Patents Represented by Attorney Robert A. Gerlach
  • Patent number: 5244763
    Abstract: Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: September 14, 1993
    Assignee: Eastman Kodak Company
    Inventors: Ralph B. Nielsen, Lan B. Thai, Hwei-ling Yau
  • Patent number: 5244728
    Abstract: A photographic paper coated with a polyolefin resin layer on each surface, one of the free surfaces of one of the polyolefin layers bearing a print retaining antistatic layer, the print retaining antistatic layer consisting essentially of an aluminum modified colloidal silica and an antistatic agent in a binder polymer, the binder polymer consisting essentially of an addition product of from about 30 to 78 mol % of an alkyl methacrylate wherein the alkyl group has from 3 to 8 carbon atoms, from about 2 to about 10 mol % of an alkali metal salt of an ethylenically unsaturated sulfonic acid and from 20 to about 65 mol % of a vinyl benzene, the polymer having a glass transition point of from 30.degree. to 65.degree. C.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: September 14, 1993
    Assignee: Eastman Kodak Company
    Inventors: Wayne A. Bowman, Mario D. DeLaura, Norman S. Edgett
  • Patent number: 5230818
    Abstract: A coating composition is provided for master media for anhysteretic transfer of magnetically recorded information to a copy medium which comprises from about 50 to about 69% of a magnetic pigment, from about 2.95 to about 6.90% of an abrasive powder, from 0 to about 5.4% of a colloidal inorganic powder, from about 2.9 to about 4.5% of a wetting agent, from about 0.7 to about 3.1% of a lubricant, from about 14.1 to about 33.6% of a binder, at least 85% of which is a polyurethane and from 0.05 to about 15% of which is a polyisocyanate crosslinking agent. The composition is preferably disposed on a substrate backcoated with a composition containing from about 15 to about 25% of carbon black, from about 15 to about 25% of an inorganic filler, from about 0.5 to about 2% of an abrasive, from about 20 to about 30% of a vinyl copolymeric binder, from about 15 to about 25% of a polyurethane binder, from about 7.5 to about 17.5% of an NCO terminated crosslinking agent, from about 0.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: July 27, 1993
    Assignee: Eastman Kodak Company
    Inventors: Robert O. James, Harry J. Sherwood, Joseph A. Verdone
  • Patent number: 5223383
    Abstract: Disclosed are photographic elements having reflective or diffusely transmissive supports shaped from a continuous oriented polymer phase having dispersed therein microbeads of a polymer which are at least partially bordered by void space, the microbeads being present in an amount of about 5-50% by weight based on the weight of the oriented polymer, and the void space occupying about 2-60% by volume of the support. Preferably, the microbeads are cross-linked to an extent they will be resilient and elastic at the orientation temperature, and are coated with a slip agent. Such supports have excellent physical properties.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: June 29, 1993
    Assignee: Eastman Kodak Company
    Inventors: Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glen C. Smith
  • Patent number: 5221598
    Abstract: A base for a photographic element is provided which comprises a support having disposed thereon a vanadium pentoxide antistatic layer and an overlying barrier layer of a heat-thickening polyacrylamide polymer having hydrophilic functionality, and a method for preparing it.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: June 22, 1993
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Wayne A. Bowman, Billy R. Dotson
  • Patent number: 5219510
    Abstract: A cellulose ester film which can be melt cast is manufactured by esterfying cellulose to form a cellulose acetate or cellulose acetate propionate having degrees of substitution of DSac=1.9 to 2.6, DSpr=0 to 0.9 and DS.sub.OH =0 to 0.55 and melt compounding the resulting polymer with a non-volatile phosphoric acid ester. A film is formed by melt extruding the compounded polymer onto a cooling surface to form a solid film. The film is then biaxially oriented at 130.degree. to 200.degree. C. and a stretch ratio of 1.25.times. to 2.5.times. in both directions. The resulting product is a film of excellent properties such as surface smoothness, light transmission, low haze, low color, high elastic modulus and curl relaxation after aqueous processing. The melt cast film is useful as a photographic roll film to replace solvent cast cellulose triacetate.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: June 15, 1993
    Assignee: Eastman Kodak Company
    Inventors: Julie S. Machell, I. Daniel Sand
  • Patent number: 5217804
    Abstract: Magnetic particles are cobalt surface treated gamma iron oxide (Fe.sub.2 O.sub.3) having a specific area of at least 30 m.sup.2 /g and a powder coercivity greater than about 450 Oe, the particles being coated with from about 10 to about 50% by weight of a material having a refractive index less than about the refractive index of a binder for the particles.
    Type: Grant
    Filed: November 6, 1990
    Date of Patent: June 8, 1993
    Assignee: Eastman Kodak Company
    Inventors: Robert O. James, Sidney J. Bertucci, George L. Oltean
  • Patent number: 5215192
    Abstract: A method for improving the archival properties of a processed photographic film and a storage assembly for achieving the same by placing the film in a sealed container together with molecular sieve zeolites.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: June 1, 1993
    Assignee: Eastman Kodak Company
    Inventors: Arunachalam T. Ram, Carl F. Holtz, Richard C. Sehlin, David F. Kopperl
  • Patent number: 5198517
    Abstract: Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.
    Type: Grant
    Filed: August 6, 1991
    Date of Patent: March 30, 1993
    Assignee: Eastman Kodak Company
    Inventors: Ralph B. Neilsen, Lan B. Thai, Hwei-ling Yau
  • Patent number: 5198499
    Abstract: Cross-linked conductive polymer, coating compositions and light sensitive elements containing at least one antistat layer where the cross-linked polymer is a copolymer of a vinylbenzene sufonic acid and an ethylenically unsaturated monomer containing at least one primary hydroxl group cross-linked with a methoxyalkylmelamine.
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: March 30, 1993
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Raymond T. Jones
  • Patent number: 5198330
    Abstract: An improved photographic support, especially useful for color prints, is comprised of a paper base material having thereon a polyolefin coating containing a white pigment and an optical brightener, such as a mixture comprising inclusion compounds of certain fluorescent bis(benzoxazolyl)-stilbenes.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: March 30, 1993
    Assignee: Eastman Kodak Company
    Inventors: Peter A. Martic, Todd R. Skochdopole
  • Patent number: 5187259
    Abstract: A soluble, chain extended gelatin having a high molecular weight and significantly higher viscosity at equivalent gelatin concentration compared to standard gelatin and significantly faster setting time is produced by preparing an aqueous gelatin composition containing from about 6% to about 18% dry weight of gelatin and from about 0.25 to about 5 millimoles of a bis-(vinyl sulfonyl) compound per 100 grams of gelatin, heating the composition at a temperature of from about 40 to about 60.degree.C. and at a pH of from about 4.5 to about 7 for from about one to about eight hours.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: February 16, 1993
    Assignee: Eastman Kodak Company
    Inventors: Melvin D. Sterman, James L. Bello
  • Patent number: 5166378
    Abstract: Mono-acylated hydrazines are prepared in high yield by reaction of a hydrazine salt with an azole derivative of acyl halide in the presence of a strong base. Useful hydrazine salts include those of the formula RNHNH.sub.2 .multidot.HX, where R is alkyl, aryl, aralkyl, acyl, aroyl, heterocyclic or heteroaryl, and HX is a mineral or organic acid. Useful azole derivatives include those of the formula R'CO--A, where R' is alkyl, aryl, aralkyl, heterocyclic or heteroaryl and A is an azole radical such as pyrrole, imidazole, pyrazole, triazole, tetrazole, indole or benzimidazole.
    Type: Grant
    Filed: May 24, 1990
    Date of Patent: November 24, 1992
    Assignee: Eastman Kodak Company
    Inventors: Chang K. Kim, Francesco Debellis, Michael E. Campbell
  • Patent number: 5159072
    Abstract: A method of heating dichloromethane laden streams to prevent discharge into the environment by contacting the laden stream with N,N-dialkyldithiocarbamate salt in the presence of oxygen and water.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: October 27, 1992
    Assignee: Eastman Kodak Company
    Inventor: Arunas V. Kavaliunas
  • Patent number: 5143765
    Abstract: Disclosed is a shaped article comprising a continuous oriented thermoplastic polymer matrix having dispersed therein microbeads of a polymer which are at least partially bordered by void space, the microbeads being present in an amount of about 5%-50% weight based on the weight of said oriented thermoplastic, said void space occupying about 2%-60% by volume of said shaped article. Preferably, the microbeads are cross-linked to an extent they will be resilient and elastic at the orientation temperature, and are coated with a slip agent. The shaped article is preferably in the form of a sheet, fibers, or other molded article, and preferably has a relatively low specific gravity and whiteness.
    Type: Grant
    Filed: March 21, 1991
    Date of Patent: September 1, 1992
    Assignee: Eastman Kodak Company
    Inventors: Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glen C. Smith
  • Patent number: 5141685
    Abstract: The present invention relates to a method of forming shaped articles having a continuous phase of an oriented thermoplastic polymer containing cross-linked polymer microbeads at least partially bordered by void space. The thermoplastic polymer in molten form is mixed with a plurality of the crosslinked polymer microbeads, and the mixture is then formed into a shaped article. The article is stretched in at least one direction to orient it. The orienting conditions and the character and quantity of crosslinked polymer microbeads is effective to form voids in the article at least bordering the microbeads on sides thereof in the direction(s) of orientation.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: August 25, 1992
    Assignee: Eastman Kodak Company
    Inventors: Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glenn C. Smith
  • Patent number: 5138024
    Abstract: A copolyester is synthesized by reacting a dialkyl ester of an aromatic dicarboxylic acid (e.g., dimethyl terephthalate) with ethylene glycol, low molecular weight poly(ethylene glycol) and a salt of a sulfonic acid-substituted aromatic dicarboxylate (e.g., sodium sulfoisophthalic acid) simultaneously in a first stage reaction in the presence of a phosphite or phosphate stabilizer. The intermediate product of the first stage is further reacted in a second stage in the presence of a polycondensation catalyst to obtain a random copolyester of the desired molecular weight. The copolyester is extruded to form a film which, after orientation and heat setting, has excellent clarity and is useful as a photographic film support. Aqueous processing of the film relaxes any core set or curl.
    Type: Grant
    Filed: January 25, 1991
    Date of Patent: August 11, 1992
    Assignee: Eastman Kodak Company
    Inventors: Carl T. Brozek, Robert C. Daly, Robert H. Fehnel, Constantine C. Petropoulos
  • Patent number: 5126405
    Abstract: Crosslinked conductive polymers, coating compositions and light sensitive elements containing at least one antistat layer where the cross-linked polymer is a copolymer of a vinylbenzene sulfonic acid and an ethylenically unsaturated monomer containing at least one primary hydroxyl group cross-linked with a hydrolyzed metal lower alkoxide.
    Type: Grant
    Filed: May 23, 1990
    Date of Patent: June 30, 1992
    Assignee: Eastman Kodak Company
    Inventors: Raymond T. Jones, Charles C. Anderson
  • Patent number: 5125996
    Abstract: Imaging paper having randomly distributed fibers and uniformly dispersed throughout unexpanded synthetic thermoplastic polymeric microspheres, a method of preparation and a method of imparting an image thereto.
    Type: Grant
    Filed: August 27, 1990
    Date of Patent: June 30, 1992
    Assignee: Eastman Kodak Company
    Inventors: Bruce C. Campbell, Barry Crouse, Todd M. Spath
  • Patent number: 5108611
    Abstract: A method of preparing a coupler dispersion in gelatin by separating the auxiliary coupler solvent using a hydrophobic microporous membrane and contacting the opposite surface of the membrane with a coupler solvent.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: April 28, 1992
    Assignee: Eastman Kodak Company
    Inventors: Stephen P. Chen, Edgar P. Lougheed, Carl B. Richenberg