Abstract: A method for producing a solvent resistant, low-extractable, film from an actinic radiation curable homogenous aqueous composition containing a water soluble compound, having at least one alpha, beta-ethylenically unsaturated radiation polymerizable double bond, and water as essential components.
Type:
Grant
Filed:
December 27, 2002
Date of Patent:
May 2, 2006
Assignee:
Sun Chemical Corporation
Inventors:
Subhankar Chatterjee, Mikhail Laksin, David Biro, Jean Dominique Turgis
Abstract: A process for conditioning azo pigment with surfactants of ethoxylate alkyl phenols in the presence of a strong alkali in the aqueous condition.
Type:
Grant
Filed:
December 31, 2003
Date of Patent:
March 28, 2006
Assignee:
Sun Chemical Corporation
Inventors:
Edward H. Sung, George H. Robertson, Humberto A. Velasquez
Abstract: A web offset heatset printing ink composition having less than about 2 wt. % of volatile organic compounds containing an aqueous polymer latex dispersed in an ink base of a resin, a non-volatile plasticizer, and a pigment and method for preparing same.
Type:
Grant
Filed:
December 31, 2003
Date of Patent:
March 28, 2006
Assignee:
Sun Chemical Corporation
Inventors:
David Klein, Gary F. Dandreaux, Richard R. Durand, Jr., Thierry Frinault, Kenneth Smith
Abstract: A method of acrylating a resin containing one or more hydroxyl functional group and derived from a natural product, comprising preparing a mixture of a hydroxyalkyl acrylate and an isocyanate; and reacting said mixture with said resin.
Abstract: A pigment's etheramine sulfonic acid salt is described. Also described is a method for enhancing the performance of a pigment composition containing an organic pigment, comprising enhancing the dispersion of said pigment by adding to 100 parts of said pigment about 1 to 40 parts of a pigment's etheramine sulfonic acid salt.
Type:
Grant
Filed:
April 14, 2003
Date of Patent:
August 9, 2005
Assignee:
Sun Chemical Corporation
Inventors:
Kevin A. Arthur, George H. Robertson, George McLaren, Stanislav G. Vilner, Ronald R. Forbes
Abstract: Active water compatible actinic radiation curable printing ink or coating compositions comprised of maleimide derivatives, water compatible resins and water, which are capable of curing at a practical intensity and energy level and a method for curing same.
Type:
Grant
Filed:
August 27, 2003
Date of Patent:
February 22, 2005
Assignee:
Sun Chemical Corporation
Inventors:
David Anthony Biro, Mikhail Laksin, Yoshinobu Sakurai, Hisatomo Yonehara, Katsuji Takahashi
Abstract: A multi-functional photoinitiator of formula (I) R1m—Q—(A1—PI)n??(I) wherein Q is a heteroatom selected from Si, Ti, Zr and Sn or any two independently selected such heteroatoms linked by a covalent bond or a by C1-16 (preferably C1-9) alkylene group, n is at least 2 and n+m=the functionality of Q, each R1 is the same or different and is a non-photoinitiator group; each group PI is the same or different and is a photoinitiator group. Each —A1— is the same or different and is selected from linking groups of formula —(A2)p—Z— wherein p has an average of from 1 to 10, preferably from 3 to 5 and the groups —A2— are either (a) each independently selected from C2-4 alkyleneoxy groups; or (b) each independently selected from groups of formula —O—(CH2)qCO— wherein q is from 3 to 5, and Z is selected from —O—, —S— and —NR6— where R6 is C1-6 alkyl.
Type:
Grant
Filed:
August 4, 2000
Date of Patent:
February 1, 2005
Assignee:
Sun Chemical Corporation
Inventors:
Roger Edward Burrows, Shaun Lawrence Herlihy, Derek Ronald Illsley
Abstract: Solid, solvent-free inks are provided for use in hot melt flexographic printing. The ink is composed of a pigment; a thermoplastic binder which is an ethylene copolymer, a hydrocarbon resin, or a combination thereof; a wax which is a highly branched hydrocarbon wax, a polyethylene homopolymer wax, an oxidized polyethylene wax, an animal wax, a vegetable wax or combinations thereof; a solid linear alcohol; and, a dispersing agent. The ink may also contain a solid plasticizer. The solid ink has a melting point of about 75° C. or greater, and when heated to a temperature between about 90° C. and about 135° C., a molten ink is formed which has a viscosity between about 100 cps and about 1200 cps. The solid inks are used in melt flexographic printing by heating the ink to a temperature greater than about 90° C.
Type:
Grant
Filed:
December 28, 2001
Date of Patent:
January 11, 2005
Assignee:
Sun Chemical Corporation
Inventors:
Jitendra Modi, Edward Stone, Ana Marie Flores, Robert Catena, Robert Auerbach
Abstract: A method for curing an active single phase water compatible actinic radiation curable composition, comprising: irradiating a water compatible non emulsion, non dispersing compound, water, and a maleimide derivative.
Type:
Grant
Filed:
August 27, 2003
Date of Patent:
December 28, 2004
Assignee:
Sun Chemical Corporation
Inventors:
David Anthony Biro, Mikhail Laksin, Yoshinobu Sakurai, Hisatomo Yonehara, Katsuji Takahashi
Abstract: The invention relates to a water-based intaglio printing ink especially suited for the intaglio printing of security documents, such as postage stamps, stock certificates and the like, wherein the water-based intaglio printing ink having a) an epoxy resin ester reacted with an unsaturated monobasic acid and a reactive monomer, b) a glycol and/or glycol ether c) a pigment, d) a monoalkanolamine, e) a drier and f) water.
Abstract: A method for producing a low-extractable film packaging from an actinic radiation curable aqueous composition containing a water soluble compound having at least one &agr;, &bgr;-ethylenically unsaturated, radiation polymerizable group and water as essential components carried out by applying the aqueous composition to a surface which is then irradiated in a single step with actinic radiation in the presence of the water thereby forming a cured film wherein less than 50 ppb of the water soluble compound or its residual components are extractable by a food simulant.
Type:
Grant
Filed:
March 29, 2000
Date of Patent:
October 12, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Subhankar Chatterjee, Mikhail Laksin, David Biro, Jean Dominique Turgis
Abstract: An aqueous organic pigment dispersion used to integrally color concrete and other building materials which includes: alkali metal silica particles as a binder; organic pigment; water; and dispersing agent in an amount effective to disperse the organic pigment and the binder in the water. A method for preparing the aqueous organic pigment dispersion includes (i) mixing, at 3,000 to 10,000 rpm, alkali metal silica particles; organic pigment; and dispersing agent, thereby forming a dispersion premix; (ii) milling the dispersion precursor in a mixer filled with glass beads for a period of time sufficient to reduce the particle size of the organic pigment to about 100 to about 300 nanometers, thereby forming a non-standardized dispersion; and (iii) standardizing the dispersion against a color standard by adding water.
Type:
Grant
Filed:
September 9, 2002
Date of Patent:
September 7, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Charles W. Perry, Donald C. Dulaney, James Moore
Abstract: The present invention is for a method and associated apparatus whereby low viscosity flexograhic printing inks having a viscosity controlling diluent are used in implementing wet trapping of sequentially applied ink layers by controlling the time between ink layer applications such that sufficient diluent evaporates from an applied layer to increase the first applied layer viscosity sufficiently to wet trap a subsequently applied superposed ink layer.
Abstract: Disclosed is a process for the preparation of a pigment dispersion starting with a tank flushed pigment that is continuously fed into a twin screw extruder, washed and dried by vacuum to get a desirable product.
Type:
Grant
Filed:
April 5, 2002
Date of Patent:
July 27, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Kalpathy R. Anantharaman, Michael L. Lewis, Pat Galioto
Abstract: The present invention relates an improved silicone modified water-based emulsion used primarily for publication gravure ink. Publication gravure water-based ink produced with the new polymer exhibits superior paper holdout, smoother lay, and higher gloss on super calendered and uncoated paper substrates as compared to conventional water-based gravure inks.
Type:
Grant
Filed:
October 25, 2001
Date of Patent:
July 20, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Ramasamy Krishnan, Robert Catena, Selcuk Avci
Abstract: Solvent-free, energy curable low viscosity gravure and non-conductive ink jet inks which contain a pigment; a rheological additive having the structure P—(U—Y)s, wherein P is the residue of an organic pigment or dye, Y is a polyalkylene oxide moiety, U is a linking moiety covalently bonding Y to P and s is an integer from 1 to 3; and an energy curable liquid vehicle which may be a cationic, thermal cationic or a free radical initiated polymerization system, cured by actinic radiation; and optionally containing a photoinitiating system.
Type:
Grant
Filed:
February 27, 2001
Date of Patent:
April 27, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Mikhail Laksin, Subhankar Chatterjee, Russell J. Schwartz, Paul A. Merchak, Patrice Aurenty, Edward Stone, Gordon Kotora
Abstract: Solvent based poly(urethane/urea) resins suitable for formulating flexographic and gravure laminating printing ink and coating compositions formed from a poly(urethane) prepolymer solution made from a blend of polymeric diols and diols reacted with diisocyanates and then with diamine in an organic solvent. The resin is prepared by adding the poly(urethane) prepolymer solution at a controlled rate to the diamine in a organic solvent which allows a resin solution to be formed, which may be used in the formulation of laminating printing ink and coating compositions without the need for adjuvants, grinding in polyvinyl butyral or blending with nitrocellulose base.
Type:
Grant
Filed:
November 13, 2000
Date of Patent:
April 20, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Ralph Arcurio, Mark Rocco, David J. Slavinski, Mark Schneider
Abstract: A waterbased heatset offset lithographic ink comprising water, polyamide resins or fumarated rosin resins, hydroxyethylethylene urea, a modified linseed oil, a dibutylated benzoguanamine, a pigment and p-toluene sulfonic acid.
Type:
Grant
Filed:
December 19, 2002
Date of Patent:
March 23, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Ramasamy Krishnan, Marilyn Yamat, Hugo Babij