Patents Represented by Attorney, Agent or Law Firm Sarah Meeks Roberts
  • Patent number: 5536625
    Abstract: This invention provides an accelerator for peracid bleaches used for bleaching silver halide photographic elements. The accelerator is a complex of ferric (Fe III) ion and a 2-pyridinecarboxylic acid or a 2,6-pyridinecarboxylic acid. The accelerator may be contained in the bleaching solution, a solution preceding the bleaching solution or in the photographic elements themselves.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: July 16, 1996
    Assignee: Eastman Kodak Company
    Inventors: John M. Buchanan, Stuart T. Gordon, Keith H. Stephen, Richard P. Szajewski, Sidney J. Bertucci
  • Patent number: 5536633
    Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a sulfur donating compound, and a sulfinate compound represented by Formula (I)Z--SO.sub.2 M.sup.1 (I)wherein Z is a non-metallic aryl, alkyl or heterocyclic group, and M is a cationic counter ion;and wherein the sulfur donor is not a thiosulfonate or a diamino disulfide; and a method of making the emulsion.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: July 16, 1996
    Assignee: Eastman Kodak Company
    Inventor: Roger Lok
  • Patent number: 5529890
    Abstract: A stabilizing bath that provides image stability and uniform drainage of excess fluid to prevent drying spots and that reduces or eliminates the formation of residue on the base side of color negative films is comprised of hexamethylenetetramine, a nonionic polyethoxylated surfactant, and an anionic sulfate or sulfonate surfactant. The stabilizing bath is used as the final processing bath prior to drying. The nonionic surfactant provides uniform drainage of excess fluid and the anionic sulfate or sulfonate surfactant functions to reduce or eliminate the formation of residue on the base side of color negative films.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: June 25, 1996
    Assignee: Eastman Kodak Company
    Inventors: Hugh G. McGuckin, John S. Badger, Michael W. Orem
  • Patent number: 5521055
    Abstract: In photographic processing apparatus, by-products are produced due to the chemical reactions which occur during the processing of photographic materials. It is known to remove some of these by-products in accordance with the area of photographic material processed and a knowledge of the average level of production of the by-products. This leads to inaccuracies in maintaining a fixed level of the by-products in the processing solutions. Described herein is a method of controlling a subsystem which removes by-products from the processing solutions by using data relating to the exposure given to a photographic material in the printing stage of the processing apparatus to calculate the amount of by-products produced so that they can be exactly removed from the processing solutions.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: May 28, 1996
    Assignee: Eastman Kodak Company
    Inventor: Christopher B. Rider
  • Patent number: 5508150
    Abstract: A method of processing an image wise exposed and developed silver halide photographic element comprising bleaching the photographic element in a bleaching or bleach-fixing solution containing as the primary bleaching agent a complex of ferric ion and a tridentate or a tetradentate ligand, and then processing the photographic element in a solution containing a chelating compound represented by Formula IHOOC(CH.sub.2).sub.m (X) ((CH.sub.2).sub.n COOH).sub.2 (I)whereX is N, or C--OH;n and m are independently 0, 1, or 2; andM is a cationic ion.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: April 16, 1996
    Assignee: Eastman Kodak Company
    Inventors: Mary E. Craver, Janet M. Huston, Robert J. Opitz
  • Patent number: 5499488
    Abstract: A plurality of different materials which are required for use in a process and which are to be kept separate up to a predetermined stage in the process are supplied with each different material being encapsulated within a plurality of discrete shells, the shells serving to keep the different materials separate from each other. The shells for the different materials are distinguishable from each other so as to permit subsequent sorting of the shells into batches of shells all containing the same material.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: March 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Andrew Green, Paul C. Ward
  • Patent number: 5491050
    Abstract: A method of processing an exposed originating silver halide color photographic element comprising developing the photographic element in a color devoloper containing a p-phenylenediamine color developing agent in the presence of a 1-phenyl pyrazolidin-3-one compoundwherein the originating silver halide photographic element comprises a radiation sensitive emulsion in reactive association with a development inhibitor releasing compound and containing a silver halide grain population comprised of grains comprising at least 50 mole percent silver chloride, based on total silver forming the grain population projected area, wherein at least 50 percent of total grain projected area is accounted for by intrinsically stable silver halide tabular grains(1) bounded by {100} major faces having adjacent edge ratios of less than 10 and(2) each having an average aspect ratio of at least 2, and wherein the silver halide content of the photographic element comprises at least 50 mole % silver chloride and no more than 2 mole %
    Type: Grant
    Filed: February 9, 1994
    Date of Patent: February 13, 1996
    Assignee: Eastman Kodak Company
    Inventors: Thomas B. Brust, Sharon Gould, James E. Sutton, Richard P. Szajewski
  • Patent number: 5478703
    Abstract: A method of fixing a developed photographic silver halide material comprising at least 2 silver halide layers sensitized to different regions of the spectrum, comprising placing the material in face-to-face contact with a fixer sheet in the presence of a processing solution and a silver halide solvent which forms a solubilized silver halide species from the undeveloped areas of the material, wherein the fixer sheet contains reducing means capable of forming metallic silver therein from the solubilized silver halide.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: December 26, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael J. Simons
  • Patent number: 5464728
    Abstract: This invention provides a method of processing a developed high iodide color silver halide photographic element by bleaching the element with a peracid bleach and fixing the element with a fixer containing sodium cation and thiosulfate, wherein the amount of ammonium ion in the fixer is less than 1.4M.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: November 7, 1995
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, John M. Buchanan
  • Patent number: 5460924
    Abstract: This invention provides an accelerator for peracid bleaches used for bleaching silver halide photographic elements. The accelerator is a complex of ferric (Fe III) ion and a 2-pyridinecarboxylic acid or a 2,6-pyridinecarboxylic acid. The accelerator may be contained in the bleaching solution, a solution preceding the bleaching solution or in the photographic elements themselves.
    Type: Grant
    Filed: April 20, 1994
    Date of Patent: October 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: John M. Buchanan, Stuart T. Gordon, Keith H. Stephen, Richard P. Szajewski, Sidney J. Bertucci
  • Patent number: 5451491
    Abstract: A method of desilvering an imagewise and developed color silver halide element, said method comprising bleaching the photographic element with a peracid bleach and subsequently contacting the photographic element with a fixer solution comprising thiosulfate anion and sodium cation;wherein the Molar-minute fixing Time is less than about 0.2 Molar-minutes.times.m.sup.2 /g Ag.times.the grams of incorporated silver per square meter of the photographic element.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, John M. Buchanan
  • Patent number: 5445925
    Abstract: A color image can be obtained from a color photographic element by multiple color development steps. The first color development is carried out in the usual manner after imagewise exposure. The second color development step is carried out after bleaching with a rehalogenating bleaching agent, and is used to develop only rehalogenated silver halide. This specific development is possible by either using a chloride rehalogenating agent in the bleaching solution, using a sulfite fixing agent before bleaching, or by fogging the element between bleaching and the second color development step.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: August 29, 1995
    Assignee: Eastman Kodak Company
    Inventors: Peter D. Marsden, Gareth B. Evans
  • Patent number: 5443943
    Abstract: Unique imagewise exposed and developed originating color silver halide photographic elements can be processed with bleaching and/or fixing solutions. The element is characterized by several important features. It contains a silver halide grain population of at least 50 mole percent chloride, based on total silver forming the grain population projected area, wherein at least 50 percent of total grain projected area is accounted for by intrinsically stable tabular grains (1) bounded by {100} major faces having adjacent edge ratios of less than 10, and (2) an aspect ratio of at least 2. Also, at least 50 mole % of the element silver halide is silver chloride, and no more than 2 mole % silver iodide. It also contains a bleach accelerator releasing compound. The element is also free of a desilvering rate retarding amount of a development inhibitor releasing compound having a free sulfur valence which binds to silver.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: August 22, 1995
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, John M. Buchanan
  • Patent number: 5436118
    Abstract: A method of processing an imagewise exposed silver halide photographic element comprising developing and desilvering the photographic element in a low volume thin tank processor wherein the processor operates at 15% or less of maximum production capacity.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: July 25, 1995
    Assignee: Eastman Kodak Company
    Inventors: Jerel R. Carli, David G. Foster, Edgar P. Gates, David L. Patton, John H. Rosenburgh, Sheridan E. Vincent
  • Patent number: 5434035
    Abstract: A method of treating a seasoned fixing solution comprising desilvering a fixing solution containing a chelating compound represented by Formula IMOOC(CH.sub.2)m(X)p((CH.sub.2).sub.n COOM).sub.q (I)where X is N, or C--OH;n and m are independently 0, 1, or 2;if X is N then p is 0 or 1 and q is 1 or 2;if X is C-OH then p is 0, 1 or 2 and q is 1 or 2; andM is a cationic counterion; andfurther containing a carryover amount of a bleaching agent which is a complex of ferric ion and a tridentate or a tetradentate ligand.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: July 18, 1995
    Assignee: Eastman Kodak Company
    Inventors: Mary E. Craver, Manuel A. Santos-Rosario, Keith H. Stephen
  • Patent number: 5424176
    Abstract: A fixing solution having a pH.gtoreq.7 and comprising a fixing amount of sulfite and a fix accelerating amount of a thioether compound; wherein the fixing solution contains less than 0.05 moles/liter of thiosulfate and a method of processing an imagewise exposed and developed silver halide photographic element comprising fixing in said fixing solution a silver halide photographic element containing at least one emulsion or deposit of silver halide comprising greater than 90 mole % silver chloride.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: June 13, 1995
    Assignee: Eastman Kodak Company
    Inventors: Eric R. Schmittou, Therese M. Feller, Stuart T. Gordon
  • Patent number: 5418117
    Abstract: A method of processing an imagewise exposed photographic silver halide colour material by a redox amplification method in wherein colour developing solution is applied to the material in the presence of atmospheric oxygen and a hydroxylamine compound of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl or aryl groups either of which may be substituted, andwherein the colour developer solution is agitated sufficiently for redox amplification to occur.
    Type: Grant
    Filed: July 15, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Kodak Company
    Inventor: Peter D. Marsden
  • Patent number: 5411842
    Abstract: A method for making a photographic silver halide developer composition, preferably immediately before use, by electrolysing an aqueous medium containing a developing agent precursor composition which forms or releases a silver halide developing agent at an electrode upon electrolysis.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventors: Michael Ridgway, Nigel E. Milner, Siu C. Tsoi, Paul C. Ward
  • Patent number: 5389501
    Abstract: A method of fixing a photographic element with a fixing solution containing less than 20% ammonium thiosulphate wherein the photographic element has incorporated therein a fix accelerator precursor which is a silver salt of an amino thiol having a solubility of less than 1 g/l (as silver ion) when held for 23.degree. C. for 5 minutes in a colour developer solution at pH 10 having a sulphite concentration of 4.25 g/l and a bromide concentration of 1.2 g/l.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: February 14, 1995
    Assignee: Eastman Kodak Company
    Inventors: David N. Rogers, John R. Fyson
  • Patent number: 5385816
    Abstract: This invention provides a color photographic element comprising, in an adjacent silver halide emulsion layer,(1) a development inhibitor releasing developer (IRD) which comprises a hydrazide, sulphonamidophenol, sulphonamidonaphthol, or hydroquinone moiety attached directly or via a linking group to a development inhibitor moiety which compound is oxidizable during silver halide development enabling release of the development inhibitor moiety under alkaline conditions,(2) a sulphonhydrazide color developing agent, and(3) a color coupler capable of forming image dye with the sulphonhydrazide during silver halide development.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: January 31, 1995
    Assignee: Eastman Kodak Company
    Inventors: Paul L. R. Stanley, Siu C. Tsoi