Patents Represented by Attorney, Agent or Law Firm R. L. Graham
  • Patent number: 5618566
    Abstract: Modular die constructions includes a plurality of side-by-side self-contained, interchangeable meltblowing modules on a manifold so that the length of the die can be varied by adding modules or removing modules from the manifold.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: April 8, 1997
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5607701
    Abstract: A meltblowing die for producing nonwoven polymer webs includes an inner tube having a plurality of orifices arranged in a row thereon, and an outer tube encasing the inner tube and having a slot formed therein in registry with the row orifices. The inner tube and outer tubes are constructed to define converging air passages on either side of the row of orifices, whereby hot air delivered to the outer tube converges on polymer fibers extruded through the orifices and imparts drag forces thereon to attenuate and draw down the fibers to microsize.
    Type: Grant
    Filed: February 16, 1995
    Date of Patent: March 4, 1997
    Assignee: J&M Laboratories, Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5605720
    Abstract: An in-line continuous method of formulating and applying a hot melt adhesive to a substrate involves metering a particulate polymer adhesive and a tackifier in a weight ratio in an extruder where the raw materials are formed into a homogeneous melt. The melt is continuously discharged directly into a hot melt applicator for deposition onto a substrate.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: February 25, 1997
    Assignee: J & M Laboratories Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5605706
    Abstract: A meltblowing die assembly featuring a preassembled die tip assembly permitting the rapid exchange thereof. The preassembled die tip assembly includes a die tip having a triangular nosepiece, a member mounted on the die tip assembly for conforming the die tip to the die body, and a pair of air plates mounted on the die tip and in combination with the nosepiece define converging air slots.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: February 25, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5543387
    Abstract: Subterranean oil-bearing formations are treated with aqueous acid solutions which include an effective amount of an alkoxylated alkyl substituted phenol sulfonate which exhibits both antisludge and demulsification properties.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: August 6, 1996
    Assignees: Nalco/Exxon Energy Chemicals, L.P, Exxon Production Research Co.
    Inventors: Anita R. Mokadam, Charles E. Strubelt, Dennis A. Williams, Kenneth M. Webber
  • Patent number: 5543388
    Abstract: Elemental iodine is used to improve the performance of conventional corrosional inhibitors in oil field acidizing operations. The iodine, because of its solubility, may be used in a formulation which includes a corrosion inhibitor and surfactants dissolved in a suitable organic solvent.
    Type: Grant
    Filed: August 5, 1993
    Date of Patent: August 6, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Dennis A. Williams, Lee A. McDougall, James R. Looney
  • Patent number: 5505878
    Abstract: Water-in-oil emulsions are broken by the use of adducts prepared by reacting high molecular weight polyalkylene glycol with ethylene oxide, or diglycidyl ether, or both ethylene oxide and diglycidyl ether. The adduct demulsifiers may be used alone or as a blend with other demulsifiers.
    Type: Grant
    Filed: May 18, 1994
    Date of Patent: April 9, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Grahame N. Taylor, Richard Mgla
  • Patent number: 5470823
    Abstract: A coalbed formation is stimulated to improve the recovery of methane which involves injecting into the coalbed formation an aqueous acid solution containing an organic amphoteric tertiary ammonium compound having from 1 to 3 tertiary ammonium groups, each N of which contains at least one C.sub.3 to C.sub.4 unsaturated carboxylic acid group, and wherein the compound contains a terminal benzyl or C.sub.5 -C.sub.19 alkyl group.
    Type: Grant
    Filed: May 3, 1993
    Date of Patent: November 28, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Dennis A. Williams, James R. Looney, Michael W. Conway, Robert A. Swenson
  • Patent number: 5470663
    Abstract: High MI, high MP ethylene-fluorinated ethylene copolymers (preferably ECTFE) are meltblown through relatively large orifices. The web produced by the process is characterized by low fiber size and high strength.
    Type: Grant
    Filed: January 6, 1995
    Date of Patent: November 28, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Larry C. Wadsworth, Ahamad Y. Khan
  • Patent number: 5468367
    Abstract: A salt of polyacrylic acid having a molecular weight of between 1,000 and 50,000, preferably 1,000 to 5,000, is used to inhibit inorganic fouling in crude oil.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: November 21, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Ghazi Dickakian
  • Patent number: 5453519
    Abstract: Dialkylphenylenediamines are used to inhibit oxidation and polymerization of furfural or furfural derivatives. The preferred use of the inhibitor is in the solvent refining of lubricating oils using furfural to extract constituents from the lubricating oils. Prior to and/or during the treatment the acidity of the furfural is adjusted to a level below 0.20 mg KOH/gram furfural.
    Type: Grant
    Filed: March 29, 1994
    Date of Patent: September 26, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Ghazi Dickakian
  • Patent number: 5445509
    Abstract: A meltblowing die assembly featuring a preassembled die tip assembly permitting the rapid exchange thereof. The preassembled die tip assembly includes a die tip having a triangular nosepiece, a member mounted on the die tip assembly for conforming the die tip to the die body, and a pair of air plates mounted on the die tip and in combination with the nosepiece define converging air slots.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: August 29, 1995
    Assignee: J & M Laboratories, Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5427999
    Abstract: Amines which are compounds of the formula I: ##STR1## where R is a C.sub.6-20 hydrocarbon;X is --NR.sub.1 -- or --O--;each R.sub.1 is independently H or --[(CH.sub.2).sub.1-4 ]COOH or a C.sub.6-20 hydrocarbon;n is 1, 2 or 3;and which contains at least one (CH.sub.2).sub.1-4 COOH group; or salt thereof are useful in inhibiting corrosion of metals in a marine or freshwater environment e.g. in oil- and gas-field applications since they show relatively low toxicity to marine organisms.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: June 27, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Paul J. Clewlow, John A. Haslegrave, Niall Carruthers, Daniel S. Sullivan, III, Brent Bourland
  • Patent number: 5421941
    Abstract: A hot melt adhesive polymer is applied to a diaper backsheet by an aligned series of meltblowing units which are selectively operable to apply the coating in the desired geometry on the diaper backsheet.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: June 6, 1995
    Assignee: J & M Laboratories, Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5409642
    Abstract: An apparatus and method for producing a meltblown continuous and seamless nonwoven tube is described. The apparatus comprises a meltblowing die for extruding two groups of polymer thermoplastic filaments onto a rotating mandrel to form a multilayer layer tube thereon. The tube is withdrawn from the mandrel by a rotating screw. The present apparatus is capable of producing nonwoven tubes having variable fiber diameters and/or composition in the radial direction, making them ideally suited for filtration purposes.
    Type: Grant
    Filed: October 6, 1993
    Date of Patent: April 25, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Martin A. Allen, John T. Fetcko
  • Patent number: 5407585
    Abstract: Water-in-oil emulsions are broken by the use of adducts prepared by reacting high molecular weight polyalkylene glycol with ethylene oxide, or diglycidyl ether, or both ethylene oxide and diglycidyl ether. The adduct demulsifiers may be used alone or as a blend with other demulsifiers.
    Type: Grant
    Filed: August 16, 1993
    Date of Patent: April 18, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Grahame N. Taylor, Richard Mgla
  • Patent number: 5370184
    Abstract: Granules containing a gel breaker are used in a well treatment involving the use of a gelled fluid. The granules exhibit delayed release of the breaker to permit placement of the gelled fluid into the subterranean formation. The method of the present invention is used in gravel packing operation to degrade polymeric gelling agents used in the gravel packing liquid.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: December 6, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Lee A. McDougall, Fati Malekahmadi, Dennis A. Williams
  • Patent number: 5354453
    Abstract: Reactive S (e.g. H.sub.2 S and mercaptans) in petroleum liquid are scavenged by the use of oil soluble trialkyl hexahydro triazines wherein at least one alkyl group, and preferably all three, contain from 7 to 20 carbon atoms.
    Type: Grant
    Filed: April 13, 1993
    Date of Patent: October 11, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Kishan Bhatia
  • Patent number: 5322630
    Abstract: A method of acidizing a subterranean formation with an acqueous acid solution wherein the acid solution contains corrosion inhibiting amounts of an amine derivative prepared by reacting an unsaturated carboxylic acid with (a) fatty amine or polyamine, or (b) a fatty amido amine or polyamine, or (c) a fatty imidazoline amine or polyamine. The derivative is characterized by the absence of primary amino groups, and preferably contains only tertiary amino groups.
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: June 21, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Dennis A. Williams, James R. Looney, Daniel S. Sullivan, Brent I. Bourland, John A. Haslegrave, Paul J. Clewlow, Niall Carruthers, Terence M. O'Brien
  • Patent number: 5300235
    Abstract: Amine derivatives which are compounds of the formula (I): ##STR1## in which R is a C.sub.6-20 hydrocarbon; Y is --CO--NH-- and n is an integer of 1 to 6; or ##STR2## in which X is an alkylene group of 2 to 6 carbon atoms and n is an integer of 0 to 6;each R.sub.1 is independently H, --(CH.sub.2).sub.1-4 COOH, a C.sub.6-20 hydrocarbon or C.sub.6-20 hydrocarbon-carbonyl;R.sub.2 is H, (CH.sub.2).sub.1-4 COOH or C.sub.6-20 hydrocarboncarbonyl;the compound containing at least one (CH.sub.2).sub.1-4 COOH group; or a salt thereof are useful in inhibiting corrosion of metals in oil- and gas-field applications, and also show low toxicity to marine organisms.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: April 5, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Paul J. Clewlow, John A. Haselgrave, Niall Carruthers, Terence M. O'Brien