Abstract: A diesel fuel composition comprising from about 70 to about 95 weight percent of dimethyl ether, up to about 20 weight percent of methanol, and from about 0.1 to about 20 weight percent of water is disclosed.

Abstract: The present invention is an integrated process for converting light hydrocarbon gas to heavier hydrocarbon liquids. In each embodiment, a Fischer-Tropsch (FT) process comprising a thermal reformer and a reactor containing an FT catalyst is combined with one or more additional processes to achieve operational synergies. In a first embodiment, an FT process is integrated with a cryogenic liquefied natural gas (LNG) process wherein tail gas from the FT reaction is used to drive a refrigeration compressor in the LNG process. The tail gas, optionally supplemented with natural gas, may be fed directly to a gas turbine or may be combusted in steam boiler, which in turn provides steam to a steam turbine. The natural gas may be processed prior to its being fed to the LNG process and the FT process in order to remove any impurities and/or condensate. The process may be further integrated with a fertilizer production process comprising an ammonia synthesis process and a urea synthesis process.

Abstract: A power generating method that includes the steps of burning a reformed fuel in the presence of air in a combustor of a gas turbine to generate a hot exhaust gas is disclosed. The hot exhaust gas is then passed through a turbine section of the gas turbine to generate power and, thereafter, the hot exhaust gas is passed through a heat recovery system where the hot exhaust gas is successively cooled as it passes through a series of heat exchangers. Heat exchangers comprising the heat recovery system include combustion air pre-heater(s); a thermochemical recuperator (or reformer), wherein hot exhaust gas provides the endothermic heat of reaction necessary to reform a raw fuel/steam mixture to the combustible, reformed fuel that is eventually burned in the combustor; and one or more water/steam heaters which supply steam to a low-pressure, condensing steam turbine of a bottoming Rankine cycle to generate additional power.

Abstract: Composite materials of the invention, which include a gas-tight ceramic, a porous metallic support, and an interfacial zone therebetween eliminate the need for mechanical seals between two such dissimilar materials. Oxygen ion-conducting dense ceramic membranes are formed on a porous metallic alloy to provide an interfacial zone identifiable by a gradient of composition in at least one metallic element across the interfacial zone between the dense ceramic membrane and the porous support. Processes using composite materials in accordance with the invention are, for example, used for production of synthesis gas comprising carbon monoxide and molecular hydrogen, whereby the synthesis gas is, advantageously, free of deleterious and/or inert gaseous diluents such as nitrogen.

Abstract: An improved process for the compression and heating of air or oxygen-enriched air for charging to an autothermal reactor by using a single high compression ratio compressor to produce a high-pressure, high-temperature air or oxygen-enriched air stream for mixture with a hydrocarbon gas stream to produce a charge stream to an autothermal reactor at an elevated pressure above about 350 psig and at an elevated temperature from about 700 to about 900.degree. F.

Abstract: Hydrotalcite-like clays, catalysts derived therefrom, and methods of hydrocarbon reforming using the catalyst are disclosed. The hydrotalcite-like clays, which may be calcined to form the catalyst, have the formula [M.sup.2+.sub.(1-x) M.sup.3+.sub.x (OH).sub.2 ].sup.x+ (A.sup.n-.sub.x/n).mH.sub.2 O at an elevated temperature for a time sufficient to decompose A and to dehydrate said compound, wherein M.sup.2+ comprises at least two species of metal ions having a valence of 2+ selected from the group consisting of Cu.sup.2+, Zn.sup.2+, Ni.sup.2+, and Mg.sup.2+, provided that if M.sup.2+ comprises Mg.sup.2+ at least one of Zn.sup.2+ and Ni.sup.2+ is also present, wherein the atomic ratio of the total of Zn.sup.2+ and Mg.sup.2+ to the total of Cu.sup.2+ and Ni.sup.2+ is up to about 9, inclusive, wherein the total of Zn.sup.2+ and Mg.sup.2+ comprises at least about 5 wt. % of said M.sup.2+ metals; M.sup.3+ is at least one metal ion having a valence of 3+ selected from the group consisting of Al.sup.3+, Fe.sup.

Abstract: A particularly useful process of contacting a feedstream containing dioxygen, carbon monoxide, ether, and alkanol which can be vaporized under conditions of reaction, with a blend of catalysts which are heterogeneous to the feedstream, under conditions of reaction sufficient to form a mixture containing at least one higher molecular weight oxygenated organic compound. In another aspect this invention relates to a blend of catalysts consisting of at least one molecular sieve, natural or synthetic, which has been found useful for hydrocarbon conversion reactions and a catalyst comprising a metal halide or a mixed metal halide supported on active carbon which is effective in catalyzing direct formation of organic carbonates.

Abstract: An electrochemical process for extracting oxygen from an oxygen-containing gas which uses an electrochemical cell having two zones separated by a multi-component membrane made from intimate, gas-impervious, multi-phase mixture of an electronically conductive phase and an oxygen ion-conducting phase. In one zone a gas containing oxygen is passed in contact with the membrane. In the other zone a gas capable of reacting with oxygen is passed in contact with the membrane.

Abstract: The present invention relates to devices for conducting, simultaneously, exothermic and endothermic chemical conversions with transfer of heat therebetween. More particularly, this invention relates to autothermic modules using oxygen ion-conducting dense ceramic membranes to separate, selectively, oxygen from an oxygen-containing gas and supply it directly to partial combustion of gaseous organic compounds. Processes using autothermic modules in accordance with this invention are, advantageously, used for production of synthesis gas comprising carbon monoxide and molecular hydrogen which synthesis gas is substantially free of deleterious and/or inert gaseous diluents such as nitrogen. In particular, for conversions, within the integral autothermic module, of natural gas or other forms of gaseous lower alkanes to synthesis gas by means of partial combustion followed by reforming.

Abstract: A particularly useful process which includes the steps of providing a source of formaldehyde formed by conversion of dimethyl ether in the presence of a catalyst comprising silver as an essential catalyst component; and contacting the source of formaldehyde and a predominately dimethyl ether feedstream with a heterogeneous, condensation promoting catalyst capable of hydrating dimethyl ether under conditions of reaction sufficient to form an effluent comprising water, methanol, formaldehyde, dimethyl ether, and polyoxymethylene dimethyl ethers is disclosed. Unreacted dimethyl ether is recovered from the effluent and recycled to the formation of polyoxymethylene dimethyl ethers. The resulting dimethyl ether-free liquid mixture is heated in the presence of an acidic catalyst to convert at least the methanol and formaldehyde present to polyoxymethylene dimethyl ethers. Advantageously, methylal and higher polyoxymethylene dimethyl ethers are formed and separated in a catalytic distillation column.

Abstract: A direct, simplified and relatively salt-free process is described for making anionic, hydrotalcite-type pillared clay compositions which contain nickel, and their heat-treated derivatives. Compositions of the invention are manufactured from ractants which contain a relatively minor amount of metal salts or, preferably, contain essentially no metal salts. Preferred compositions made by the process form a number of new nickel-containing catalytic materials which are unusually resistant to deactivation, for example resistant to coke formation when used to catalyze chemical conversions of a hydrocarbyl compound with an oxygen-containing gas at elevated temperatures to form synthesis gas.

Abstract: The present invention relates to composite materials for membrane reactors which include a gas-tight ceramic, a porous support, and an interfacial zone therebetween. More particularly, this invention relates to composite materials using oxygen ion-conducting dense ceramic membranes formed on a porous support comprising a metallic alloy to provide an interfacial zone identifiable by a gradient of composition in at least one metallic element across the interfacial zone between the dense ceramic membrane and the porous support. Processes using composite materials in accordance with the invention are, for example, used for production of synthesis gas comprising carbon monoxide and molecular hydrogen which synthesis gas is, advantageously, free of deleterious and/or inert gaseous diluents such as nitrogen.

Abstract: A method, a map and an article of manufacture for the exploration of hydrocarbons. In one embodiment of the invention, the method comprises the steps of: accessing 3D seismic data; dividing the data into an array of relatively small three-dimensional cells; determining in each cell the semblance/similarity, the dip and dip azimuth of the seismic traces contained therein; and displaying dip, dip azimuth and the semblance/similarity of each cell in the form a two-dimensional map. In one embodiment, semblance/similarity is a function of time, the number of seismic traces within the cell, and the apparent dip and apparent dip azimuth of the traces within the cell; the semblance/similarity of a cell is determined by making a plurality of measurements of the semblance/similarity of the traces within the cell and selecting the largest of the measurements.

Abstract: The invention relates to high energy, oxygenated fuel compositions suitable for use in compression ignition internal combustion engines which fuel compositions contain a synergistic combination of dimethyl ether, methanol, and water, the combination providing a single liquid phase with good ignition characteristics. More particularly fuels comprising from about 72 to about 95 weight percent of dimethyl ether, from about 0.1 to about 20 weight percent of methanol, and from about 0.1 to about 20 weight percent of water are disclosed.

Abstract: A method and apparatus for the exploration of hydrocarbons comprising the steps of: obtaining a set of seismic signal traces distributed over a predetermined three-dimensional volume of the earth; dividing the three-dimensional volume into a plurality of analysis cells having portions of at least two seismic traces located therein; computing outer products of the seismic traces within each cell; forming the covariance matrix for each cell from these outer products; computing the dominant eigenvalue and the sum of the eigenvalues of the covariance matrix of each cell and computing a seismic attribute from the ratio of the dominant eigenvalue to the sum of the eigenvalues of the covariance matrix of each cell; and forming map of the seismic attributes of selected groups of cells.

Abstract: A continuous vapor phase processes for direct condensation of methanol and/or dimethyl ether with dilute acetylene feedstream to a mixture containing at least one higher molecular weight alkanol, such as n-propanol or isobutanol, over an alkaline catalyst which is, advantageously, an essentially magnesium oxide catalyst.

Abstract: A continuous process for recovery of acetylene-free gaseous mixture from gaseous feedstreams containing acetylene and optionally other low molecular weight hydrocarbons by contacting the acetylene-containing feedstream with an alkanol in combination with a super acid catalyst, Lewis acid, Bronsted acids, or mixtures thereof, under conditions of reaction sufficient to form a mixture containing at least one acetal organic compound, and a gaseous product substantially free of acetylene. Preferred catalysts include boron trifluoride in methanol with mercuric oxide. Processes according to the invention are, advantageously, used for recovery of acetylene-free gaseous mixture from gaseous feedstreams containing a mixture of acetylene, a synthesis gas comprising dihydrogen and carbon monoxide, and optionally one or more members of the group consisting of dimethyl ether, formaldehyde, ethylene, and propylene.

Abstract: An apparatus and method for automatically dispensing chemical sticks into a well bore is provided. In the preferred form, the apparatus is for dispensing soap sticks to unload an oil/gas producing well of fluid, e.g., salt water, built-up therein. The apparatus is a tubular receptacle with an upper storage section and a lower receiving chamber with sticks stacked end-to-end in the storage section and fed, as by gravity feed, to the receiving chamber after a stick is dispensed therefrom. An operating mechanism controls dispensing so that a stick is dispensed based on a predetermined timing sequence or when a predetermined well condition is reached. A preferred soap stick for use in the apparatus includes a water-soluble, flexible, resilient sheath encasing the stick body tightly therein.

Abstract: A method and nickel-containing catalyst are disclosed for preparing synthesis gas by the reforming of a hydrocarbyl compound using an oxygen-containing compound.

Abstract: A process of contacting a feedstream containing dioxygen, carbon monoxide, ether, and alkanol, which can be vaporized under conditions of reaction, with a blend of catalysts which are heterogeneous to the feedstream, under conditions of reaction sufficient to form a mixture containing at least one higher molecular weight oxygenated organic compound is described. In another aspect, this invention relates to a blend of catalysts consisting of at least one molecular sieve, natural or synthetic, which has been found useful for hydrocarbon conversion reactions and a catalyst comprising a metal halide or a mixed metal halide supported on active carbon, which is effective in catalyzing direct formation of organic carbonates.