Abstract: A process for producing peroxydicarbonates comprising first reacting at least one inorganic peroxide with at least one alkali metal hydroxide to form at least one alkali metal peroxide. The at least one alkali metal peroxide is added to a mixture of at least one haloformate, at least one dispersant and water. The mixture is homogenized during the entire reaction to form a peroxydicarbonate. The peroxydicarbonate is dispersed as small droplets of from 1 to 10 microns in size in the aqueous mixture. The entire mixture is added to a polymerization reactor containing an ethylenically unsaturated monomer. The peroxydicarbonate functions as the free radical initiator to polymerize the monomer. The peroxydicarbonate is substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.

Abstract: A product capable of absorbing unwanted odors and unpleasant flavors, is sealed from said odors and flavors by being sealingly overwrapped with a film comprising an oriented film of a blend of polypropylene and a polymerized polyterpene selected from the group consisting of polymerized d-limonene, polymerized beta-pinene, polymerized synthetic approximation of d-limonene and beta-pinene and mixtures thereof.

Abstract: A laminated multilayer film substrate for use in the production of banknotes having an oriented polypropylene core layer with print features and at least one high density polyethylene layer on each side of the oriented polypropylene layer. The resultant films exhibit good embossability, dead-fold characteristics and other properties, and are difficult to counterfeit, making them highly suited for the production of bank notes and other security documents.

Abstract: A laminated film structure that includes a primary web having a migratory additive in a first outer layer and a metallocene polyethylene in a second outer layer that can be laminated to a secondary web without treating the surface of the second outer layer with a primer or solvent. The primary web further includes a core substrate layer disposed between the two outer layers that can include a biaxially oriented polypropylene. The laminated film structures have improved bond strength between the primary web and the secondary web.

Abstract: A laminated multilayer film substrate for use in the production of banknotes includes a first layer comprising (a) a first layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said first layer being oriented in the transverse direction (TD) to a degree which is at least three times greater than the degree of orientation present in the machine direction (MD); (b) a second layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.

Abstract: An oriented multi-layer film comprised of a core layer comprising a metallocene-catalyzed substantially isotactic propylene polymer, a first additional layer on a side of the core layer, and a second additional layer on a side of the core layer which side is opposite to the side having the first additional layer. In one embodiment of the invention, the core layer includes a polymerized alicyclic hydrocarbon such as polyterpene.

Abstract: The present invention relates to multilayer film which is heat sealable over a broad temperature range. It is desirable to have a broad sealing temperature range to increase the production of packaging machines. The present invention also relates to multilayer film which provides easy opening and hermetic seals to packages. The film is made up of a core layer comprising linear low density polyethylene (LLDPE) and at least one skin layer having a melting point of at least 10° C. below the core layer melting point.

Abstract: The invention is directed to an oriented multi-layer film which comprises a voided layer and at least one non-voided layer on at least one surface of the voided layer. In one embodiment, the voided layer comprises a Ziegler-Natta or metallocene-catalyzed substantially isotactic propylene polymer in a polymer matrix with a cavitation initiator. In a second embodiment, the non-voided layer comprises a Ziegler-Natta or metallocene-catalyzed substantially isotactic polypropylene polymer. In a third embodiment, both the voided core layer and at least one non-voided layer comprise a metallocene-catalyzed substantially isotactic polypropylene polymer.

Abstract: A sealable film comprises: (a) an inner layer comprising an olefin polymer; (b) a sealing layer; and (c) a separable layer positioned between the inner layer and the sealing layer, the separable layer comprising (1) ethylene-propylene block copolymer or (2) a blend of polyethylene and another olefin which is incompatible with the polyethylene, specifically either (i) polypropylene homopolymer or (ii) ethylene-propylene block copolymer. Methods of making the sealable film are described.

Abstract: The present invention is directed to biaxially oriented polymeric films. Specifically, the present invention is directed to biaxially oriented polyethylene films having unidirectional tear characteristics in machine direction and method thereof. The film of the present invention consists of (1) a core layer of medium density polyethylene (MDPE) and optionally a cavitating agent; and (2) at least one skin layer on at least one surface of the core layer. The skin layer is also made from a polyethylene. The core and skin layers coextensively adhere to one another and are biaxially oriented in both machine and traverse directions.

Abstract: An opaque, oriented polymeric film structure comprises: (a) a core layer containing a thermoplastic polymeric matrix material which has a first surface and a second surface, the core layer having a plurality of voids, substantially all or all of the voids being free from a void-initiating particle and at least some of the voids being interconnected with an adjacent void in the polymeric matrix material, the number of voids not containing a void-initiating particle being sufficient to impart a significant degree of opacity to the film structure; and (b) at least one outer or skin layer containing a thermoplastic polymeric material and an effective amount of a nucleating agent to suppress cavitation in said at least one outer or skin layer. The film structure has a smooth surface and can be tailored to provide a controlled permeability, and is particularly suitable for food packaging.

Abstract: Methods of preparing biaxially oriented polyethylene films with improved optics and sealability properties are provided. The methods include stretching in the machine direction a multi-layer base sheet having a core layer with a first and a second side, at least one skin layer and outer surfaces; then coating at least one of the outer surfaces with a resin selected from the group consisting of low density polyethylene, very low density polyethylene, linear low density polyethylene and blends thereof, and finally, stretching the base sheet in a direction transverse to the machine direction.

Abstract: An oriented multi-layer film comprises:(a) at least one layer comprising an olefin polymer, for example, isotactic polypropylene; and(b) a barrier layer adjacent the at least one layer of (a), comprising a syndiotactic polypropylene which preferably possesses an isotacticity of less than 25%, more preferably less than 15%, in particular less than 6%, and moisture and oxygen permeability reducing amounts of wax.

Abstract: A process for the production of a highly active olefin polymerization vanadium catalyst, comprising a vanadium compound and an organophosphorous compound combined on a catalyst support, which is capable of producing a broad range of polymer products. The polymer product's molecular weight distribution may be tailored to suit a desired application by controlling the P/V ratio of the catalyst.

Abstract: Dispersions of hydrophobic substance e.s. resin emulsions, usually having a relatively low average particle size can be continuously and speedily prepared by feed a hydrophobic substance in the liquid state into at least two static mixers, arranged in a series. The resin is introduced at a temperature above 50 degrees C. but below its degradation temperature of hydrophobic substance and water under pressure is introduced into the first mixer. The mixture of resin and water is passed to another mixer maintained at a temperature lower than that prevailing in the first mixer and below the boiling point of water. Optionally aqueous solution of surfactant under pressure instead of water is introduced into the first mixer and optionally aqueous surfactant is introduced into the second mixer.

Abstract: Polyolefin films for heat sealed packaging and twist wrapping are obtained by blending under high shear conditions and a rosin or resin, preferably hydrogenated to form a concentrate containing from 10 to 90 wt. %, preferably 20 to 60 wt. % of the resin or rosin and subsequently blending the concentrate with a and extruding the resultant blend to form a film.

Abstract: A foamable composition for in situ expansion for example in a car pillar includes a base polymer derived of ethylene and an olefinically unsaturated acrylic ester with an M1 of from 0.1 to 6 and containing from 10 to 40% of ester derived units. The composition is foamed and cross-linked to adhere to the car pillar interior and provide closed cell foam acting as a moisture-sound barrier.

Abstract: A thermoplastic film is provided which is especially suited for use in stretch/cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising (i) a polymer of at least ethylene and acrylate or vinyl acetate, blended with (ii) a compatible, non-migratory tackifier. The film may further comprise a non-cling layer comprising a thermoplastic material essentially free of tackifier, with or without an anticling (slip and/or antiblock) additive. Preferred thermoplastic materials include linear low density polyethylene and polypropylene.