Abstract: The present invention relates to a system, apparatus, and process to reduce the oxidized mercury in an exhaust gas to elemental mercury and to prevent its reoxidation by congeneric components in the exhaust gas prior to the photometric measurement of said elemental mercury. In the process, the sample stream flows through a reactor heated to preferably about 800.degree. C. in which a stream of hydrogen is introduced directly into a hot portion thereof. The congeneric oxidized mercury species, i.e, HgCl.sub.2, and HgO are thermally reduced quantitatively to elemental mercury. The hydrogen reacts in situ with oxygen to form water vapor and with chlorine to form hydrochloride gas. The hydrochloride gas is effectively absorbed by the water vapor and consequently prevents the reoxidation of elemental mercury. The concentration of total mercury in a stream can then be determined by the intensity of radiation absorbed by a UV spectrometer.

Abstract: This invention relates to the design and operation of paired subsurface flow constructed wetlands in which significant improvements in wastewater treatment are possible. These improvements are brought about by coupling paired subsurface flow wetlands and using reciprocation, whereby adjacent cells are sequentially and recurrently drained and filled using either gravity, mechanical pumps, U-tube air-lifts and/or a combination thereof. This fill and drain technique turns the entire wetland area into a biological reactor, complete with anoxic, anaerobic and aerobic environments. The frequency, depth and duration of the fill and drain cycle can be adjusted to control redox conditions for specific biologically mediated reactions including, but not limited to, nitrification, denitrification, sulfate reduction, and methanogenesis. Emissions of noxious gases such as hydrogen sulfide and mentane can be minimized.

Abstract: The inclusion of certain organic hydroxy acids, most notably citric acid, in the iron sulfate formulations of at least one prior art hydrophilic polymer delivery system followed by drying and crushing the product into particles has been found to significantly improve the efficiency and ease of application of iron source fertilizer materials for iron-sensitive plants growing on iron-deficient soils for periods exceeding one year. The dried particles most preferably may be selectively metered into soil in or near the seed row as a band application at or prior to planting or spot placed in the root zone of growing plants in soil. The dry band absorbs soil moisture to provide a unique environment which restricts contact of soluble iron fertilizers with the soil and provides for complexation of iron in the formulation with organic hydroxy acids also contained in the formulation, thereby minimizing the extent of chemical reactions with the soil that reduce the availability of the applied iron to plant roots.

Abstract: The present invention relates to methods and means including a process and system for producing an elemental-mercury-free reference flue gas which is used to obtain background photometric measurements thereby eliminating the photometric interferences of flue gas components to the photometric measurement of mercury. In the process, elemental mercury is selectively removed from a portion of a gaseous stream (the reference portion) and the intensity of radiation absorbed is measured by a UV spectrometer on the resulting mercury-free reference gas, and thereafter the concentration of mercury in the remainder of the gaseous stream is determined through utilization of the ratio of the transmitted radiation of the mercury-containing flue gas with respect to that of the mercury-free reference portion of the gaseous stream. The mercury concentration can then be determined without interference by other absorbing moieties at 254 nm in the flue gas.

Abstract: A process for effectively and economically separating an ionic component such as acid from a nonionic component such as sugar in polar solutions using ion exclusion technology whereby the viability of using hydrolysis to convert wood and agricultural waste products such as corn stover into fuel alcohol is substantially effected. Underlying the gist of this invention are newly discovered methods by which dispersion, caused by shrinkage of resin within ion exclusion columns, is controlled resulting in operation of such columns, over a wide range of process conditions to produce separate and distinct elution profiles for the acid and sugar. Successful operation of these new ion exclusion methods, techniques, and systems can replace lime precipitation which currently is being used in acid hydrolysis processing.

Abstract: The inclusion of certain organic hydroxy acids, most notably citric acid, in the iron sulfate formulations of at least one prior art hydrophilic polymer delivery system followed by drying and crushing the product into particles has been found to significantly improve the efficiency and ease of application of iron source fertilizer materials for iron-sensitive plants growing on iron-deficient soils for periods exceeding one year. The dried particles most preferably may be selectively metered into soil in or near the seed row as a band application at or prior to planting or spot placed in the root zone of growing plants in soil. The dry band absorbs soil moisture to provide a unique environment which restricts contact of soluble iron fertilizers with the soil and provides for complexation of iron in the formulation with organic hydroxy acids also contained in the formulation, thereby minimizing the extent of chemical reactions with the soil that reduce the availability of the applied iron to plant roots.

Abstract: A process for effectively and economically separating an ionic component such as acid from a nonionic component such as sugar in polar solutions using ion exclusion technology whereby the viability of using hydrolysis to convert wood and agricultural waste products such as corn stover into fuel alcohol is substantially effective. Underlying the gist of this invention are newly discovered methods by which dispersion, caused by shrinkage of resin within ion exclusion columns, is controlled resulting in operation of such columns, over a wide range of process conditions to produce separate and distinct elution profiles for the acid and sugar. Successful operation of these new ion exclusion methods, techniques, and systems can replace lime precipitation which currently is being used in acid hydrolysis processing.

Abstract: A process for effectively and economically separating an ionic component such as acid from a nonionic component such as sugar in polar solutions using ion exclusion technology whereby the viability of using hydrolysis to convert wood and agricultural waste products such as corn stover into fuel alcohol is substantially effected. Underlying the gist of this invention are newly discovered methods by which dispersion, caused by shrinkage of resin within ion exclusion columns, is controlled resulting in operation of such columns, over a wide range of process conditions to produce separate and distinct elution profiles for the acid and sugar. Successful operation of these new ion exclusion methods, techniques, and systems can replace lime precipitation which currently is being used in acid hydrolysis processing.

Abstract: A process for effectively and economically separating an ionic component such as acid from a nonionic component such as sugar in polar solutions using ion exclusion technology whereby the viability of using hydrolysis to convert wood and agricultural waste products such as corn stover into fuel alcohol is substantially effective. Underlying the gist of this invention are newly discovered methods by which dispersion, caused by shrinkage of resin within ion exclusion columns, is controlled resulting in operation of such columns, over a wide range of process conditions to produce separate and distinct elution profiles for the acid and sugar. Successful operation of these new ion exclusion methods, techniques, and systems can replace lime precipitation which currently is being used in acid hydrolysis processing.

Abstract: New techniques and means for their utilization are described for substantially improving gas to liquid transfer including aeration of hydroelectric project tailwaters and treatment of sewage sludge and sewage treatment effluent or other wastewaters. Liquid flow is directed over an infuser device to separate the liquid into a plurality of free-falling curtains disposed to impinge upon a collection pool therebeneath wherein a substantial number of gas bubbles entrained by any particular curtain are acted upon by successive impingements of downstream curtains to effect turbulent interaction, shearing, and reentrainment of such bubbles and substantially increase the residence time thereof in the resulting recombined flow.

Abstract: Improved release profiles which can, for the first time, be customized to match requirements of systems including crop nutrient uptake are realized by providing a plurality of heterogeneous particles comprised of water-soluble constituents set in a matrix of water-insoluble materials, and further providing a continuous homogeneous barrier of same, or a different water-insoluble material, juxtaposed the peripheral surface of each such heterogeneous particle. A first alternate embodiment includes forming in situ reaction products to reduce the specific gravity of such heterogeneous particles. In a second alternate embodiment, there is substituted for all, or a portion of such water-soluble material, organic media comprised primarily of composted poultry litter wherein soluble iron values remain available for substantial periods of time without incorporating or utilizing expensive conventional synthetic chelating agents.

Abstract: New techniques and means for their utilization are described for substantially improving gas to liquid transfer including aeration of hydroelectric project tailwaters and treatment of sewage sludge and sewage treatment effluent or other wastewaters. Liquid flow is directed over an infuser device to separate the liquid into a plurality of free-falling curtains disposed to impinge upon a collection pool therebeneath wherein a substantial number of gas bubbles entrained by any particular curtain are acted upon by successive impingements of downstream curtains to effect turbulent interaction, shearing, and reentrainment of such bubbles and substantially increase the residence time thereof in the resulting recombined flow.

Abstract: The present invention relates to techniques for successful storage, handling, shipment, and utilization of an inexpensive, poor-quality form of by-product ammonium sulfate (AS). Such AS undergoes rapid and severe caking almost immediately after production because the crystals are too small and often contain excessive moisture. Such rapid and severe caking renders the AS nearly impossible to move or use "as is" without expensive crushing and screening of the material. Accordingly, such poor-quality AS is often used in production of solution or suspension fertilizers. In the present invention, long-storing, non-caking, highly-flowable AS fines are produced by practicing an unconventional technique of mixing the attapulgite gelling clays normally used in production of such suspensions directly with the fresh, poor-quality, caking-type ammonium sulfate fines and storing the resulting improved AS fines dry until needed for production of suspensions or other uses.

Abstract: A process for effectively and economically separating an ionic component such as acid from a nonionic component such as sugar in polar solutions using ion exclusion technology whereby the viability of using hydrolysis to convert wood and agricultural waste products such as corn stover into fuel alcohol is substantially effective. Underlying the gist of this invention are newly discovered methods by which dispersion, caused by shrinkage of resin within ion exclusion columns, is controlled resulting in operation of such columns, over a wide range of process conditions to produce separate and distinct elution profiles for the acid and sugar. Successful operation of these new ion exclusion methods, techniques, and systems can replace lime precipitation which currently is being used in acid hydrolysis processing.

Abstract: An improved flowmeter system is described, together with circuitry, hardware, and techniques for its utilization for determining the rate of flow of fluids in conduits at a situs substantially remote from the information gathering and analysis situs. Arrangements are provided for utilization of the system in conduits, including deep water wells, having diameters as small as 2 inches, and wherein very low flowrates of liquid therein can be quite accurately measured to depths in the range of hundreds to thousands of feet.

Abstract: Inclusion of a certain finely powdered by-product of the citrus fruit processing industry, notably a waste product consisting of processed peel, stems, seeds, and pulp, with relatively inexpensive, finely-powdered soluble iron sulfate [FeSO.sub.4 or Fe.sub.2 (SO.sub.4).sub.3 ] significantly improves the efficiency of iron source fertilizer materials for iron-sensitive plants growing on iron-deficient soils and can maintain supply of available iron to growing plants for substantially extended periods of time. These compositions may be band applied in powdered or granular form in or near the seed row at or prior to planting or spot placed in the root zone of growing plants in soil.

Abstract: An improved flowmeter system is described, together with circuitry, hardware, and techniques for its utilization for determining the rate of flow of fluids in conduits at a situs substantially remote from the information gathering and analysis situs. Arrangements are provided for utilization of the system in conduits, including deep water wells, having diameters as small as 2 inches, and wherein very low flowrates of liquid therein can be quite accurately measured to depths in the range of hundreds to thousands of feet.