Abstract: A teflon-bonded thin, flexible .beta."-Al.sub.2 O.sub.3 solid electrolyte parator is provided for use in a high temperature electrochemical cell including a sodium-lead alloy anode (Na.sub.0.9 Pb.sub.0.1) and an FeS.sub.2 cathode.
Type:
Grant
Filed:
June 10, 1991
Date of Patent:
October 13, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: Cathode or anode electrodes are prepared for high temperature, rechargeable olten salt batteries using 80 to 90 weight percent of their respective active powdered components mixed with 10 to 20 weight percent powdered electrolyte salt. The powdered electrode mixture is then spread evenly onto an electrical current collector sheet or foil. The current collector containing the electrode mixture is then heated under a dry inert gas atmosphere to a temperature at or near the melting point of the electrolyte salt.
Type:
Grant
Filed:
August 1, 1990
Date of Patent:
May 19, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: An improved scandate cathode having an increased emission density is prepared from a porous tungsten billet that has been impregnated with Ba.sub.3 Al.sub.2 O.sub.6 by coating the top surface of the impregnated billet with a mixture of Sc.sub.6 WO.sub.12,Sc(WO.sub.4).sub.3, and W in the mole ratio of 1:3:2, heating the billet to about 1000.degree. C. in a vacuum to cause BaWO.sub.4 and Sc to form in the billet in a molar ratio of 1:1, removing the billet and cleaning in a jewelers lathe, and preparing the billet for a cathode environment.
Type:
Grant
Filed:
July 17, 1991
Date of Patent:
May 19, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Louis F. Branovich, Gerard L. Freeman, Donald W. Eckart
Abstract: A high temperature molten salt electrochemical cell including an electrode tack assembly sealed in a containment vessel is provided for use in testing experimental high temperature molten salt battery chemistries in which the electrode stack assembly uses a spring loaded design that maintains electrical contact between current collectors and electrodes by compensating for the electrode contraction and expansions observed during the heating and cooling cycles.
Type:
Grant
Filed:
July 30, 1990
Date of Patent:
May 19, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: A superconducting film of HoBa.sub.2 Cu.sub.3 O.sub.7-x on a substrate is tained from a mixture containing stoichiometric amounts of Ho.sub.2 O.sub.3, BaCO.sub.3 and CuO powders by a method including the steps of(A) processing the powder mixture to an average particle size of about 2 to 3 .mu.m,(B) adding about three grams of the powder to about 25 cc of an organic dispersant,(C) depositing the powder in the organic dispersant on the substrate by electrophoresis in electric fields of about 100 to about 1000 volts/cm for about 3 to about 15 minutes to obtain superconducting films having a thickness of about 5 to about 25 .mu.m; and(D) sintering and annealing in oxygen.
Type:
Grant
Filed:
August 26, 1991
Date of Patent:
May 5, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Arthur Tauber, Robert D. Finnegan, Michelle A. Dornath Mohr, Frank A. McBride
Abstract: A high temperature molten salt bipolar stacked module battery is provided which electrolyte creepage between cells is shielded and compression maintained on the cell stacks during thermal cycling. In addition, the modular design of the individual cells lends this construction to high voltage battery make-up.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
March 24, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: The use of electrically conducting oxides, that permit the diffusion of hogen through the electrode material, as electrodes in the air-or H-sweeping of quartz.
Type:
Grant
Filed:
October 1, 1990
Date of Patent:
February 11, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: An improved scandate cathode is made from a hollow cylinder of a metal that ill not react with Sc.sub.2 (WO.sub.4).sub.3. The first step in making such a cathode is to insert a metal plug at the bottom of the cylinder to a height that will allow the remaining volume of the cylinder to be filled with the reactants WO.sub.3 and Sc.sub.2 O.sub.3. Next, the reactants are heated in a vacuum to about 1100.degree. C. to form the reaction product Sc.sub.2 (WO.sub.4).sub.3. The plug is then removed from the cylinder, the cylinder is inverted, and BaH.sub.2 is added to the volume of the cylinder that had been occupied by the plug. Finally, the cylinder is heated to decompose the BaH.sub.2.
Type:
Grant
Filed:
April 22, 1991
Date of Patent:
December 24, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Louis E. Branovich, Donald W. Eckart, Gerard L. Freeman, Bernard Sith
Abstract: A high temperature molten salt thermal cell is provided where the active hodic materials are ternary metal sulfides as for example, BaNiS.sub.2, BaFeS.sub.2, and BaCoS.sub.2.
Type:
Grant
Filed:
December 10, 1990
Date of Patent:
September 3, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: Contamination in the atmosphere is sensed and identified using unsealed d mode resonators and a means to clean the resonators in an ongoing method to measure contamination induced frequency change with time, while compensating for temperatures induced frequency shifts.
Type:
Grant
Filed:
May 25, 1990
Date of Patent:
August 27, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: An improved high energy product radially oriented toroidal magnet is made om an iron cylinder toroid by a method including the steps of:(A) sandwiching the iron cylinder toroid between two disc toroids of a superconductive material at a temperature above the transition temperature of the superconductive material at which temperature the superconductive material does not have superconducting properties and therefor cannot affect the magnetic state of the iron toroid,(B) aligning the iron radially with a small applied field so that flux lines go through the toroidal magnet in a radial direction and in response to which the magnetic dipoles of the iron align themselves with those flux lines,(C) cooling the superconductive material to below the transition temperature of the superconductive material thereby trapping magnetic flux in the iron cylinder toroid, and(D) removing the small applied field from the iron cylinder toroid that does not affect the radial magnetization of the iron as the radial magnetization of
Type:
Grant
Filed:
April 30, 1990
Date of Patent:
August 20, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: An improved high temperature rechargeable molten salt battery is obtained the use of alkaline earth metal sulfides as cathode additives in transition metal sulfide cathodes in these batteries.
Type:
Grant
Filed:
September 11, 1990
Date of Patent:
July 30, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: A long life high current density cathode is made from a mixture of aluminum xide and tungsten oxide powders by processing the powders into a fused powder, adding barium hydride to the fused powder, inverting the fused powder and heating to decompose the barium hydride and obtain barium metal.
Type:
Grant
Filed:
November 6, 1990
Date of Patent:
June 11, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Louis E. Branovich, Gerard L. Freeman, Donald W. Eckart, Bernard Smith
Abstract: A high temperature rechargeable molten salt cell is provided using a lith-aluminum (48 atomic percent Li) alloy as the anode, a eutectic mixture of lithium chloride (59 mole percent) and potassium chloride (41 mole percent) with a melting point of 352.degree. C. as the electrolyte and barium nickel sulfide (BaNiS.sub.2) as the cathode active material.
Type:
Grant
Filed:
July 5, 1990
Date of Patent:
April 30, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: Freestanding, flexible, heterogeneous composites of insulating polymeric m containing relatively small percentages of an electrically conductive polymer wherein the conductive polymer exists as the dispersed phase are made by dissolving the insulating polymeric material and less than 15 percent by weight of the electrically conductive material in a solvent, casting the resulting solution onto a suitable substrate and slowly evaporating the solution at an elevated temperature.
Type:
Grant
Filed:
November 3, 1989
Date of Patent:
August 6, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
William L. Wade, Jr., Robert J. Mammone, Michael Binder
Abstract: A quartz surface is prepared for sweeping by a method including the steps : f(A) cleaning the quartz surface,(B) depositing a metal electrode onto the cleaned quartz surface, and(C) creating periodic openings in the metal electrode in such a manner that the metal is not disconnected by the arrangement of openings and all the metal is at one potential.
Type:
Grant
Filed:
September 11, 1989
Date of Patent:
August 6, 1991
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: An optical quality film is transferred from a master optical surface to a condary substrate by means of a replication technique using a master optical surface as a mold.
Type:
Grant
Filed:
September 21, 1989
Date of Patent:
December 3, 1991
Assignee:
The United States of Amercia as represented by the Secretary of the Army
Abstract: The surface leakage on a III-V semiconductor is reduced by selectively grng a mixed oxide on the surface of the semiconductor to passivate the semiconductor and reduce the surface leakage.
Type:
Grant
Filed:
April 15, 1991
Date of Patent:
April 7, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: An electrochemical cell is provided that delivers high power pulses, the l including poly 3-methylthiophene as the cathode, a member of the group consisting of Li(SO.sub.2).sub.3 AlCl.sub.4, 1.0M LiAlCl.sub.4 --SOCl.sub.2 and 1.0M LiAlCl.sub.4 --SO.sub.2 Cl.sub.2 as the electrolyte, and lithium as the anode.
Type:
Grant
Filed:
June 14, 1991
Date of Patent:
May 5, 1992
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: A lithium ion rechargeable intercallation cell is provided including a liated graphite anode, a lithiated oxide cathode, and a solution of a lithium salt in a solvent that cycles both the lithiated graphite anode and the lithiated oxide cathode as the electrolyte.
Type:
Grant
Filed:
December 10, 1990
Date of Patent:
July 7, 1992
Assignee:
The United States of America as represented by the Secretary of the Army