Abstract: A system including pretreating feed air for a cryogenic air separation plant wherein feed air is passed through an electric field, oxygen is ionized, and ionized oxygen reacts with hydrocarbons upstream of an adsorption prepurifier, and subsequent separation of the feed air by cryogenic rectification.
Type:
Grant
Filed:
September 10, 1998
Date of Patent:
March 28, 2000
Assignee:
Praxair Technology, Inc.
Inventors:
Nancy Rose Cribbin, Dante Patrick Bonaquist, Alan Barnard Stewart, Gregory William Henzler
Abstract: A method for more efficiently liquefying industrial gas wherein refrigeration for the liquefaction is generated using a defined multicomponent refrigerant fluid and provided by a single flow circuit over a wide temperature range from ambient to cryogenic temperature.
Type:
Grant
Filed:
December 30, 1998
Date of Patent:
March 28, 2000
Assignee:
Praxair Technology, Inc.
Inventors:
Walter Joseph Olszewski, Bayram Arman, Joseph Alfred Weber, Arun Acharya
Abstract: A method for liquefying an industrial gas wherein a portion of the requisite refrigeration is generated by a multicomponent refrigerant circuit and a portion is generated by turboexpansion of either a portion of the industrial gas or a portion of the multicomponent refrigerant.
Type:
Grant
Filed:
December 30, 1998
Date of Patent:
March 28, 2000
Assignee:
Praxair Technology, Inc.
Inventors:
Walter Joseph Olszewski, Bayram Arman, Arun Acharya, Joseph Alfred Weber, Mohammad Abdul-Aziz Rashad
Abstract: An annular column, particularly useful for cryogenic rectification, comprising coaxially oriented, radially spaced cylindrical column walls defining a first column region, and a second column region between the walls, wherein different fluid mixtures are rectified in each of the first column and second column regions.
Type:
Grant
Filed:
June 11, 1999
Date of Patent:
February 15, 2000
Assignee:
Praxair Technology, Inc.
Inventors:
Kenneth Kai Wong, John Frederic Billingham, Dante Patrick Bonaquist, Bayram Arman, Raymond Francis Drnevich, Minish Mahendra Shah, Todd Alan Skare
Abstract: A low NO.sub.x combustion process is carried out by reacting low concentrations of combustibles with low concentrations of oxygen. These low concentrations are obtained by injecting high velocity fuel and oxidant streams through port openings that are spatially separated.
Type:
Grant
Filed:
August 4, 1997
Date of Patent:
December 28, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Harry Monroe Ryan, III, Arthur Wellington Francis, Jr., Michael Francis Riley, Hisashi Kobayashi
Abstract: A cryogenic air separation system wherein a portion of the feed air is compressed to a very high pressure, bypasses the primary heat exchanger, and is turboexpanded to a low pressure to supply refrigeration in one step from the warm end temperature to the cryogenic temperature of the cryogenic air separation plant.
Type:
Grant
Filed:
July 10, 1998
Date of Patent:
December 14, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Dante Patrick Bonaquist, Nancy Jean Lynch
Abstract: A process for further purification of nitrogen gas, thereby producing ultra-high purity nitrogen which is substantially free of hydrogen, oxygen and carbon monoxide, wherein the nitrogen gas is contacted with a metal-containing adsorbent at a temperature of 150 K. or less.
Type:
Grant
Filed:
October 31, 1997
Date of Patent:
November 16, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Mary Louise Markowski, Thomas John Bergman, Jr., James Philip Natwora, Jr., John Keller Howell, David Richard Thompson
Abstract: A gas driven fermentation system wherein a gas such as air is passed heterogeneously upwardly through the fermentation broth to agitate and recirculate the broth, provide oxygen for fermentation and strip off carbon dioxide, and a second gas such as oxygen is passed homogeneously upwardly through the broth proximate the heterogeneous air flow to provide supplemental oxygen for fermentation.
Abstract: A method for heating and/or melting a charge such as aluminum in a furnace using heat generated by combustion to radiatively heat the charge through a layer of protective gas wherein combustion reaction products generated by the combustion are exhausted from a lower level within the furnace, and, during melting, the protective gas layer has a higher upper boundary than during a subsequent heating period, enabling reduced NO.sub.x generation, lower fuel and oxygen consumption and reduced refractory corrosion by avoiding furnace gas flow through the high temperature upper furnace region.
Type:
Grant
Filed:
March 3, 1998
Date of Patent:
October 5, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Hisashi Kobayashi, Arthur Wellington Francis, Jr., Xueping Li
Abstract: A system for producing direct reduced iron wherein iron oxide material and carbonaceous material is passed successively through an oxidizing zone and a reducing zone of a furnace, each zone fired by oxy-fuel combustion, enabling a reduction in the amount of fuel needed to process the material while generating sufficient carbon monoxide to effect the reduction and ensuring that little or no carbon monoxide is emitted from the furnace.
Abstract: A cryogenic air separation system wherein separation inefficiencies resulting from feed air flow disturbances due to discontinuous prepurifier operation are reduced or eliminated by inhibiting column liquid drainage during such disturbances using mesh packing having interspacial regions which hold up the liquid during the disturbances using surface tension.
Type:
Grant
Filed:
April 1, 1998
Date of Patent:
September 14, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
John Fredric Billingham, Walter Joseph Olszewski, John Peter Ricotta
Abstract: An annular column, particularly useful for cryogenic rectification, comprising coaxially oriented, radially spaced cylindrical column walls defining a first column region, and a second column region between the walls, wherein different fluid mixtures are rectified in each of the first column and second column regions.
Type:
Grant
Filed:
August 5, 1998
Date of Patent:
September 7, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Kenneth Kai Wong, John Frederic Billingham, Dante Patrick Bonaquist, Bayram Arman, Raymond Francis Drnevich, Minish Mahendra Shah, Todd Alan Skare
Abstract: Method and apparatus for effectively and safely using cryogenic liquid to cool a reactor vessel housing an exothermic reaction wherein the cryogenic liquid is subcooled, valved into the reactor in a downward direction, and shielded by annular coaxial shielding gas upon injection into the reactor.
Abstract: A method for efficiently providing supplemental oxygen to a reaction mixture which is oxidized by or otherwise uses air, wherein the reaction mixture is agitated to create one or more stationary vortices, oxygen is injected into the reactor vessel at a stationary vortex, and air bubbles are circulated within the reaction mixture in the reactor vessel and outside the stationary vortex or vortices into which the oxygen is injected.
Abstract: A dual feed pressure cryogenic air separation system wherein all the feed air is pressurized to an intermediate pressure and cleaned of high boiling impurities at that intermediate pressure, and a portion further compressed to the high pressure and then cooled against another portion so as to prepare that other portion for the turboexpansion to the low pressure, preferably with the turboexpansion driving the further compression.
Type:
Grant
Filed:
March 4, 1998
Date of Patent:
August 10, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Dante Patrick Bonaquist, Michael James Lockett
Abstract: A system for rapidly filling cylinders with gas while avoiding superambient temperature excursions of the cylinder contents wherein cylinder charging gas is produced by vaporizing pressurized cryogenic liquid in admixture with pressurized gas to simultaneously in one step produce the charging gas and control the temperature of the charging gas to enable the subsequent rapid filling rate.
Type:
Grant
Filed:
February 3, 1998
Date of Patent:
August 10, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
John Notaro, Erwin Schulze Beckinghausen, Jr., Bruce Hall Davidson, Thomas Edward DeBriae
Abstract: A system and method for protecting a nozzle that injects a high velocity main gas into a furnace or combustion zone. The nozzle is located in a passage recessed from the exit port opening of the passage which communicates with the combustion zone. Purge gas is passed into the passage upstream of the nozzle. The volume of the purge gas exceeds 50% of the total volume of the main gas and purge gas and the purge gas has a velocity of at least 100 ft/sec thereby preventing furnace gases from entering the passage and attacking the nozzle.
Abstract: A system for producing carbon dioxide, particularly from a feed which contains significant levels of light contaminants, wherein light overhead from a distillation column is partially condensed against heat exchange fluid containing both carbon dioxide and light contaminants and the resulting heat exchange fluid passed into the feed for the distillation column.
Abstract: An improved staged combustion method useful with oxy-fuel combustion and in a furnace which contains a charge, wherein substoichiometric combustion and secondary oxidant injection are carried out in an orientation which forms a more oxidizing atmosphere proximate the charge surface and oxidizing gas recirculates from the secondary oxidant stream to the charge surface and back to the secondary oxidant stream.
Type:
Grant
Filed:
May 15, 1998
Date of Patent:
July 20, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Geoffrey Bruce Tuson, Ronald William Schroeder, Hisashi Kobayashi
Abstract: A method for cleaning and recycling protective atmosphere for a float glass facility wherein contaminated protective atmosphere is cooled, preferably while scrubbing out particulates, compressed, and then purified by passage through a bed comprising water selective and hydrogen sulfide selective adsorbents.
Type:
Grant
Filed:
December 19, 1997
Date of Patent:
July 20, 1999
Assignee:
Praxair Technology, Inc.
Inventors:
Joseph Alfred Weber, Theodore Fringelin Fisher, Dante Patrick Bonaquist