Patents Represented by Attorney, Agent or Law Firm Susan S. Jackson
  • Patent number: 6300516
    Abstract: The invention relates to a process for preparing dialkylphosphinic acids and/or alkali metal salts thereof by reacting olefins with alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: October 9, 2001
    Assignee: Clariant GmbH
    Inventors: Norbert Weferling, Hans-Peter Schmitz, Günter Kolbe
  • Patent number: 6290768
    Abstract: Pigment preparations comprising an organic pigment and a phenol-modified natural resin derivative having a weight-average molecular weight (Mw) of from 400 to 10,000 g/mol which is obtainable by reacting a mixture of reactants containing a) from 50 to 95% by weight of natural resin or natural resin acids, b) from 0.5 to 30% by weight of monocyclic or polycyclic phenols, c) from 0.01 to 15% by weight of aldehydes or aldehyde acetals, d) from 0.001 to 2% by weight of metal compounds from groups Ia and IIa of the Periodic Table, and e) from 4.489 to 30% by weight of &agr;,&bgr;-ethylenically unsaturated carboxylic acids or their anhydrides and has an acid number in the range from 160 to 300 mg of KOH per g of resin, preferably from 200 to 260 mg of KOH per g of resin, are used advantageously in offset printing.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: September 18, 2001
    Assignee: Clariant GmbH
    Inventors: Hans Joachim Metz, Joachim Weide, Thomas Wallach
  • Patent number: 6281292
    Abstract: The invention relates to mixtures comprising A) from 10 to 90% by weight of at least one copolymer comprising structural units derived from ethylene and structural units derived from olefinically unsaturated, hydroxyl-containing compounds, and B) from 90 to 10% by weight of at least one copolymer comprising structural units derived from ethylene and structural units derived from vinyl esters, olefinically unsaturated ethers and/or acrylates.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: August 28, 2001
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann, Markus Kupetz
  • Patent number: 6277345
    Abstract: The present invention relates to the use of an absorption liquid for purifying a gas by removal of gaseous, acidic impurities. The gas to be purified can be any gas, such as synthesis gas or natural gas, which contains gaseous, acidic impurities such as CO2, H2S, SO2, CS2, HCN, COS or mercaptans. The absorption liquid comprises: A) from 0.01 to 4% by weight of at least one compound of the formula B) from 0.001 to 8.0% by weight of water, and C) at least one polyalkylene glycol alkyl ether of the formula R1—O—(R2—O)x—R3 to 100% by weight, where R1 is C1-C4-alkyl, R2 is ethylene or 2-methylethylene, R3 is hydrogen or C1-C4-alkyl, R4 is hydrogen or C1-C4-alkyl, R5 is C1-C4-alkylene and X is an integer from 1 to 10. The amine may be N-methyldiethanolamine and the ether may be polyethylene glycol dimethyl ether.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: August 21, 2001
    Assignee: Clariant GmbH
    Inventors: Achim Stankowiak, Horst Streitberger, Michael Wyschofsky
  • Patent number: 6277536
    Abstract: Compounds of the formula (I) in which the substituents are as defined in claim 1 are valuable colorants for the mass coloring of polymers, with fluorescence property, in electrophotographics toners and developers, in powders coating materials and ink-jet inks.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: August 21, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bruno Piastra, Bansi Lal Kaul, Jean Christoph Graciet
  • Patent number: 6274111
    Abstract: The invention relates to a synthetic magnesium silicate having a layered crystalline structure, to a process for its preparation and to its use.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: August 14, 2001
    Assignee: Clariant GmbH
    Inventors: Harald Bauer, Günther Schimmel, Volker Thewes
  • Patent number: 6262153
    Abstract: Disclosed are improved solid, colored wax-based article having longer color shelf-life. The invention comprises a synthetic wax, a colorant, and an effective amount of a compound of the formula (1) having symbols defined in the text. The preferred embodiments of the articles contain (1) that exhibits a UV absorptivity greater than or equal to 70 liters per gram-cm. at a wavelength of less than or equal to 400 nm, as measured in either methanol, toluene or chloroform, using a conventional UV spectrophotometer. The uses for the articles include candles, crayons, fertilizer coatings, rosebush coatings, plant grafting, sealants, sun-cracking protection of rubber and plastic products, paper coating, packaging food products, electrical insulation, waterproofing and cleaning compounds, carbon paper, and precision investment casting.
    Type: Grant
    Filed: October 12, 1998
    Date of Patent: July 17, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Joseph R. Webster, Stephen E. Russell
  • Patent number: 6255482
    Abstract: The triphendioxazine compounds of the general formula (I) in which the rings labelled A in positions 1,2-, 2,3- or 3,4- and 8,9-, 9,10- or 10,11- carry a linearly or angularly fused heterocyclic ring containing at least one nitrogen atom which is substituted or unsubstituted, with the proviso that compounds with only unsubstituted nitrogen atoms and symmetrically disubstituted compounds with C1-2alkyl and unsubstituted phenyl substituents are excluded, are outstanding pigments and are notable over the closest comparable pigments in particular for better migration, light and solvent fastnesses, better heat stability and enhanced colouring power and also better dispersibility and capability to be brought into pigment form. The invention also relates to a process for preparing these triphendioxazine compounds which is characterized by a cyclization step conducted in the presence of manganese dioxide and concentrated sulphuric acid.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: July 3, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Patrick Boeglin, Bansi Lal Kaul, Peter Kempter
  • Patent number: 6251961
    Abstract: The invention relates to a flame-retardant coating which forms an insulating layer and is based on substances which carbonize and form a foam layer in the event of a fire, on film-forming binders, on blowing agents and on customary auxiliaries and additives, wherein the blowing agent present comprises melamine polyphosphate. The novel flame-retardant coating which forms an insulating layer is particularly stable under tropical conditions (up to 100% rel. humidity, about 75° C.), i.e. it releases only an extremely small amount of NH3.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: June 26, 2001
    Assignee: Clariant GmbH
    Inventors: Wolf-Dieter Pirig, Volker Thewes
  • Patent number: 6252066
    Abstract: Quaternary polycyclic polyammonium salts of the general formula and a process for their preparation are claimed, where A1, A2, A3, A4, R1, R2, X and Y have the meanings mentioned in the description.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: June 26, 2001
    Inventors: Bernd Nestler, Michael Seebach
  • Patent number: 6251553
    Abstract: The use of mixed-crystal pigments of the quinacridone series consisting of a) from 85 to 99% by weight of unsubstituted &bgr;-phase quinacridone of the formula (I) in which R1 and R2 are hydrogen atoms, and b) from 1 to 15% by weight of one or more substituted quinacridones of the formula (I) in which the substituents R1 and R2 are identical or different and are chlorine, bromine or fluorine atoms or C1-C4-alkyl, C1-C4-alkoxy or carboxamido groups, which can be substituted by C1-C6-alkyl groups, and R1 can additionally be hydrogen, as colorants in electrophotographic toners and developers, powder coating materials, inkjet inks, electret fibers, and color filters.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: June 26, 2001
    Assignee: Clariant GmbH
    Inventors: Ruediger Baur, Manfred Urban, Hans-Tobias Macholdt, Dieter Schnaitmann, Martin Boehmer
  • Patent number: 6248921
    Abstract: The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises a) reacting alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts. The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention for preparing flame retardants.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: June 19, 2001
    Assignee: Clariant GmbH
    Inventors: Norbert Weferling, Hans-Peter Schmitz, Günter Kolbe
  • Patent number: 6241814
    Abstract: Linear unsubstituted and substituted quinacridone pigments and quinacridone mixed-crystal pigments are obtained by cyclizing dianilinoterephthalic acid with polyphosphoric acid and then hydrolyzing the ring closure mixture, said mixture being metered into an amount of water or orthophosphoric acid which is such that the final orthophosphoric acid concentration is greater than or equal to 50% by weight in the hedrolysis mixture.
    Type: Grant
    Filed: July 12, 1999
    Date of Patent: June 5, 2001
    Assignee: Clariant GmbH
    Inventors: Manfred Urban, Martin Boehmer, Dieter Schnaitmann, Joachim Weber
  • Patent number: 6242642
    Abstract: The invention relates to a process for preparing arylalkyiphosphinic acids and/or alkali metal salts thereof by reacting olefins with arylphosphonous acids and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: June 5, 2001
    Assignee: Clariant GmbH
    Inventors: Norbert Weferling, Hans-Peter Schmitz
  • Patent number: 6239081
    Abstract: The present invention relates to water-based drilling fluids having decreased corrosion properties which comprise, in addition to alkali metal carboxylates, boron compounds and, if appropriate, clays, polymers and coinhibitors.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: May 29, 2001
    Assignee: Clariant GmbH
    Inventors: Joachim Korzilius, Peter Minks
  • Patent number: 6232493
    Abstract: The invention relates to a process for preparing metal salts of arylalkylphosphinic acids, which comprises: a) reacting olefins with arylphosphonous acids or alkali metal salts thereof in the presence of a cationic free-radical initiator, and b) reacting the arylalkylphosphinic acids or alkali metal salts thereof obtained by a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal arylalkylphosphinate salts. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: May 15, 2001
    Assignee: Clariant GmbH
    Inventors: Norbert Weferling, Hans-Peter Schmitz
  • Patent number: 6228162
    Abstract: C.I. Pigment Red 53:2 is obtained in new crystal modifications (epsilon, zeta, eta, theta, iota, kappa, lambda, nu, xi, omicron, pi and rho phases) by heating any other phase of this pigment in certain organic solvents and reprecipitating the pigment. The new crystal phases differ from one another in rheology and coloristics.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: May 8, 2001
    Assignee: Clariant GmbH
    Inventor: Martin U. Schmidt
  • Patent number: 6225385
    Abstract: The present invention relates to a stabilizer mixture prepared by partially condensing PCl3 with 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide, where the phosphorus content is from 2 to 4% by weight and the content of 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide is from 0.5 to 50% by weight. The stabilizer mixture has very good solubility in organic solvents and in the polymer and has very good stabilizing action.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: May 1, 2001
    Assignee: Clariant GmbH
    Inventors: Thomas Stährfeldt, Alexander Lichtblau, Gerhard Pfahler, Karl Gaa
  • Patent number: 6221150
    Abstract: The present invention relates to pigment dispersants of the formula (I) in which Z1 is a radical of the formula (Ia) —[X—Y]q—[X1—Y1]r—[X2—NH]sH  (Ia) in which X, X1 and X2 are identical or different and are a branched or unbranched C2-C6-alkylene radical or a C5-C7-cycloalkylene radical which can be substituted by from 1 to 4 C1-C4-alkyl radicals, hydroxyl radicals, and/or by from 1 to 2 further C5-C7-cycloalkyl radicals; Y and Y1 are identical or different and are an NH—, —O— or N(C1-C6-alkyl) group, q is a number from 1 to 6, r and s independently of one another are a number from 0 to 6, but are not simultaneously zero; and Z is defined as Z1, Z2 or Z3, where Z2 is a radical of the formula (Ib) —[X—O]q1—[X1—O]qH  (Ib) in which q1 is a number from 0 to 6, and Z3 is hydrogen, hydroxyl, amino or C1-C6-alkyl where the alkyl group can
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: April 24, 2001
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Manfred Urban, Erwin Dietz
  • Patent number: 6218451
    Abstract: The present invention relates to the use of a photoreactive and UV absorbing piperidine compound of the formula A below and of a mixture consisting of this piperidine compound and at least one selected UV absorber as light stabilizers in coating materials, preferably in automotive coating materials. The invention also provides a method of stabilizing coating materials against the degradation of the polymer material present in the coating material, as induced by the action of atmospheric oxygen, heat and/or UV light, and the coating materials themselves that are stabilized in this way.
    Type: Grant
    Filed: October 12, 1998
    Date of Patent: April 17, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Karl Bechtold, Gilbert Ligner