Patents Represented by Attorney, Agent or Law Firm Thomas M. Breininger
  • Patent number: 6200420
    Abstract: Anionic nanocomposites for use as retention and drainage aids in papermaking are prepared by adding an anionic polyelectrolyte to a sodium silicate solution and then combining the sodium silicate and polyelectrolyte solution with silicic acid.
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: March 13, 2001
    Assignee: Nalco Chemical Company
    Inventors: Arthur James Begala, Bruce A. Keiser
  • Patent number: 6184257
    Abstract: The present invention provides a novel formulation in a composition comprising FeCl3 and a dialkyl diallyl ammonium polymer where the FeCl3 has been diluted with water prior to being mixed with the polymer providing a stable composition.
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: February 6, 2001
    Assignee: Calgon Corporation
    Inventor: Denis E. Hassick
  • Patent number: 6184336
    Abstract: New and improved polyamino acid polymers and derivatized polyamino acid polymers are provided. Relatively high molecular weight poly(succinimides) are prepared by solid phase polymerization of aspartic acid or glutamic acid in the presence of a super phosphoric acid catalyst. The poly(succinimides) may be hydrolyzed to provide biodegradable polyaspartic acid or polyglutamic acid homopolymer having weight average molecular weights ≧70,000. Higher molecular weight, water soluble, cross-liked polyamino acid polymers and gels are also provided. In a preferred embodiment, the poly(succinimides) are derivatized in aqueous media to provide storage stable, substantially linear, biodegradable polyamino acid polymers having pendant hydroxyl, ether, hydroxyalkylaminoalkyl, hydroxyalkoxyalkyl, carboxyl, sulfonoalkyl and/or phosphonoalkyl functionalities. The polymers are useful as chelants in various water treatment applications.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: February 6, 2001
    Assignee: Nalco Chemical Company
    Inventor: Jiansheng Tang
  • Patent number: 6177017
    Abstract: A method for the removal of metal cyanides or oxoanions from aqueous streams such as waste water streams with compounds containing 1,4-diazabicyclo[2.2.2]octane. Preferred compounds are polymers formed by free radical polymerization of N-4-vinyl benzyl-N1-1,4-diazabicyclo[2.2.2]octane dichloride (VBBD) such as copolymers poly (VBBD/acrylamide) and poly (VBBD/dimethyl amino ethyl acrylate benzyl chloride quaternary salt. Poly(1,4-dimethylbenzyl-1,4-diazabicyclo[2.2.2]octane dichloride) for the same purposes is also disclosed.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: January 23, 2001
    Assignee: Nalco Chemical Company
    Inventor: William J. Ward
  • Patent number: 6174843
    Abstract: This invention provides a composition and a method of using the composition for dispersing wax and improving the pour point of lubricating oils. The composition comprises an esterified styrene-maleic anhydride copolymer and an esterified alpha-olefin maleic anhydride copolymer.
    Type: Grant
    Filed: November 17, 1994
    Date of Patent: January 16, 2001
    Assignee: Nalco Chemical Company
    Inventors: Kim B. Peyton, Sophia L. Wang
  • Patent number: 6171521
    Abstract: This invention is directed to a zwitterionic water-soluble imine of formula: wherein R1 is heterocyclyl, heteroaryl, aryl, arylalkyl, cycloalkyl or lower alkyl; R2 is alkyl, alkenyl, aminoalkyl, diaminoalkyl, hydroxyalkyl, alkoxyalkyl, thioalkyl, alkylthioalkyl or arylalkyl; R3 is hydrogen and lower alkyl, or R1 and R3 taken together form a cycloalkyl, p is 2, 3, 4 or 5; and Z is CO2−, OCO2−, SO3−, OSO3−, PO3− or OPO3− which are useful as ferrous metal corrosion inhibitors.
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: January 9, 2001
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventor: G. Richard Meyer
  • Patent number: 6171505
    Abstract: The invention is a method for clarifying, dewatering or improving retention and drainage of industrial waste water or paper furnish with an effective amount of at least one dispersion of a water soluble cationic polymer flocculant wherein the improvement comprises the addition of said polymer which has a concentration of at least twenty five percent to said waste water or paper furnish. The industrial waste is preferably food processing waste water, oily waste water, paper mill waste water and inorganic contaminated waste water. The paper furnish may be an aqueous cellulosic suspension.
    Type: Grant
    Filed: April 3, 1998
    Date of Patent: January 9, 2001
    Assignee: Nalco Chemical Company
    Inventors: Elise E. Maury, Rudolf Buelte, Cathy C. Johnson
  • Patent number: 6168029
    Abstract: An improved method for separating electrically conductive components of an ore or mineral sand from electrically non-conductive components of the ore or mineral sand is disclosed which includes processing the ore, adding a polymer, such as an anionic polymer, to the processed ore, drying the polymer and ore, and then feeding the ore and polymer through an electrostatic separator. The addition of the anionic polymer to the processed ore increases the efficiency of the electrostatic separation process.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: January 2, 2001
    Assignee: Nalco Chemical Company
    Inventors: Raymond Leslie Henderson, Graeme Allan
  • Patent number: 6169134
    Abstract: An oil based drilling mud is viscosified with a maleated ethylene-propylene elastomers. The elastomers are preferably EPM copolymers or EPDM terpolymers. The concentration of the maleic anhydride grafted to the copolymer or terpolymer backbone ranges from 0.01 to 5 wt %, preferably 0.1 to 2.0 wt %. The maleated elastomers are far more effective oil mud viscosifiers than the organophilic clays presently used.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: January 2, 2001
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventors: Cruise K. Jones, David B. Acker
  • Patent number: 6156229
    Abstract: Stable biocide formulations containing oxidizing bromine are provided for biofouling control in industrial water systems. The formulations contain at least one stable oxidizing bromine compound that is prepared from at least one oxidizing chemical reagent, at least one bromine source and at least one bromine or halogen stabilizer. The resulting products are a mixture of stable oxidizing bromine compounds that can be used as a biocide in an industrial water system.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: December 5, 2000
    Assignee: Nalco Chemical Company
    Inventors: Shunong Yang, William F. McCoy, Anthony W. Dallmier
  • Patent number: 6153106
    Abstract: The present invention relates to a method for inhibiting the formation and deposition of silica scale in water systems. The method includes treating the water in such water systems with an effective amount of a polyamide that exhibits secondary amine and/or ether and amide functional groups.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: November 28, 2000
    Assignee: Nalco Chemical Company
    Inventors: Douglas G. Kelley, Kevin J. Moeggenborg, David P. Workman
  • Patent number: 6147034
    Abstract: This invention is directed to a gelling agent composition comprising the reaction product of a high molecular weight gelling agent additive, a low molecular weight phosphate diester acid, and a Group II or Group III metal salt, to methods of preparing the gelling agent composition, to a gelled hydrocarbon liquid comprising the gelling agent composition and to a method of fracturing subterranean formations using the gelled hydrocarbon liquid.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: November 14, 2000
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventors: Cruise K. Jones, Grahame N. Taylor
  • Patent number: 6146495
    Abstract: An improved process for inhibiting calcium carbonate scaling in aqueous systems such as that employed in the kraft process for the production of wood pulp. Such an improved process is achieved by the addition to the system of at least one antiscalant comprising at least one monomer unit derived from the group consisting of 1,2-dihydroxy-3-butene, N-(hydroxymethyl) acrylamide, and N-(sulfomethyl) acrylamide, and at least one monomer unit derived from the group consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit --(CH.sub.2 --CH.dbd.CH--CH.sub.2 --O)--.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: November 14, 2000
    Assignee: Nalco Chemical Company
    Inventors: Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
  • Patent number: 6139830
    Abstract: A method for reducing formation of deposits on a surface in contact with an aqueous system includes applying to the surface a composition comprising a polyoxypropylene-polyoxyethylene block copolymer and a biocide. The composition optionally may also include a dispersant.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: October 31, 2000
    Assignee: Calgon Corporation
    Inventors: Rodney M. Donlan, David L. Elliott, Jasbir S. Gill, Christopher L. Wiatr, Peter R. Ten Eyck
  • Patent number: 6140130
    Abstract: A system and method for the detection and removal of copper from wastewater streams from semiconductor or printed circuit board manufacturing is described and claimed. The detection system and method involve the addition of a reagent that reacts with copper to quench the fluorophore present, with the decrease in fluorescence being detected by a fluorometer. The reduction of fluorescence is then used to calculate the amount of copper present in the form of Cu+2 ion in the wastewater. The removal system and method involve either the addition of a polymer that reacts with copper to form an insoluble precipitate with said precipitate then being removed by using any technique commonly known in the art; or the use of an ion exchange column to remove the copper from the wastewater stream.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: October 31, 2000
    Assignee: Nalco Chemical Company
    Inventors: Kristine S. Salmen, Angela S. Kowalski, Brian V. Jenkins, John E. Hoots
  • Patent number: 6136205
    Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: October 24, 2000
    Assignee: Nalco Chemical Company
    Inventors: Anthony W. Dallmier, William F. McCoy, Shunong Yang
  • Patent number: 6133368
    Abstract: A dispersant system useful in the formation of dispersions of water soluble polymers is disclosed. The dispersant system comprises two polymers, the first being a copolymer of diallyldimethyl ammonium chloride with a C.sub.6 to C.sub.20 quaternary ammonium salt of a monomer selected the from the group consisting of dialkylaminoalkylacrylates, dialkylaminoalkylmethacrylates, dialkylaminoalkylacrylamides, and dialkylaminoalky (meth) acrylamides as well as certain alkyl esters of acrylic acid. The second polymer is a water soluble cationic polymer composed of at least 20 mole percent of a cationic monomer represented by the formula: ##STR1## where R.sub.4 is either hydrogen or CH.sub.3 ; R.sub.5 and R.sub.6 are each an alkyl group having 1 to 2 carbon atoms; R.sub.7 is a hydrogen atom or an alkyl group having 1 to 2 carbon atoms; A.sub.2 is either an oxygen atom or NH; B.sub.2 is either an alkylene group having 2 to 4 carbon atoms or a hydroxypropylene group and X.sub.2.sup.- is an anionic counterion.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: October 17, 2000
    Assignee: Nalco Chemical Company
    Inventors: John R. Hurlock, Manian Ramesh
  • Patent number: 6133363
    Abstract: The invention relates to a method of manufacturing dispersions of water-sble cationic vinyl polymers which can be used as process aids for separation processes, e.g. as flocculation aids, coagulation agents, retention agents or dehydration accelerators. The dispersions are produced by radical homopolymerization of cationic, hydrophobically modified vinyl monomers or their copolymerization with water-soluble vinyl monomers in aqueous saline solutions. In this respect block copolymers are used as dispersion stabilizers, and which are formed from a cationic vinyl monomer and ethyleneoxide.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: October 17, 2000
    Assignee: Fraunhofer-Gesellschaft zur Foerderung der Angewandten Forschung E.V.
    Inventors: Werner Jaeger, Arvid Zimmermann, Karl-Heinz Reichert, Katrin Zeitz
  • Patent number: 6133205
    Abstract: A method is disclosed for reducing the concentration of metal soaps of partially esterified phosphates from a hydrocarbon flowback fluid resulting from a hydraulic fracturing fluid operation using an alkaline aqueous-based additive solution.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: October 17, 2000
    Assignee: Nalco/Exxon Energy Chemical L.P.
    Inventor: Cruise K. Jones
  • Patent number: 6123870
    Abstract: Stable oxidizing bromine compounds are prepared by preparing a caustic solution comprising a halogen stabilizer, water and an alkali or alkaline earth metal hydroxide, the halogen stabilizer being selected from the group consisting of R--NH.sub.2, R--NH--R.sup.1, R--SO.sub.2 --NH.sub.2, R--SO.sub.2 --NHR.sup.1, R--CO--NH.sub.2, R--CO--NH--R.sup.1 and R--CO--NH--CO--R.sup.1 wherein R is a hydroxy group, an alkyl group or an aromatic group and R.sup.1 is an alkyl group or an aromatic group, adding bromine chloride to the solution while mixing the solution, and cooling the solution.
    Type: Grant
    Filed: April 21, 1999
    Date of Patent: September 26, 2000
    Assignee: Nalco Chemical Company
    Inventors: Shunong Yang, William F. McCoy, Anthony W. Dallmier