Patents Represented by Attorney Stewart N. Rice
  • Patent number: 4351729
    Abstract: A biological filter apparatus, and process for using the same, wherein organic pollutants in a waste water stream may be biologically degraded by a biomass of suitable microorganisms located on the surface of a packing. The filter comprises a sealed vessel in which the packing having the biomass thereon is located, and the waste water, mixed with several volumes of liquid recycle, is allowed to trickle downwardly through the packing countercurrently to ascending gases, effluent liquid is removed from the bottom of the vessel at a rate sufficient to maintain the level of effluent liquid below the packing in order to prevent the packing from being submerged in liquid. The apparatus and process are applicable to the anaerobic methanogenic processes wherein methane is produced as a product; and are also applicable to non-methanogenic processes which are conducted in the absence of added molecular oxygen wherein combined nitrogen is converted to molecular nitrogen.
    Type: Grant
    Filed: February 6, 1980
    Date of Patent: September 28, 1982
    Assignee: Celanese Corporation
    Inventor: Enrique R. Witt
  • Patent number: 4345093
    Abstract: Unreacted ethylene contained in a gaseous light ends stream derived from a process for the production of ethyl acrylate from ethylene and acrylic acid utilizing a sulfuric acid catalyst, is recovered by intimately contacting, under controlled conditions of temperature and pressure, the light ends stream with the liquid sulfuric acid catalyst make-up stream which is passed to the ethyl acrylate process. Upon contact of the light ends stream with the sulfuric acid make-up stream, the ethylene reacts with sulfuric acid to form ethyl hydrogen sulfate and diethyl sulfate, both of which remain in solution in the sulfuric acid which is then passed to the ethyl acrylate process as a source of make-up sulfuric acid. Sulfur dioxide contained in the vent-gas stream is not absorbed into the sulfuric acid, and therefore not recycled to the ethyl acrylate process.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: August 17, 1982
    Assignee: Celanese Corporation
    Inventors: Howard L. Pilat, Jerry D. Moore, Jack Chosnek
  • Patent number: 4301298
    Abstract: A normally liquid hydrocarbon having a minimum boiling point of about 425.degree. F. is utilized to provide the liquid seal in a vacuum pump which intakes a gaseous light ends stream resulting from a process for the production of ethyl acrylate by the reaction of ethylene with acrylic acid in the presence of a sulfuric acid catalyst. Upon contact in the vacuum pump, the gaseous light ends are partially absorbed into the normally liquid hydrocarbon, with the normally liquid hydrocarbon being recovered by fractionation.
    Type: Grant
    Filed: May 23, 1980
    Date of Patent: November 17, 1981
    Assignee: Celanese Corporation
    Inventors: Theodore Horlenko, James L. Paul, James W. Gordon
  • Patent number: 4257921
    Abstract: A butene may be oxidized in the vapor phase at elevated temperatures to produce acetic acid by reacting the butene with molecular oxygen in the presence of a catalyst comprising a composition of the empirical formula:V.sub.f Sb.sub.g X.sub.h Me.sub.i O.sub.jwherein V is vanadium, Sb is antimony, and O is oxygen, wherein X represents a metal which is one or more of Bi, Nb, Co, Nd, Sm, Zn, Zr or Cr, and wherein Me represents a metal which is one or more of Al, Fe or Sn, the metal represented by Me being optionally present.
    Type: Grant
    Filed: November 23, 1979
    Date of Patent: March 24, 1981
    Assignee: Celanese Corporation
    Inventors: William E. Slinkard, Anthony B. Baylis
  • Patent number: 4219671
    Abstract: A butene may be oxidized in the vapor phase at elevated temperatures to produce acetic acid by reacting the butene with molecular oxygen in the presence of a catalyst comprising a composition of the empirical formula:V.sub.f Sb.sub.g X.sub.h Me.sub.i O.sub.Jwherein V is vanadium, Sb is antimony, and O is oxygen, wherein X represents a metal which is one or more of Bi, Nb, Co, Nd, Sm, Zn, Zr or Cr, and wherein Me represents a metal which is one or more of Al, Fe or Sn, the metal represented by Me being optionally present.
    Type: Grant
    Filed: August 29, 1977
    Date of Patent: August 26, 1980
    Assignee: Celanese Corporation
    Inventors: William E. Slinkard, Anthony B. Baylis
  • Patent number: 4201868
    Abstract: A process for the reacting of methanol with carbon monoxide and hydrogen to produce increased amounts of methyl acetate, acetaldehyde and dimethyl acetal utilizing a catalyst comprising a cobalt carbonyl in complex with an organic nitrogen ligand.
    Type: Grant
    Filed: February 25, 1977
    Date of Patent: May 6, 1980
    Assignee: Celanese Corporation
    Inventor: William E. Slinkard
  • Patent number: 4199606
    Abstract: Propionic acid absorbed on a particulate carrier material, including vermiculite and perlite, which will catalyze or effect the formation of monomeric propionic acid in the propionic acid vapors which evaporate therefrom is disclosed as a preservative for various agricultural crop products and derivative and by-products thereof, including animal feeds and cereals.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: April 22, 1980
    Inventor: Bobby J. Bland
  • Patent number: 4198351
    Abstract: An improvement in the process for production of formaldehyde wherein a vapor phase mixture of methanol and air are passed over a silver catalyst, comprising the incorporation of a small amount of a halogen-containing compound into the mixture.
    Type: Grant
    Filed: April 15, 1977
    Date of Patent: April 15, 1980
    Assignee: Celanese Corporation
    Inventors: Anthony J. Branecky, David W. Harris
  • Patent number: 4190606
    Abstract: A process for dehalogenation of alpha halogenated carbonyl compounds and/or the prevention of the formation of such. The process for dehalogenation generally comprises causing there to be in solution the halogenated compound, cuprous ions (such as from cuprous chloride) and hydrogen ions (such as from hydrochloric acid), the process to be conducted in the absence of molecular oxygen, or, if molecular oxygen is present, there being an excess of cuprous ions sufficient to completely react with the molecular oxygen present. The present method can also be used to suppress formation of halogenated carbonyl compounds in processes where conditions exist which favor such formation.
    Type: Grant
    Filed: October 17, 1977
    Date of Patent: February 26, 1980
    Assignee: Celanese Corporation
    Inventor: George A. Blay
  • Patent number: 4168391
    Abstract: An improvement in the process wherein carbon monoxide and hydrogen are reacted in the liquid phase in the presence of a cobalt carbonyl catalyst whereby increased amounts of ethanol may be produced, which improvement comprises conducting the reaction in the presence of a non-polar, substantially inert, oxygenated hydrocarbon solvent.
    Type: Grant
    Filed: December 5, 1977
    Date of Patent: September 18, 1979
    Assignee: Celanese Corporation
    Inventors: William E. Slinkard, Anthony B. Baylis
  • Patent number: 4156633
    Abstract: Acrolein and other light ends are removed from the effluent of a process for the production of acrylic acid by the vapor phase catalytic oxidation of acrolein or an acrolein precursor, such as propylene, by passing the effluent to the base of a fractionation tower and contacting such with the descending stream of liquid within the tower so as to partially condense the condensibles in the effluent, a portion of the liquid bottoms being recycled to the upper portions of the tower and a portion withdrawn as crude acrylic acid product. Acrolein is removed overhead.
    Type: Grant
    Filed: July 29, 1976
    Date of Patent: May 29, 1979
    Assignee: Celanese Corporation
    Inventors: Theodore Horlenko, Gene J. Fisher
  • Patent number: PP12171
    Abstract: A Nerium oleander plant which has a petite and upright habit of growth, being particularly characterized by long blooming periods and the unique color of its inflorescnce and its habit of growth, the flowers being a white color with areas of pale yellow in the corona or throat, and which flowers grow in tight cymes or clusters resembling pompons.
    Type: Grant
    Filed: October 28, 1999
    Date of Patent: October 30, 2001
    Inventor: Ted Leon Turner, Sr.
  • Patent number: PP16660
    Abstract: A Nerium oleander plant which has a petite and upright and sprawling habit of growth, being particularly characterized by long blooming periods and the unique color of its inflorescence and its habit of growth, the flowers being a dusty rose color with areas of pale yellow in the corona or throat, and which flowers grow in cymes or clusters.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: June 13, 2006
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP4919
    Abstract: A pittosporum plant which has a dwarf habit of growth, the leaf blades being variegated and generally being medium green in color with pale yellow margins, the width of the pale yellow variegation being irregular.
    Type: Grant
    Filed: May 12, 1981
    Date of Patent: November 2, 1982
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP5233
    Abstract: A pittosporum plant which has a dwarf habit of growth and having leaf blades which are variegated, there being irregularly shaped areas of three different colors present on the variegated leaves, such being dark green, medium green and pale yellow. The variegated leaves do not have a uniform pattern of variegation, and the pattern of variegation differs from leaf to leaf.
    Type: Grant
    Filed: November 29, 1982
    Date of Patent: May 15, 1984
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP5378
    Abstract: A Nerium oleander plant which has a full and upright habit of fairly rapid growth, being particularly characterized by the unique color of its inflorescence, the flowers being a soft buff yellow color with tinges of pink.
    Type: Grant
    Filed: May 25, 1983
    Date of Patent: December 25, 1984
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP6339
    Abstract: A Nerium oleander plant which has a petite and upright habit of fairly rapid growth, being particularly characterized by the unique color of its inflorescence, the flowers being a soft pink color with tinges of pinkish red.
    Type: Grant
    Filed: September 12, 1986
    Date of Patent: October 18, 1988
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP7619
    Abstract: A Nerium Oleander plant which has a petite and upright habit of fairly rapid growth, being particularly characterized by its ever blooming character and the unique color of its inflorescence, the flowers being a light peach-pink color with areas of pink.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: August 13, 1991
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP7882
    Abstract: A Nerium oleander plant which has an intermediate and upright habit of fairly rapid growth, being particularly characterized by its everblooming character and the unique color of its inflorescence, the flowers being white with a soft pink blush or tint.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: June 9, 1992
    Inventor: Ted L. Turner, Sr.
  • Patent number: PP10157
    Abstract: A Nerbium oleander plant which has a intermediate and upright habit of fairly rapid growth, being particularly characterized by its ever blooming character and the unique color of its inflorescence, the flowers being a medium pink color with areas of pink, and by flowers having a sweet fragrance.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: December 23, 1997
    Inventor: Ted Leon Turner, Sr.