, 1983
    Assignee: Monsanto Company
    Inventor: Morris R. Ort