Patents Represented by Attorney Steven C. Benjamin
  • Patent number: 6733842
    Abstract: A process for the high-speed rotary application of a liquid coating agent onto a substrate, wherein the process comprises the steps: (a) direct supply of at least two liquid components in a specified quantity ratio which determines the qualitative and quantitative composition of the coating agent to at least one high-speed rotary atomizer or preparation of a premix from at least two liquid components in a specified quantity ratio which determines the qualitative and quantitative composition of the coating agent and supply of the premix to at least one high-speed rotary atomizer, (b) high-speed rotary atomization of the components directly supplied in step (a) or of the premix supplied in step (a) to the at least one high-speed rotary atomizer and (c) application of the material atomized in step (b) onto a substrate, wherein at least one of the components used in step (a) differs from at least one further component used in step (a) with regard to density by 0.
    Type: Grant
    Filed: May 1, 2003
    Date of Patent: May 11, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Michael Becker, Dirk Holfter, Karl-Friedrich Doessel
  • Patent number: 6720380
    Abstract: The invention relates to a modular system for the production of coating compositions for coating plastics comprising the following component modules: A) at least one base module containing at least one binder, extenders and/or pigments, optionally together with conventional coating additives, water and/or organic solvents, B) at least one adhesion module containing at least one adhesion-promoting component optionally together with binders, conventional coating additives, extenders, organic solvents and/or water, C) at least one elasticity module containing at least one elasticising component optionally together with conventional coating additives, extenders, organic solvents and/or water and D) at least one binder module containing at least one binder optionally together with additives, organic solvents and/or water.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: April 13, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Udo Hellmann, Maria Weigel
  • Patent number: 6719452
    Abstract: A rapid process for making transparent tints that match the color and tinting strength of a standard tint. The process involves the use of a faster and more accurate shading technique that utilizes the light transmittance properties of the tints in the wet over the visible spectrum and calculates therefrom the amount of components required to bring the tint within an acceptable match to the standard.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: April 13, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ken Stephen Schermacher, Allan Blase Joseph Rodrigues, Anthony Joseph Martino, Douglas E. Spahr, Timothy Aaron Snyder
  • Patent number: 6703452
    Abstract: The present invention relates to coating compositions which can be used as the clear coat for automotive finishing or refinishing, the coating composition containing a film-forming binder which contains (A) hydroxyl-containing acrylic polymer and polyhydroxyl-tertiary amine, (B) organic polyisocyanate, and (C) catalyst, to provide a coating film which is quick to cure at ambient temperature.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: March 9, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Gia Huynh-Ba
  • Patent number: 6689457
    Abstract: The present invention provides compositions comprising a graphite, binder precursor and low polarity solvent that upon hardening form layers of an electrically conductive material. The compositions of the present invention are sprayable by an internally charged electrostatic sprayer.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: February 10, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: David C. K. Chang, Monica A. Pickett, Debra Feldman Singer, Aleksandr Sorser, Debra Sue Strickland
  • Patent number: 6689459
    Abstract: An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct which is an epoxy resin that has been reacted with an amine, a blocked polyisocyanate crosslinking agent and an organic or inorganic acid as the neutralizing agent for the epoxy amine adduct; where the improvement is a catalyst of an alkyl tin oxide that has been dissolved with an organic or inorganic acid to provide a clear cathodic electrocoating composition.
    Type: Grant
    Filed: April 20, 2000
    Date of Patent: February 10, 2004
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Ding-Yu Chung, Yuehua Liu
  • Patent number: 6680356
    Abstract: A fast hardening clear coating composition for repairing a clearcoat/colorcoat finish of a vehicle, which composition is capable of being wet sanded, buffed or polished to a high gloss finish on the same day of application, comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl component comprising a hydroxyl-containing acrylic polymer and a hydroxyl-terminated polyester oligomer, and an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate, where the composition further contains, as a combined curing catalyst, at least one dialkyl tin aliphatic carboxylate, at least one tertiary aliphatic mono or diamine, and at least one aliphatic carboxylic acid, in an effective amount such that the clear coating composition on curing at ambient temperatures is in a water spot free and sufficiently hard state for sanding or buffing within about 4 hours after application or on cool down when baked under normal cond
    Type: Grant
    Filed: September 9, 2002
    Date of Patent: January 20, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Gia Huynh-Ba
  • Patent number: 6677425
    Abstract: A fast hardening clear coating composition for repairing a clearcoat/colorcoat finish of a vehicle, which composition is capable of being wet sanded, buffed or polished to a high gloss finish on the same day of application, comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl component comprising a hydroxyl-containing acrylic polymer and a hydroxyl-terminated polyester oligomer, and an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate, where the composition further contains, as a combined curing catalyst, at least one dialkyl tin aliphatic carboxylate, at least one tertiary aliphatic mono or diamine, and at least one aliphatic carboxylic acid, in an effective amount such that the clear coating composition on curing at ambient temperatures is in a water spot free and sufficiently hard state for sanding or buffing within about 4 hours after application or on cool down when baked under normal cond
    Type: Grant
    Filed: September 9, 2002
    Date of Patent: January 13, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Gia Huynh-Ba
  • Patent number: 6660793
    Abstract: Transparent iron oxide pigment dispersions which produce waterborne coating compositions having excellent transparency and reduced haze are provided. The dispersions contain dispersed pigment, an aqueous carrier, and a mixture of water-dispersible acrylic copolymer dispersants, the mixture containing at least one acrylic copolymer dispersant having acid functional groups, at least one acrylic copolymer dispersant having phosphate functional groups, and optionally at least one acrylic copolymer dispersant having alkyl amino groups and preferably benzyl groups in the pigment anachoring segment. Such pigment dispersions are useful in forming automotive waterborne paints, particularly “metallic” automotive paints.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: December 9, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Patrick F. McIntyre, Karyn B. Visscher, Kenneth S. Kirshenbaum
  • Patent number: 6642346
    Abstract: This invention is directed to a coating composition used for original equipment manufacturing or refinishing uses in the automotive industry, which coating composition utilizes an acrylic polymer which contains substituted or unsubstituted exomethylene lactones or lactams as a comonomer.
    Type: Grant
    Filed: January 25, 2001
    Date of Patent: November 4, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Charles J. Brandenburg, Randal D. King, Larry G. Oien, Peter W. Uhlianuk
  • Patent number: 6635207
    Abstract: Process for recycling of powder coating waste, wherein powder coating waste is moved in a vessel rotating about a rotational axis inclined at an angle of 20 to 70 degrees to the horizontal and is thereby exposed to heat, until powder coating agglomerates with a size of 1 mm to 3 cm or 1 to 10 mm or powder coating pearls with a size of 1 to 10 mm are formed.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: October 21, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: René Graewe
  • Patent number: 6632880
    Abstract: A coating composition containing about 40-90% by weight of film forming binder and 10-60% by weight of an organic liquid carrier; wherein the binder contains about (a) 10-70% by weight, based on the weight of the binder, of a dispersed gelled acrylic polymer having (i) a core of gelled polymerized ethylenically unsaturated monomers which is not soluble in the organic liquid carrier and having chemically grafted thereto (ii) substantially linear stabilizer polymeric components that are soluble in the organic liquid carrier and comprise polymerized ethylenically unsaturated monomers and have a weight average molecular weight of about 500-20,000 determined by GPC (gel permeation chromatography) using polystyrene as the standard; wherein the core, the stabilizer polymeric component, or both contain at least 3% by weight of polymerized ethylenically unsaturated monomers having isocyanate groups attached thereto that are capable of reacting with component (b); (b) 30-90% by weight, based on the weight of the b
    Type: Grant
    Filed: July 9, 2001
    Date of Patent: October 14, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert J. Barsotti, Laura Ann Lewin, Christopher Scopazzi
  • Patent number: 6607646
    Abstract: An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of a hydoxyl-carbonate blocked polyisocyanate crosslinking agent. Electrodeposited finishes are formed that have reduced weight loss when heated to cure.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: August 19, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Allisa Gam
  • Patent number: 6599973
    Abstract: A polymeric dispersant for pigments based on an acrylic graft copolymer wherein the graft copolymer has a weight average molecular weight of about 5,000-100,000 and comprises a hydrophobic polymeric backbone and discrete anionic and nonionic hydrophilic side chains attached to the backbone. These graft copolymers are useful as dispersants in aqueous systems, and are particularly useful in formulating exterior water borne coatings for automobiles and trucks.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: July 29, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Karyn B. Visscher, Patrick F. Mc Intyre
  • Patent number: 6541078
    Abstract: The invention is directed to a process for coating substrates by applying at least one coating composition to an optionally precoated substrate and then curing the coating layer(s) thus obtained, wherein at least one of the coating layers is produced from a coating composition which contains a binder system having olefinic double bonds capable of free-radical polymerization and having reactive functional groups within the meaning of addition and/or condensation reactions, the resin solids of the coating composition having a C═C-equivalent weight from 300 to 10,000, preferably from 300 to 8,000, and curing of this (these) coating layer(s) is carried out by irradiation with NIR radiation in the wave length range 760-1500 nm.
    Type: Grant
    Filed: May 9, 2001
    Date of Patent: April 1, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Volker Rekowski, Oliver Reis, Martin Wulf
  • Patent number: 6531188
    Abstract: Process for producing a multi-layer lacquer finish, in which a surfacer coating compound is applied to a substrate optionally pre-coated with a priming layer and/or further coating layers, and a top coating comprising a color-imparting and/or special-effect-imparting base lacquer layer and a transparent clear lacquer layer, or a top coating comprising a pigmented one-layer top lacquer, is then applied, in which the surfacer coating compound which is used is one which either contains binders which are curable exclusively by free radical and/or cationic polymerization, wherein the said binders are cured by means of high-energy radiation, or is one which contains binders which are curable by free radical and/or cationic polymerization, wherein the said binders are cured by means of high-energy radiation, and additionally contains chemically cross-linking binders.
    Type: Grant
    Filed: August 3, 2000
    Date of Patent: March 11, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Karin Maag, Helmut Löffler, Werner Lenhard
  • Patent number: 6528126
    Abstract: A process for multi-coat lacquering by applying a coat of filler and/or other coating compounds on to a substrate and then a top coat consisting of a base coat/clear lacquer construction or of a pigmented one-coat finish, at least one of the coats in the multi-coat construction being prepared from a coating compound which is at least partially curable by high-energy radiation, and irradiating this (these) coat(s) with UV radiation and IR radiation, a UV source having a proportion of IR radiation in its emission spectrum being, used for the irradiation with UV and IR radiation and, by alternately adding a UV filter and an IR filter and/or alternately adding and removing a UV filter or an IR filter in front of the radiation source, at least two irradiation intervals being formed, during which irradiation is variously carried out with UV radiation, IR radiation or UV radiation and IR radiation simultaneously.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: March 4, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Wolfgang Feyrer, Christine Kimpel, Helmut Löffler, Karin Maag, Jens Zeyen
  • Patent number: 6521715
    Abstract: A polymer dispersant for pigments based on an acrylic graft copolymer wherein the graft copolymer has a weight average molecular weight of 3,000-100,000 and comprises a polymeric backbone and macromonomer side chains attached to the backbone, wherein (1) the polymeric backbone is formed of polymerized ethylenically unsaturated monomers and (2) the side chains are macromonomers that are attached to the backbone at a single terminal point and are formed from polymerized ethylenically unsaturated monomers and have a weight average molecular weight of about 1,000-30,000 wherein the graft copolymer contains about 2 to 70% by weight, based on the weight of the graft copolymer, of polymerized ethylenically unsaturated monomers containing acetoacetate groups that are polymerized into the backbone, side chains, or both, and the acetoacetate groups are reacted with a primary amine to form a pendant acetoacetyl amine group on the graft copolymer which serves as the pigment anchoring group.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: February 18, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Sheau-Hwa Ma
  • Patent number: 6518395
    Abstract: Process for preparation powder coating formulations by pressure release of a composition comprising a low molecular mass inert compound, with release of the low molecular mass inert compound, in which process one or more base resins and one or more hardeners for the base resins, or one or more self-curing base resins, and, if desired, further customary coatings components, are converted together or separately into a flowable form by heating, the low molecular mass inert compound is dissolved under pressure at least in one of the base resin or hardener components employed, either before these components are combined with the other components or in the already prepared mixture, the overall mixture is homogenized, and then the mixture of all components is released from pressure, with cooling.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: February 11, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Peter Klostermann, Karin Maag, Dietrich Saatweber, Hans-Ulrich Simmrock, Eckard Weidner
  • Patent number: 6508922
    Abstract: A process for the production of a multi-layer coating, wherein a primer layer which is electrically conductive in the at least partially cured state is applied by electrodeposition from an electrodeposition coating agent (I) to an electrically conductive three-dimensional object, at least partially cured exclusively by the action of near infra-red radiation substantially only on the surfaces of the object exposed to the radiation, and an additional coating layer is applied by electrodeposition from an electrodeposition coating agent (II) which is different from electrodeposition coating agent (I), and then this additional coating layer as well as completely uncured or incompletely cured area parts of the primer layer produced from electrodeposition coating agent (I) are cured.
    Type: Grant
    Filed: May 10, 2001
    Date of Patent: January 21, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Matthias Kimpel, Martin Wulf, Oliver Reis