Abstract: The present invention relates to a synergistic additives mixture for producing calendered polyolefin articles, comprising A) at least one component from the group of peroxide-destroying phosphorus or sulfur compounds, B) at least one component from the group of phenolic antioxidants, C) at least one component from the group of sterically hindered amines, and D) if desired, further additives. Using this additive mixture prevents sticking to the hot roll surfaces and reduces the degradation of the polymer.
Type:
Grant
Filed:
February 3, 1999
Date of Patent:
January 31, 2006
Assignee:
Clariant GmbH
Inventors:
Christian Wick, Gerhard Pfahler, Alexander Lichtblau
Abstract: A process for preparing diketopyrrolopyrrole pigments comprises conducting the elementary steps of pigment synthesis (reaction and hydrolysis) in a miniaturized continuous reactor.
Abstract: A terpolymer comprising monomer units derived from an olefin having more than 40 carbon atoms, maleic anhydride, and an alkylallyl polyglycol ether of the formula
R—(OCH2CH2)nO—CH2—CH═CH2
where n=3-20 and R=C1-C4-alkyl.
Abstract: Resins obtainable from compounds of formula 1
in which the substituents R2 and HNR1 can be in the ortho, meta or para position relative to one another, and
R1 has the same meaning as R2, or has the meaning —COR2, where R1 is independent of R2,
R2 is C1-C30-alkyl, C2-C30-alkenyl, C6-C18-aryl, C7-C30-alkylaryl, by the steps, which can be carried out in any order, of
A) reaction with an aldehyde of the formula 2
R3—CHO (2),
wherein R3 is H, C1-C30-alkyl, C2-C30-alkenyl, C6-C18-aryl or C7-C30-alkylaryl, and
B) alkoxylation with a C2-C4-alkylene oxide in molar excess, such that the resulting alkoxylate has a degree of alkoxylation of from 1 to 100 alkylene oxide units per —NH group,
and the resin has a molecular weight of from 250 to 100,000 units, and their use as emulsion breakers.
Type:
Grant
Filed:
April 14, 2000
Date of Patent:
March 9, 2004
Assignee:
Clariant GmbH
Inventors:
Frank Holtrup, Tanja Schönstetter, Heidi Grundner
Abstract: A process for producing coated bleach activator granules in which bleach activator base granules are coated with a coating substance and are simultaneously and/or subsequently thermally conditioned.
Abstract: Resins useful in methods of breaking oil-water emulsions. The resins obtained by reacting a compound of formula 1 with an aldehyde and alkoxylating, in any order:
wherein X is —NHR1; —COOH; or —CONHR2; and
is ortho—, meta— or para— to X and is a radical of —O—R3; —C(O)R4; —OC(O)R5; —NR6R7; wherein R1-R7 values are defined herein.
Type:
Grant
Filed:
May 14, 2002
Date of Patent:
November 11, 2003
Assignee:
Clariant GmbH
Inventors:
Frank Holtrup, Elisabeth Wasmund, Wolfram Baumgärtner, Michael Feustel
Abstract: Copolymers based on ethylene and unsaturated carboxylic esters and their use as mineral oil additives.
The invention relates to copolymers of low olefins and vinyl esters, containing
a) from 85 to 97 mol % of bivalent structural units of the formula 1
—CH2—CR1R2— 1
in which R1 and R2, independently of one another, are hydrogen or methyl, and
b) at least 3 mol % of bivalent structural units of the formula 2
in which R3 is saturated, branched C6-C16-alkyl which has a tertiary carbon atom, wherein R3 is bonded by its tertiary carbon atom to the carboxyl function.
The copolymers according to the invention are used as flow improvers for mineral oil distillates.
Type:
Grant
Filed:
November 6, 2000
Date of Patent:
July 29, 2003
Assignee:
Clariant GmbH
Inventors:
Matthias Krull, Markus Kupetz, Raimund Wildfang
Abstract: Disclosed are improved solid, colored wax-based article having longer color shelf-life. The invention comprises a synthetic wax, a colorant, and an effective amount of a compound of the formula (1)
having symbols defined in the text.
The preferred embodiments of the articles contain (1) that exhibits a UV absorptivity greater than or equal to 70 liters per gram-cm. at a wavelength of less than or equal to 400 nm, as measured in either methanol, toluene or chloroform, using a conventional UV spectrophotometer.
The uses for the articles include candles, crayons, fertilizer coatings, rosebush coatings, plant grafting, sealants, sun-cracking protection of rubber and plastic products, paper coating, packaging food products, electrical insulation, waterproofing and cleaning compounds, carbon paper, and precision investment casting.
Abstract: A process for preparing diketopyrrolopyrrole pigments comprises conducting the elementary steps of pigment synthesis (reaction and hydrolysis) in a miniaturized continuous reactor.
Abstract: An additive for inhibiting the formation of gas hydrates in connection with hydrocarbon production and transportation comprising the water-soluble polymers comprising structural elements of the formula
wherein
each R is independently H or C1-C5-alkyl;
X is H, an alkaline or earth alkaline metal or a quaternary ammonium group;
R1 is H or C1-C18-alkyl; and R2 is C1-C18-alkyl;
and wherein the alkyl groups represented by R1 and R2 optionally carry a hydroxy or amino substituent; and, optionally, a minor proportion of structural elements of the formula
wherein R, R1, R2 and X may have the meaning as above, and Alk is a C1-C5-alkylene chain.
Abstract: The invention relates to a liquid to paste machine dishwashing detergent which, in addition to customary machine dishwashing detergent ingredients, comprises a crystalline, layered silicate of the formula
aA2O.bBO.cC2O3.dD2O5.eSiO2.fH2O,
in which A is an alkali metal and/or hydrogen, B is an alkaline earth metal, C is an element from the third main group of the Periodic Table, and D is an element from the fifth main group of the Periodic Table, and the following also apply: 0≦a≦1; 0≦b≦0.5; 0≦c/e≦0.05; 0≦d/e≦0.25; 1.9≦e≦4; 0≦f≦20.
The invention also relates to a process for the preparation of this machine dishwashing detergent and to its use.
Type:
Grant
Filed:
November 24, 1999
Date of Patent:
April 1, 2003
Assignee:
Clariant GmbH
Inventors:
Günther Schimmel, Lothar Westermann, Harald Bauer
Abstract: This invention relates to monoalkyl phosphoric esters, dialkyl phosphoric esters, and, in small amounts, trialkyl phosphoric esters or salts thereof, which are preferably based on &bgr;-branched fatty alcohols, particularly Guerbet alcohol, which are effective in lowering the surface tension of both polar and also nonpolar liquids, and which have high stability, even at elevated temperatures, and low sensitivity to electrolytes and acids. The invention further relates to the use of such mixtures as emulsifiers in cosmetic and pharmaceutical formulations, and to the resulting products.
Type:
Grant
Filed:
February 26, 1998
Date of Patent:
April 1, 2003
Assignee:
Clariant GmbH
Inventors:
Angelika Turowski-Wanke, Matthias Löffler, Oliver Eyrisch, Werner Skrypzak
Abstract: The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises
a) reacting alkylphosphonous and/or hypo- phosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and
b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkyl20 phosphinate salts.
Abstract: The invention provides an explosive composition consisting of
A) an oxygen-donating constituent, which forms a disperse phase,
B) an organic constituent, which forms a dispersion phase, and
C) at least one emulsifier,
wherein the emulsifier includes a copolymer comprising, in random or regular order, structural units derived from maleic anhydride and from one or more olefins having more than 40 carbon atoms, where the structural units derived from maleic anhydride have been modified by reaction with alcohols, aminoalcohols, ammonia or amines.
Abstract: The invention relates to a process for the preparation of terpolymers of ethylene and at least 2 further olefinically unsaturated compounds by polymerization in a tubular reactor fitted with at least one side branch, wherein the fresh monomer components, which are introduced into the tubular reactor via the reactor inlet (the primary stream) or via the side branch or side branches (secondary stream or secondary streams), in each of the streams contain ethylene and at most one further olefinically unsaturated compound.
Type:
Grant
Filed:
December 8, 1998
Date of Patent:
January 21, 2003
Assignee:
Clariant GmbH
Inventors:
Matthias Krull, Werner Reimann, Wilhelm Zoller, Heinz Dieter Bühnen, Gerhard Bettermann
Abstract: The present invention relates to a synergistic flame retardant combination for thermoplastic polymers which comprises as component A a salt of 1-hydroxydihydrophosphole oxides of the formula (Ia) or formula (Ib) and/or 1-hydroxyphospholane oxides of the formula (II)
and as component B a nitrogen compound of the formula (III) to (VIII) or a mixture of the compounds designated by the formulae
in which the substituents are as defined in the description.
Type:
Grant
Filed:
August 27, 1998
Date of Patent:
January 21, 2003
Assignee:
Clariant GmbH
Inventors:
Elke Jenewein, Bernd Nass, Wolfgang Wanzke
Abstract: The additive described essentially comprises a selected alkoxylated fatty amine or fatty amine derivative and a special metal salt compound, preferably a metal soap. This additive for heavy oils effects a good emulsification or dispersion of asphaltenes and other higher-molecular weight compounds and, in addition, inter alia, increased storage stability, improved pumpability due to decreased viscosity of the oil and longer service lives of the filter systems. In addition, it also effects enhanced combustion of the heavy oils. The effective amount of additive in these oils is 2 to 2000 ppm. The oils described are suitable, in particular, as furnace fuel for industrial plants and power stations and as engine fuel for marine engines.
Type:
Grant
Filed:
October 27, 1997
Date of Patent:
December 3, 2002
Assignee:
Clariant GmbH
Inventors:
Günther Hertel, Michael Feustel, Hakan Byström, Geoffrey Richards
Abstract: The invention relates to a pigment preparation comprising an organic pigment and 0.2 to 20% by weight, based on the total weight of the pigment preparation, of an ammonium polyphosphate or of an organophosphorus compound.
Type:
Grant
Filed:
December 8, 2000
Date of Patent:
November 12, 2002
Assignee:
Clariant GmbH
Inventors:
Rüdiger Jung, Klaus Saitmacher, Arpad Acs
Abstract: New heterocyclic compounds are disclosed which are used as intermediates for the preparation of trans-thiazine-indigo pigments which are in part new compounds and can be used for the mass pigmentation of organic substrates. Also disclosed are different environmentally friendly water-based processes for the preparation of the new heterocyclic compounds and the corresponding pigments.
Type:
Grant
Filed:
March 15, 2000
Date of Patent:
October 29, 2002
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Till Borchert, Bansi Lal Kaul, Bruno Piastra, Valérie Wolf
Abstract: A new polymorphic form of 2,9-dichloroquinacridone having improved pigmentary properties and a method of forming said 2,9-dichloroquinacridone comprising the step of ring closure of appropriately substituted terephthalic acid in sulphuric acid.