Abstract: Solvent based poly(urethane/urea) resins suitable for formulating flexographic and gravure laminating printing ink and coating compositions formed from a poly(urethane) prepolymer solution made from a blend of polymeric diols and diols reacted with diisocyanates and then with diamine in an organic solvent. The resin is prepared by adding the poly(urethane) prepolymer solution at a controlled rate to the diamine in a organic solvent which allows a resin solution to be formed, which may be used in the formulation of laminating printing ink and coating compositions without the need for adjuvants, grinding in polyvinyl butyral or blending with nitrocellulose base.
Type:
Grant
Filed:
November 13, 2000
Date of Patent:
April 20, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Ralph Arcurio, Mark Rocco, David J. Slavinski, Mark Schneider
Abstract: A waterbased heatset offset lithographic ink comprising water, polyamide resins or fumarated rosin resins, hydroxyethylethylene urea, a modified linseed oil, a dibutylated benzoguanamine, a pigment and p-toluene sulfonic acid.
Type:
Grant
Filed:
December 19, 2002
Date of Patent:
March 23, 2004
Assignee:
Sun Chemical Corporation
Inventors:
Ramasamy Krishnan, Marilyn Yamat, Hugo Babij
Abstract: Active water compatible energy curable compositions comprised of maleimide derivatives, water compatible resins and water which are capable of curing at a practical intensity and energy level and a method for curing same.
Type:
Grant
Filed:
July 23, 2001
Date of Patent:
March 16, 2004
Assignee:
Sun Chemical Corporation
Inventors:
David Anthony Biro, Mikhail Laksin, Yoshinobu Sakurai, Hisatomo Yonehara, Katsuji Takahashi
Abstract: This invention relates to a process of preparing a perylene pigment compositions containing a reactive co-precipitated blend of
(1) about 75 to about 99.9 mol %, relative to the pigment composition, of a compound having the formula (I)
wherein
R is hydrogen, C1-C6 alkyl, C5-C8 cycloalkyl, C7-C16 aralkyl, or C6-C10 aryl,
A is C1-C6 alkyl, C1-C6 alkoxy, a sulfonyl group, amino, ammonium, hydroxy, nitro, or halogen, and
m is zero or a number from 1 to 8; and
(2) about 0.1 to about 25 mol %, relative to the pigment composition, of a perylene dicarboxamidine imide having the formula (II)
wherein
W is optionally substituted or modified C2-C3 alkylene.
Abstract: A flexographic preprint ink composition, which includes at least 3 weight percent of a pigment; at least 15 weight percent of a hydrolyzed gelatin; and water. The ink composition may also contain conventional additives, such as surfactants and defoaming agents, typically found in flexographic ink compositions. The flexographic ink composition can exhibit better heat resistance, mileage, strength, wet trap, foam resistance, drying, stability, and plate transfer than conventional flexographic inks which contain soy as a binder.
Abstract: A hot melt ink composition containing a an alkylene distearate which improves the color strength of the ink and is formed as a reaction product of a C4-C8 diol and at least one acid selected from the group consisting of a C16-C18 monofunctional acid and a C9-C10 difunctional acid.
Type:
Grant
Filed:
January 5, 2001
Date of Patent:
November 11, 2003
Assignee:
Sun Chemical Corporation
Inventors:
Edward Stone, Jitendra J. Modi, Robert J. Catena
Abstract: Disclosed is a polyurethane resin having a number average molecular weight of up to 5,000 which is prepared by reacting a diisocyanate compound with at least one monomer diol compound and optionally a polymer diol compound without a chain extender to form a polymer, wherein the molar ratio of the monomer diol compound over the polymer diol compound when present is above 1 followed by capping the polymer with a terminator.
Abstract: An energy curable printing ink composition containing a branched polyester comprising monofunctional and difunctional components having an excess functionality of about 0.1 to 0.20. Also described is a method of reducing misting and/or dot gain in an energy curable printing ink composition by adding such branched polyesters to the composition.
Type:
Grant
Filed:
January 11, 2000
Date of Patent:
August 12, 2003
Assignee:
Sun Chemical Corporation
Inventors:
Edward Stone, Gordon Kotora, Neil Young
Abstract: A two-step method for introducing acrylic functions into high molecular weight natural resins, under mild conditions, without the risk of gellation, wherein an acrylated natural resin ester is prepared by esterifying one or more of the sterically hindered hydroxy groups of the natural resin ester in an inert solvent with a 3-halopropionic acid, to form a 3-halopropionate ester of the natural resin ester and dehydrohalogenated the 3-halopropionate ester by reacting it with an organic base.
Abstract: An aqueous polymer dispersion comprising a polymer substantially free of cationic polymerizable groups and a cationic photoinitiator, wherein the polymer is capable of being precipitated by an acid or base generating photoinitiator upon exposure to radiation and is optionally an energy curable polymer.
Type:
Grant
Filed:
September 17, 2001
Date of Patent:
May 6, 2003
Assignee:
Sun Chemical Corporation
Inventors:
John Rooney, Subhankar Chatterjee, Mikhail Laksin, Jean-Dominque Turgis
Abstract: A printing ink composition containing resin and glycerine, wherein the composition has less than 5 wt. % volatile organic compounds and has no hazardous air pollutants and a method of preparing such composition.
Type:
Grant
Filed:
January 5, 2001
Date of Patent:
April 8, 2003
Assignee:
Sun Chemical Corporation
Inventors:
Clay McCall, Ricky V. Mitchell, Doreen E. Smith
Abstract: A method of conditioning an organic crude pigment by treating, under high shear, 1 part by weight of the crude pigment and about 0.5 to 1.9 parts by weight of polyphosphoric acid or polyphosphoric acid methyl ester at a temperature ranging from about 90 to 160° C.
Type:
Grant
Filed:
November 10, 2000
Date of Patent:
March 25, 2003
Assignee:
Sun Chemical Corporation
Inventors:
Edward H. Sung, Humberto Velasquez, George H. Roberston, Veronica L. Chambers
Abstract: A process for the preparation of an organic pigment dispersion is disclosed and consists of dispersing a dried soft-textured organic pigment in a dispersion vehicle, wherein the dispersion vehicle contains an ink varnish and alkyd and the dispersion is carried out in a tank equipped with a sweep and a high speed dispersion blade.
Type:
Grant
Filed:
December 28, 2001
Date of Patent:
March 11, 2003
Assignee:
Sun Chemical Corporation
Inventors:
Kalpathy Anantharaman, Michael Lewis, Anthony Maliyackel, Alan Gregory, Sanjoy Ganguly, Allen Bauer
Abstract: Aqueous based pigment dispersions wherein the pigment is dispersed in a dispersant dye in the absence of any other dispersant or additive and aqueous based printing ink compositions containing these a pigment dispersions. Methods for preparing aqueous based pigment dispersions, wherein the pigment is dispersed in a dispersant dye, and method for preparing printing ink compositions incorporating these dispersions.
Type:
Grant
Filed:
November 20, 2000
Date of Patent:
January 7, 2003
Assignee:
Sun Chemical Corporation
Inventors:
Darren Mark Ortalano, Christopher Joseph Vissing
Abstract: A process for producing beta-phase quinacridone by (a) reacting 2,5-dianilino-terephthalic acid with polyphosphoric acid in the presence of 2,5-dianisidino-terephthalic acid at a reaction temperature of at least 85° C.; (b) diluting the reaction mixture with water; (c) drowning the diluted mixture in a water-miscible alkanol; (d) heating the slurry at a temperature of from 100 to 130° C. at a pressure of 20 to 50 psi; and (e) recovering the beta-phase quinacridone.
Type:
Grant
Filed:
January 5, 2001
Date of Patent:
December 17, 2002
Assignee:
Sun Chemical Corporation
Inventors:
Edward Sung, Kathleen M. Kozak, George H. Robertson, Terrence R. Chamberlain
Abstract: An Offset Lithographic Printing Process employing low VOC lithographic printing ink formulations containing monomeric diluents, curable by cationic polymerization in the presence of fountain solution and resin rheology modifiers compatible with cationic catalysts.
Type:
Grant
Filed:
September 20, 2001
Date of Patent:
December 3, 2002
Assignee:
Sun Chemical Corporation
Inventors:
Edward Stone, Gordon Kotora, Mikhail Laksin, Subhankar Chatterjee, Bhalendra J. Patel
Abstract: A process for improving the heat stability of Pigment Violet 23 by conditioning crude Pigment Violet 23 in the presence of about 1 to 10 wt. % of Pigment Violet 23 by-products (1), (2) and (3).
Type:
Grant
Filed:
January 5, 2001
Date of Patent:
November 5, 2002
Assignee:
Sun Chemical Corporation
Inventors:
Norman W. Smith, Terrence R. Chamberlain, Barbara N. Berg, George McLaren, Russell J. Schwartz
Abstract: An etheramine pigment dispersing salt for enhancing the dispersion performance of an organic pigment composition adding to 100 parts by weight of pigment about 1 to 40 parts by weight of an etheramine pigment dispersing salt.
Type:
Grant
Filed:
November 16, 2000
Date of Patent:
October 29, 2002
Assignee:
Sun Chemical Corporation
Inventors:
George H. Robertson, Kevin A. Arthur, Russell J. Schwartz, Stanislav Vilner, George McLaren
Abstract: A method of acid swelling crude perylene pigment by treating the crude with about 2 to 10 parts by weight of toluene sulfonic acid at an elevated pressure and at temperatures ranging from 40 to 140° C.
Type:
Grant
Filed:
November 10, 2000
Date of Patent:
October 15, 2002
Assignee:
Sun Chemical Corporation
Inventors:
Edward H. Sung, George H. Robertson, Chris M. Arizo
Abstract: Lithographic printing ink formulations compatible with cationic catalysts containing a diluent and rheology modifying resins curable by cationic polymerization in the presence of water or fountain solution.
Type:
Grant
Filed:
February 7, 2000
Date of Patent:
September 17, 2002
Assignee:
Sun Chemical Corporation
Inventors:
Edward Stone, Gordon Kotora, Mikhail Laksin, Subhankar Chatterjee, Bhalendra J. Patel