Abstract: Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.
Type:
Grant
Filed:
January 11, 1993
Date of Patent:
September 14, 1993
Assignee:
Eastman Kodak Company
Inventors:
Ralph B. Nielsen, Lan B. Thai, Hwei-ling Yau
Abstract: Rapidly processible and irreversibly bleachable polymeric filter dyes for photographic elements are provided wherein a benzoxazle styryl chromophore is covalently bonded to a copolymer, particularly a copolymer of methyl acrylate, methacrylic acid, and sulfoethylmethacrylate, as well as filter layers and photosensitive elements containing them.
Abstract: A coating composition is provided for master media for anhysteretic transfer of magnetically recorded information to a copy medium which comprises from about 50 to about 69% of a magnetic pigment, from about 2.95 to about 6.90% of an abrasive powder, from 0 to about 5.4% of a colloidal inorganic powder, from about 2.9 to about 4.5% of a wetting agent, from about 0.7 to about 3.1% of a lubricant, from about 14.1 to about 33.6% of a binder, at least 85% of which is a polyurethane and from 0.05 to about 15% of which is a polyisocyanate crosslinking agent. The composition is preferably disposed on a substrate backcoated with a composition containing from about 15 to about 25% of carbon black, from about 15 to about 25% of an inorganic filler, from about 0.5 to about 2% of an abrasive, from about 20 to about 30% of a vinyl copolymeric binder, from about 15 to about 25% of a polyurethane binder, from about 7.5 to about 17.5% of an NCO terminated crosslinking agent, from about 0.
Type:
Grant
Filed:
December 20, 1991
Date of Patent:
July 27, 1993
Assignee:
Eastman Kodak Company
Inventors:
Robert O. James, Harry J. Sherwood, Joseph A. Verdone
Abstract: Disclosed are photographic elements having reflective or diffusely transmissive supports shaped from a continuous oriented polymer phase having dispersed therein microbeads of a polymer which are at least partially bordered by void space, the microbeads being present in an amount of about 5-50% by weight based on the weight of the oriented polymer, and the void space occupying about 2-60% by volume of the support. Preferably, the microbeads are cross-linked to an extent they will be resilient and elastic at the orientation temperature, and are coated with a slip agent. Such supports have excellent physical properties.
Type:
Grant
Filed:
April 30, 1990
Date of Patent:
June 29, 1993
Assignee:
Eastman Kodak Company
Inventors:
Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glen C. Smith
Abstract: A base for a photographic element is provided which comprises a support having disposed thereon a vanadium pentoxide antistatic layer and an overlying barrier layer of a heat-thickening polyacrylamide polymer having hydrophilic functionality, and a method for preparing it.
Type:
Grant
Filed:
November 23, 1992
Date of Patent:
June 22, 1993
Assignee:
Eastman Kodak Company
Inventors:
Charles C. Anderson, Wayne A. Bowman, Billy R. Dotson
Abstract: A cellulose ester film which can be melt cast is manufactured by esterfying cellulose to form a cellulose acetate or cellulose acetate propionate having degrees of substitution of DSac=1.9 to 2.6, DSpr=0 to 0.9 and DS.sub.OH =0 to 0.55 and melt compounding the resulting polymer with a non-volatile phosphoric acid ester. A film is formed by melt extruding the compounded polymer onto a cooling surface to form a solid film. The film is then biaxially oriented at 130.degree. to 200.degree. C. and a stretch ratio of 1.25.times. to 2.5.times. in both directions. The resulting product is a film of excellent properties such as surface smoothness, light transmission, low haze, low color, high elastic modulus and curl relaxation after aqueous processing. The melt cast film is useful as a photographic roll film to replace solvent cast cellulose triacetate.
Abstract: Magnetic particles are cobalt surface treated gamma iron oxide (Fe.sub.2 O.sub.3) having a specific area of at least 30 m.sup.2 /g and a powder coercivity greater than about 450 Oe, the particles being coated with from about 10 to about 50% by weight of a material having a refractive index less than about the refractive index of a binder for the particles.
Type:
Grant
Filed:
November 6, 1990
Date of Patent:
June 8, 1993
Assignee:
Eastman Kodak Company
Inventors:
Robert O. James, Sidney J. Bertucci, George L. Oltean
Abstract: A method for improving the archival properties of a processed photographic film and a storage assembly for achieving the same by placing the film in a sealed container together with molecular sieve zeolites.
Type:
Grant
Filed:
October 16, 1992
Date of Patent:
June 1, 1993
Assignee:
Eastman Kodak Company
Inventors:
Arunachalam T. Ram, Carl F. Holtz, Richard C. Sehlin, David F. Kopperl
Abstract: Cross-linked conductive polymer, coating compositions and light sensitive elements containing at least one antistat layer where the cross-linked polymer is a copolymer of a vinylbenzene sufonic acid and an ethylenically unsaturated monomer containing at least one primary hydroxl group cross-linked with a methoxyalkylmelamine.
Abstract: An improved photographic support, especially useful for color prints, is comprised of a paper base material having thereon a polyolefin coating containing a white pigment and an optical brightener, such as a mixture comprising inclusion compounds of certain fluorescent bis(benzoxazolyl)-stilbenes.
Abstract: Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.
Type:
Grant
Filed:
August 6, 1991
Date of Patent:
March 30, 1993
Assignee:
Eastman Kodak Company
Inventors:
Ralph B. Neilsen, Lan B. Thai, Hwei-ling Yau
Abstract: A soluble, chain extended gelatin having a high molecular weight and significantly higher viscosity at equivalent gelatin concentration compared to standard gelatin and significantly faster setting time is produced by preparing an aqueous gelatin composition containing from about 6% to about 18% dry weight of gelatin and from about 0.25 to about 5 millimoles of a bis-(vinyl sulfonyl) compound per 100 grams of gelatin, heating the composition at a temperature of from about 40 to about 60.degree.C. and at a pH of from about 4.5 to about 7 for from about one to about eight hours.
Abstract: Mono-acylated hydrazines are prepared in high yield by reaction of a hydrazine salt with an azole derivative of acyl halide in the presence of a strong base. Useful hydrazine salts include those of the formula RNHNH.sub.2 .multidot.HX, where R is alkyl, aryl, aralkyl, acyl, aroyl, heterocyclic or heteroaryl, and HX is a mineral or organic acid. Useful azole derivatives include those of the formula R'CO--A, where R' is alkyl, aryl, aralkyl, heterocyclic or heteroaryl and A is an azole radical such as pyrrole, imidazole, pyrazole, triazole, tetrazole, indole or benzimidazole.
Type:
Grant
Filed:
May 24, 1990
Date of Patent:
November 24, 1992
Assignee:
Eastman Kodak Company
Inventors:
Chang K. Kim, Francesco Debellis, Michael E. Campbell
Abstract: A method of heating dichloromethane laden streams to prevent discharge into the environment by contacting the laden stream with N,N-dialkyldithiocarbamate salt in the presence of oxygen and water.
Abstract: Disclosed is a shaped article comprising a continuous oriented thermoplastic polymer matrix having dispersed therein microbeads of a polymer which are at least partially bordered by void space, the microbeads being present in an amount of about 5%-50% weight based on the weight of said oriented thermoplastic, said void space occupying about 2%-60% by volume of said shaped article. Preferably, the microbeads are cross-linked to an extent they will be resilient and elastic at the orientation temperature, and are coated with a slip agent. The shaped article is preferably in the form of a sheet, fibers, or other molded article, and preferably has a relatively low specific gravity and whiteness.
Type:
Grant
Filed:
March 21, 1991
Date of Patent:
September 1, 1992
Assignee:
Eastman Kodak Company
Inventors:
Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glen C. Smith
Abstract: The present invention relates to a method of forming shaped articles having a continuous phase of an oriented thermoplastic polymer containing cross-linked polymer microbeads at least partially bordered by void space. The thermoplastic polymer in molten form is mixed with a plurality of the crosslinked polymer microbeads, and the mixture is then formed into a shaped article. The article is stretched in at least one direction to orient it. The orienting conditions and the character and quantity of crosslinked polymer microbeads is effective to form voids in the article at least bordering the microbeads on sides thereof in the direction(s) of orientation.
Type:
Grant
Filed:
December 11, 1990
Date of Patent:
August 25, 1992
Assignee:
Eastman Kodak Company
Inventors:
Larry K. Maier, Elizabeth K. Priebe, Jong S. Lee, Paul E. Woodgate, Glenn C. Smith
Abstract: A copolyester is synthesized by reacting a dialkyl ester of an aromatic dicarboxylic acid (e.g., dimethyl terephthalate) with ethylene glycol, low molecular weight poly(ethylene glycol) and a salt of a sulfonic acid-substituted aromatic dicarboxylate (e.g., sodium sulfoisophthalic acid) simultaneously in a first stage reaction in the presence of a phosphite or phosphate stabilizer. The intermediate product of the first stage is further reacted in a second stage in the presence of a polycondensation catalyst to obtain a random copolyester of the desired molecular weight. The copolyester is extruded to form a film which, after orientation and heat setting, has excellent clarity and is useful as a photographic film support. Aqueous processing of the film relaxes any core set or curl.
Type:
Grant
Filed:
January 25, 1991
Date of Patent:
August 11, 1992
Assignee:
Eastman Kodak Company
Inventors:
Carl T. Brozek, Robert C. Daly, Robert H. Fehnel, Constantine C. Petropoulos
Abstract: Imaging paper having randomly distributed fibers and uniformly dispersed throughout unexpanded synthetic thermoplastic polymeric microspheres, a method of preparation and a method of imparting an image thereto.
Type:
Grant
Filed:
August 27, 1990
Date of Patent:
June 30, 1992
Assignee:
Eastman Kodak Company
Inventors:
Bruce C. Campbell, Barry Crouse, Todd M. Spath
Abstract: Crosslinked conductive polymers, coating compositions and light sensitive elements containing at least one antistat layer where the cross-linked polymer is a copolymer of a vinylbenzene sulfonic acid and an ethylenically unsaturated monomer containing at least one primary hydroxyl group cross-linked with a hydrolyzed metal lower alkoxide.
Abstract: A method of preparing a coupler dispersion in gelatin by separating the auxiliary coupler solvent using a hydrophobic microporous membrane and contacting the opposite surface of the membrane with a coupler solvent.
Type:
Grant
Filed:
August 16, 1991
Date of Patent:
April 28, 1992
Assignee:
Eastman Kodak Company
Inventors:
Stephen P. Chen, Edgar P. Lougheed, Carl B. Richenberg