Patents Represented by Attorney, Agent or Law Firm Sarah Meeks Roberts
  • Patent number: 5968724
    Abstract: This invention relates to silver halide photographic element comprising a silver halide emulsion chemically sensitized in the presence of an isothiazolin-one compound represented by the formula ##STR1## wherein R.sup.1 is a substituent; and Z is a substituted or unsubstituted saturated ring, wherein the isothiazolin-one compound was added after precipitation of the emulsion.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: October 19, 1999
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Roger L. Klaus, Roger L. Lok, Jerzy Z. Mydlarz, Brian S. White
  • Patent number: 5962656
    Abstract: A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formulaCOUP--T.sup.1 --T.sup.2 --(T.sup.3).sub.b --PUGwhereinCOUP is a coupler moiety having a coupling site to which T.sup.1 is attached;T.sup.1 and T3 are timing or linking groups;T.sup.2 is an indazole timing or linking group which, after release from T.sup.1, functions by electron transfer down a conjugated chain to release T.sup.3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T.sup.1 and *** denotes the point of attachment to T.sup.3 or PUG;R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring;V is independently a substituent group as further defined;q is 0, 1, 2, 3 or 4;b is 0 or 1; andPUG is a photographically useful group.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: October 5, 1999
    Assignee: Eastman Kodak Company
    Inventors: William James Begley, Teh Hsuan Chen, Donald Singleton, Jr., Frank Dino Coms
  • Patent number: 5958664
    Abstract: The present invention relates to a new coupler which is capable of releasing a development accelerator having the formula: ##STR1## wherein COUP is a coupler moiety,T is a timing group and n is 0, 1 or 2,A is a group capable of being adsorbed to the silver halide surface,L is a linking group and r is 0 or 1, andR.sub.1 and R.sub.2 are independently selected from an alkyl group, substituted or unsubstituted, and an aryl group, substituted or unsubstituted.The present invention also concerns a photographic silver halide recording material containing such a coupler and further relates to a process for processing such a material.The invention provides a new DARC compound showing improved speed increase without undue fog formation.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: September 28, 1999
    Assignee: Eastman Kodak Company
    Inventors: Siu-Chung Tsoi, Peter J. Twist, David T. Southby
  • Patent number: 5945270
    Abstract: This invention relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising an organomercapto Au(I) complex having the formula?(M--SOL).sub.n --A--S--Au--S--A--(SOL--M).sub.n !Mwherein M is a cationic counterion;SOL is a solubilizing group:A is a substituted or unsubstituted divalent organic linking group;and n is 1 to 4 and wherein the compound is symmetrical.It further relates to a method of preparing a silver halide emulsion utilizing said organomercapto Au(I) complexes.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: August 31, 1999
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, Weimar W. White, Brian P. Cleary
  • Patent number: 5939245
    Abstract: This invention relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising a Au(I) compound having the formula wherein Z is a substituted or unsubstituted alkyl, aryl, alkylaryl, or heterocyclic group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently substituted or unsubstituted alkyl, aryl, alkylaryl, or heterocyclic groups, or one or both of R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4, may independently combine to form a nitrogen containing ring with the nitrogen to which they are attached.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: August 17, 1999
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, Weimar W. White, Melanie W. Marshall
  • Patent number: 5935771
    Abstract: This invention relates to a method of preventing fog formation in a silver halide photographic element, said method comprising bringing a silver halide developer solution, or a solution preceding a silver halide developer solution, into contact with a cyanide scavenger by a method other than the seasoning out of the cyanide scavenger from a sensitized silver halide photographic element.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: August 10, 1999
    Assignee: Eastman Kodak Company
    Inventors: Terrence Robert O'Toole, Daniel Lawrence Kapp, Kenneth George Harbison, Frank Anthony Pettrone, Kenneth Don Fowler
  • Patent number: 5932407
    Abstract: A color photographic element comprising a film support and a first radiation-sensitive layer further includes an oxidized developer-scavenging naphtholic coupler that is substantially immobilized in the element but forms a dye that can be removed from the material during photographic processing. The naphtholic coupler, which comprises a dye-forming moiety and a ballasted, substantially photographically inert coupling-off moiety, has the structure ##STR1## where R.sup.1 and R.sup.2 each independently represents hydrogen, an alkyl group, an alkoxyalkyl group, or a hydroxyalkyl group, R.sup.1 and R.sup.2 together containing a total of up to 4 carbon atoms; R.sup.3 represents hydrogen, halo, or an alkoxy, an alkylcarbonamido, an alkylsulfonamido, a carbamoyl, or a sulfamoyl group containing up to 4 carbon atoms; R.sup.1, R.sup.2, and R.sup.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: August 3, 1999
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Stephen P. Singer, Allan F. Sowinski
  • Patent number: 5928851
    Abstract: The present invention describes an image dye-forming coupler of formula (I) ##STR1## wherein L is an oxymethylene or oxycarbonyl group; n is 0 or 1; COUP is a coupler moiety and R.sub.1 and R.sub.2 are the same or different and are groups selected such that(a) together with the nitrogen atom a good leaving group is formed;(b) at least one of them contains a PUG linked to an electrophilic center (E); and(c) neither R.sub.1 nor R.sub.2 is a hydrogen atom wherein the coupler is a DIAR coupler from which inhibitor is released from a coupling-off group after a timed delay which results from an additional reaction step. Such delay permits control over the time of release, rate of release and rate of diffusion of a photographically useful group (PUG) without altering the nature of the PUG itself.A method of preparing the coupler is also described wherein the two parts of the molecule can be built up separately and combined in a single reaction allowing ready access to a large variety of possible structures.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: July 27, 1999
    Assignee: Eastman Kodak Company
    Inventor: Philip Arthur Allway
  • Patent number: 5925507
    Abstract: A highly useful photographic film base containing a miscible blend of is polyester containing at least 30 weight percent cyclohexylene dimethanol, CHDM/EG-PE, and a polycarbonate containing bisphenols, BP-PC, in specified proportions. Photographic elements prepared with this film base have a lesser tendency to take core-set and post process curl than do elements prepared with polyester containing cyclohexylene dimethanol, CHDM/EG-PE, film base.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: July 20, 1999
    Assignee: Eastman Kodak Company
    Inventors: Dennis J. Massa, James M. O'Reilly, Wen-Li A. Chen
  • Patent number: 5914226
    Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a dithiolone 1-oxide compound represented by the following formula: ##STR1## wherein b is C(O), C(S), C(Se), CH.sub.2 or (CH.sub.2).sub.2, and R.sup.1 and R.sup.2 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, sulfo groups, or amino groups, or R.sup.1 and R.sup.2 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; and a sulfinate compound.
    Type: Grant
    Filed: September 11, 1997
    Date of Patent: June 22, 1999
    Assignee: Eastman Kodak Company
    Inventor: Roger Lok
  • Patent number: 5912111
    Abstract: This invention relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising a Au(I) compound having the formula ##STR1## wherein Z is a substituted or unsubstituted alkyl, aryl, alkylaryl, or heterocyclic group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently substituted or unsubstituted alkyl, aryl, alkylaryl, or heterocyclic groups, or one or both of R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4, may independently combine to form a nitrogen containing ring with the nitrogen to which they are attached.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: June 15, 1999
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, Weimar W. White, Melanie W. Marshall
  • Patent number: 5912112
    Abstract: A photographic element comprising a support having situated thereon a silver halide emulsion layer, said emulsion layer comprising a compound of the formula:Z--S--Au(I)--S--Q (I)whereinZ represents an alkyl, aryl, or heterocyclic group; andQ represents a heterocyclic group wherein S and Q together represent a mesoionic group.
    Type: Grant
    Filed: March 5, 1998
    Date of Patent: June 15, 1999
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, Weimar W. White, Melanie W. Marshall
  • Patent number: 5912110
    Abstract: A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula ##STR1## wherein COUP is a coupler moiety having a coupling site to which T.sup.1 is attached;T.sup.1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated chain, or by nucleophilic displacement reaction, to release from HETERO;HETERO is a heterocyclic group containing at least two heteroatoms independently selected from oxygen, nitrogen, or sulfur, wherein one of the heteroatoms is directly attached to T.sup.1 ;R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; andPUG is a photographically useful group.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: June 15, 1999
    Assignee: Eastman Kodak Company
    Inventors: William James Begley, Teh Hsuan Chen, Frank Dino Coms, Donald Singleton, Jr.
  • Patent number: 5879872
    Abstract: This invention relates to a silver halide photographic element comprising a silver halide emulsion precipitated and/or chemically sensitized in the presence of an sulfenimide compound represented by the formula: ##STR1## wherein M represents the atoms necessary to form, with R.sup.1 and R.sup.2, a five or six-membered ring or a multiple ring system; w is 1 or 0, wherein when w is 0, R.sup.1 and R.sup.2 are independently substituted or unsubstituted aliphatic, aromatic or heterocyclic groups, and when w is 1, R.sup.1 and R.sup.2 are independently carbonyl or sulfonyl groups; R.sup.3 is independently a substituted or unsubstituted aliphatic, aromatic or heterocyclic group and x is 0 or 1.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: March 9, 1999
    Assignee: Eastman Kodak Company
    Inventors: Franklin D. Saeva, Roger L. Klaus, Jerzy Z. Mydlarz
  • Patent number: 5871899
    Abstract: A silver halide color photographic element comprising a support, a silver halide emulsion and poly(alkylene oxide)s wherein greater than 50 percent of the poly(alkylene oxide)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini; and wherein the poly(alkylene oxide)s have a molecular weight ranging substantially between 1700 and 6000 AMU.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: February 16, 1999
    Assignee: Eastman Kodak Company
    Inventors: David A. Dickinson, George J. Burgmaier, Thomas R. Welter
  • Patent number: 5858640
    Abstract: This invention provides a thermally processable imaging element comprising a support and a thermographic or photothermographic imaging layer, said imaging layer comprising a sulfenimide compound represented by the formula: ##STR1## wherein M represents the atoms necessary to form, with R.sup.1 and R.sup.2, a five or six-membered ring or a multiple ring system; w is 1 or 0, wherein when w is 0, R.sup.1 and R.sup.2 are independently substituted or unsubstituted aliphatic, aromatic or heterocyclic groups, and when w is 1, R.sup.1 and R.sup.2 are independently carbonyl or sulfonyl groups; R.sup.3 is independently a substituted or unsubstituted aliphatic, aromatic or heterocyclic group and x is 0 or 1.In one embodiment the thermally processable imaging element comprises:(a) photographic silver halide, and(b) an image-forming combination comprising(i) an organic silver salt oxidizing agent, with(ii) a reducing agent for the organic silver salt oxidizing agent.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: January 12, 1999
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Cowdery-Corvan, Roger L. Klaus, Franklin D. Saeva
  • Patent number: 5834604
    Abstract: A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the element further comprising a photographic coupler represented by the formulaCOUP--(T.sup.1).sub.b --T.sup.2 --(T.sup.3).sub.c --PUGwherein the substituents are as defined in the specification.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: November 10, 1998
    Assignee: Eastman Kodak Company
    Inventors: William James Begley, Frank Dino Coms, Teh-Hsuan Chen, Donald Singleton, Jr.
  • Patent number: 5817809
    Abstract: A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the element further comprising a photographic coupler represented by the formulaCOUP--(T.sup.1).sub.b --T.sup.2 --(T.sup.3).sub.c --PUGwhereinCOUP is a coupler moiety having a coupling site to which T.sup.1 is attached;T.sup.1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated or unconjugated chain, or by a nucleophilic displacement reaction, to release T.sup.2 ;T.sup.2 is a triazole timing or linking group which, after release from T.sup.1, functions by a nucleophilic displacement reaction to release T.sup.3 or PUG and is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T.sup.1 and *** denotes the point of attachment to T.sup.3 or PUG;R.sup.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: October 6, 1998
    Assignee: Eastman Kodak Company
    Inventors: William James Begley, Frank D. Coms, Teh-Hsuan Chen
  • Patent number: 5811226
    Abstract: This invention relates to a method of preventing fog formation in a silver halide photographic element, said method comprising bringing a silver halide developer solution, or a solution preceding a silver halide developer solution, into contact with a cyanide scavenger by a method other than the seasoning out of the cyanide scavenger from a sensitized silver halide photographic element.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: September 22, 1998
    Assignee: Eastman Kodak Company
    Inventors: Terrence Robert O'Toole, Daniel Lawrence Kapp, Kenneth George Harbison, Frank Anthony Pettrone, Kenneth Don Fowler
  • Patent number: 5789143
    Abstract: This invention relates to a silver halide color photographic element comprising a support, a silver halide emulsion and poly(thioether)s wherein greater than 50 percent of the poly(thioether)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini and wherein the poly(thioether)s have a molecular weight greater than 800.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: August 4, 1998
    Assignee: Eastman Kodak Company
    Inventors: George J. Burgmaier, David A. Dickinson, Robert A. Guistina