Abstract: Polyoxyalkylene polyether admixtures and polysiloxane-polyoxyalkylene block copolymers, a solventless process for producing said copolymers using said admixtures, a process for producing flexible polyether polyurethane foam using said copolymers as foam stabilizers and the foam produced thereby.
Abstract: Linear siloxane-polyoxyalkylene (AB).sub.n block copolymers having an average molecular weight of at least about 30,000, compositions of polyurethane-forming froths containing said copolymers, the curable froths produced from said compositions, methods for utilizing said froths as well as the cured foams and articles produced therefrom, said froths having utility in the production of molded polyurethane foam articles, foam backings for carpeting and fabrics, coatings for wire, cable and other articles, small cavity encapsulations, and the like.
Abstract: Linear siloxane-polyoxyalkylene (AB).sub.n block copolymers having an average molecular weight of at least about 30,000, compositions of polyurethane-forming froths containing said copolymers, the curable froths produced from said compositions, methods for utilizing said froths as as well as the cured foams and articles produced therefrom, said froths having utility in the production of molded polyurethane foam articles, foam backings for carpeting and fabrics, coatings for wire, cable and other articles, small cavity encapsulations, and the like.
Abstract: A particular class of tertiary alcohol substituted organosilicone polymers are provided which comprise chemically combined monofunctional siloxy units (M.sub.o) and difunctional siloxy units (D.sub.o) and, for every two moles of M.sub.o, an average of from about two to about 100 silicon-bonded tertiary alcohol groups (Q) and an average of from about 2 to about 30 silicon-bonded E.degree. groups where E.degree. is hydrogen or a polyoxyalkylene block (E). When E.degree. is hydrogen, the polymers are tertiary alcohol-substituted polyalkylsiloxane hydrides and, when E.degree. is E, the polymers are tertiary alcohol-substituted polyalkylsiloxane-polyoxyalkylene copolymers. The monofunctional siloxy units encompassed by M.sub.o have at least two alkyls bonded to the respective silicon atoms thereof and the difunctional siloxy units encompassed by D.sub.o have at least one alkyl bonded to the respective silicon atoms thereof, the remaining group bonded to silicon of said M.sub.o and D.sub.
Abstract: Particulate thermoplastic polyurethane polymers are produced in inert organic non-solvent for the polymer by polymerization of diisocyanate, dihydroxy polymer and chain extender in the presence of an organic polymeric interfacial agent. The agent can be a block copolymer of C.sub.6 -C.sub.30 alkyl alkenoate and vinyl halide, a block copolymer of the alkenoate and a polyoxyalkylene glycol, a block copolymer of the alkenoate and a cyclic ester such as caprolactone, or a graft copolymer of the alkenoate, vinyl monomer with hydroxyl or amino group such as an hydroxyalkyl acrylate or an amino alkyl acrylate, and a cyclic ester.
Type:
Grant
Filed:
July 17, 1975
Date of Patent:
December 28, 1976
Assignee:
Union Carbide Corporation
Inventors:
Frank Edward Critchfield, Frank Paul Del Giudice, Richard Michael Gerkin
Abstract: Process for producing cyclic siloxanes by hydrolysis and condensation, the improvement comprising carrying out the process in the presence of a cationic surface active agent.
Abstract: Polyoxyalkylene polyether admixtures and polysiloxane-polyoxyalkylene block copolymers, a solventless process for producing said copolymers using said admixtures, a process for producing flexible polyether polyurethane foam using said copolymers as foam stabilizers and the foam produced thereby.
Abstract: A process for producing high resilience polyether urethane foam using a cyanoalkoxy-alkyl modified siloxane fluid; the foams derived therefrom; a solvent-solution of said siloxane; and cyanoalkoxy-alkyl modified siloxane fluids per se.
Abstract: A process for producing high resilience polyether urethane foam using a cyanoalkoxy-alkyl modified siloxane fluid; the foams derived therefrom; a solvent-solution of said siloxane; and cyanoalkoxyalkyl modified siloxane fluids per se.
Abstract: Quaternary ammonium salts of chloromethylated silanes or siloxanes which contain at least one[Cl.sup.-R.sub.3 "N.sup.+CH.sub.2 --Ar--(R).sub.n ]radical directly linked to a silicon atom wherein Ar is an arylene radical, wherein R.sub.3 "N taken collectively is a tertiary amine radical and wherein the compounds are useful in conventional silicon applications such as anti-static agents, wetting agents, lubricants, hydraulic fluids, coating resins, elastomers and cationic surfactants.
Abstract: Linear siloxane-polyoxyalkylene (AB).sub.n block copolymers having an average molecular weight of at least about 30,000, compositions of polyurethane-forming froths containing said copolymers, the curable froths produced from said compositions, methods for utilizing said froths as well as the cured foams and articles produced therefrom, said froths having utility in the production of molded polyurethane foam articles, foam backings for carpeting and fabrics, coatings for wire, cable and other articles, small cavity encapsulations, and the like.
Abstract: Compositions comprising a polyepoxide or an amine hardner and less than 0.1 per cent by weight of a quaternary ammonium compound based on the weight of the polyepoxide or amine hardner employed which compositions resist filler hard-settle upon storage and are suitable precursor compositions for cured epoxide products.
Abstract: A process for producing high resilience polyether urethane foam using a cyanoalkyl modified siloxane fluid; the foams derived therefrom; a solvent-solution of said siloxane; and cyanoalkyl modified siloxane fluids per se.
Abstract: Linear siloxane-polyoxyalkylene (AB).sub.n block copolymers having an average molecular weight of at least about 30,000, compositions of polyurethane-forming froths containing said copolymers, the curable froths produced from said compositions, methods for utilizing said froths as well as the cured foams and articles produced therefrom, said froths having utility in the production of molded polyurethane foam articles, foam backings for carpeting and fabrics, coatings for wire, cable and other articles, small cavity encapsulations, and the like.